摘要
The increase in anthropogenic carbon dioxide(CO_(2))emissions has exacerbated the deterioration of the global environment,which should be controlled to achieve carbon neutrality.Central to the core goal of achieving carbon neutrality is the utilization of CO_(2) under economic and sustainable conditions.Recently,the strong need for carbon neutrality has led to a proliferation of studies on the direct conversion of CO_(2) into carboxylic acids,which can effectively alleviate CO_(2) emissions and create high-value chemicals.The purpose of this review is to present the application prospects of carboxylic acids and the basic principles of CO_(2) conversion into carboxylic acids through photo-,electric-,and thermal catalysis.Special attention is focused on the regulation strategy of the activity of abundant catalysts at the molecular level,inspiring the preparation of high-performance catalysts.In addition,theoretical calculations,advanced technologies,and numerous typical examples are introduced to elaborate on the corresponding process and influencing factors of catalytic activity.Finally,challenges and prospects are provided for the future development of this field.It is hoped that this review will contribute to a deeper understanding of the conversion of CO_(2) into carboxylic acids and inspire more innovative breakthroughs.
基金
financial support from the King Abdullah University of Science and Technology(KAUST).
作者简介
Correspondence:Huabin Zhang,KAUST Catalysis Center(KCC),King Abdullah University of Science and Technology(KAUST),Thuwal 23955-6900,Saudi Arabia.Email:Huabin.zhang@kaust.edu.sa;Wenhuan Huang,Key Laboratory of Chemical Additives for China National Light Industry,College of Chemistry and Chemical Engineering,Shaanxi University of Science and Technology,Xi'an 710021,China.Email:huangwenhuan@sust.edu.cn;Linjie Zhi,Advanced Chemical Engineering and Energy Materials Research Center,China University of Petroleum(East China),Qingdao 266580,China.Email:zhilj@upc.edu.cn。
