摘要
采用沉淀-研磨法制备了一系列不同WO3含量的WO3/ZnO复合光催化剂,应用N2物理吸附、X射线衍射、扫描电镜、傅里叶变换红外光谱、紫外-可见光谱和光致发光谱等手段对催化剂进行了表征,并以λ=365nm的紫外光为光源,评价了该催化剂光催化降解酸性橙II的活性,考察了WO3的复合对WO3/ZnO样品光催化性能的影响.结果表明,当复合2%WO3,并于600°C焙烧时,所制备的WO3/ZnO催化剂活性最高,比纯ZnO的提高了约一倍.合适的煅烧温度可以提高催化剂结晶度,而WO3的复合可抑制ZnO晶粒的长大,提高催化剂比表面积和改善催化剂表面羟基数量,并可抑制光生电子与光生空穴的复合,从而显著提高其光催化脱色活性.
A series of WO3/ZnO composite photocatalysts with different WO3 concentrations were prepared by a precipitation-grinding method followed by calcination at different temperatures.The prepared samples were characterized by N2 physical adsorption,X-ray diffraction,scanning electron microscopy,Fourier transform infrared spectroscopy,UV-visible spectroscopy,and photoluminescence spectroscopy.The photocatalytic activity of the samples was evaluated by photocatalytic degradation of acid orange II under UV light （λ=365 nm） irradiation.The results showed that at the optimal calcination temperature of 600 °C,the WO3/ZnO composite photocatalyst with 2 wt% concentration of WO3 showed about doubled photocatalytic activity compared to pure ZnO.The increase in the photocatalytic activity could be attributed to the coupling of WO3,which suppressed the growth of ZnO particles,increase of the surface area and increased amount of surface OH groups of the sample.The presence of WO3 also restrained the recombination rate of e？/h＋ pairs.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第4期555-565,共11页
基金
国家自然科学基金(21067004)
江西省自然科学基金(2010GZH0048)
江西省教育厅青年科学基金(GJJ10150)
固体表面物理化学国家重点实验室开放基金厦门大学(200906)~~
关键词
氧化钨
复合
氧化锌
光催化
酸性橙II
tungsten oxide
coupling
zinc oxide
photocatalysis
acid orange II
作者简介
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