摘要
As a versatile energy carrier,H_(2) is considered as one of the most promising sources of clean energy to tackle the current energy crisis and environmental concerns,which can be produced from photocatalytic water splitting.However,solar-driven photocatalytic H_(2) production from pure water in the absence of sacrificial reagents remains a great challenge.Herein,we demonstrate that the incorporation of Ru single atoms(SAs)into ZnIn_(2)S_(4)(Ru-ZIS)can enhance the light absorption,reduce the energy barriers for water dissociation,and construct a channel(Ru-S)for separating photogenerated electron−hole pairs,as a result of a significantly enhanced photocatalytic water splitting process.Impressively,the productivity of H_(2) reaches 735.2μmol g^(-1) h^(-1) under visible light irradiation in the absence of sacrificial agents.The apparent quantum efficiency(AQE)for H_(2) evolution reaches 7.5% at 420 nm,with a solarto-hydrogen(STH)efficiency of 0.58%,which is much higher than the value of natural synthetic plants(~0.10%).Moreover,Ru-ZIS exhibits steady productivity of H_(2) even after exposure to ambient conditions for 330 days.This work provides a unique strategy for constructing charge transfer channels to promote the separation of photogenerated electron−hole pairs,which may motivate the fundamental researches on catalyst design for photocatalysis and beyond.
基金
financially supported by the National Key R&D Program of China(2020YFB1505802)
the Ministry of Science and Technology(2017YFA0208200)
the National Natural Science Foundation of China(22025108,U21A20327,and 22121001)
the start-up funding from Xiamen University.
作者简介
Huiping Peng,State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China;Mingzi Sun,Department of Applied Biology and Chemical Technology,The Hong Kong Polytechnic University,Kowloon,Hong Kong SAR 999077,China,orcid.org/0000-0001-5136-7265;Fei Xue,State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China;Xiaozhi Liu,Beijing National Laboratory for Condensed Matter Physics Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China,orcid.org/0000-0001-8647-8694;Dong Su,Beijing National Laboratory for Condensed Matter Physics Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China,orcid.org/0000-0002-1921-6683;Corresponding Authors:Bolong Huang,Department of Applied Biology and Chemical Technology,The Hong Kong Polytechnic University,Kowloon,Hong Kong SAR 999077,China,orcid.org/0000-0002-2526-2002,Email:bhuang@polyu.edu.hk;Corresponding Authors:Yong Xu,i-lab,Suzhou Institute of Nano-Tech and Nano-Bionics(SINANO),Chinese Academy of Sciences(CAS),Suzhou 215123,China,orcid.org/0000-0001-5115-6492,Email:yxu2023@sinano.ac.cn;Corresponding Authors:Xiaoqing Huang,State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China,orcid.org/0000-0003-3219-4316,Email:hxq006@xmu.edu.cn。
