摘要
以2-(2,4,6-Me3C6H2N=CH)C4H3NH为配体与铕配合物[(Me3Si)2N]3Eu(μ-Cl)Li(THF)3反应,合成了三价铕金属配合物[2-(2,4,6-Me3C6H2N=CH)C4H3N]3Eu(THF),以此配合物为催化剂催化芳胺与N,N'-二异丙基碳二亚胺反应,得到一系列胍产物,研究了反应时间、温度、催化剂用量和溶剂对催化反应的影响。结果表明:铕配合物具有良好的催化活性,以2%mol的催化剂用量、在THF中加热60℃反应8 h,得到高于80%产率的相应胍产物。
Treatment of the europium complex[（Me3Si）2N]3Eu（μ-C1）Li（THF）3with 2-（2,4,6-Me3C6H2N=CH） C4H3NH affor- ded a trivalent europium metal complex with formula [2-（2,4,6-Me3C6H2N=CH） C4H3N]3Eu（THF）. A series of guanidine prod- ucts were synthesized by the reaction of aromatic amines to N, N＇-diisopropylcarbodiimide with the europium complex as cata- lyst. The influence of the conditions such as reaction time, temperature, catalyst loading and solvent on the reaction was studied. The results showed that the europium complex exhibited a high catalytic activity and that the guanidine products were obtained beyond 80% yields in the following conditions：the molar ratio of the catalyst loading was 2% mol, the solvent was THF, the temperature was 60~C ,and the time was 8 h.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2013年第2期224-228,共5页
Chemical Research and Application
基金
安徽省高校优秀青年人才基金项目(2012SQRL207)资助
安徽省高校省级自然科学重点研究项目(KJ2012A268)资助
作者简介
刘超（1977-），男，实验师，主要研究方向：金属有机化学。E—mail：ahliueha0333@sohu．com
