Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity ar...Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.展开更多
Three-dimensional(3D)graphene monoliths are a new carbon material,that has tremendous potential in the fields of energy conversion and storage.They can solve the limitations of two-dimensional(2D)graphene sheets,inclu...Three-dimensional(3D)graphene monoliths are a new carbon material,that has tremendous potential in the fields of energy conversion and storage.They can solve the limitations of two-dimensional(2D)graphene sheets,including interlayer restacking,high contact resistance,and insufficient pore accessibility.By constructing interconnected porous networks,3D graphenes not only retain the intrinsic advantages of 2D graphene sheets,such as high specific surface area,excellent electrical and thermal conductivities,good mechanical properties,and outstanding chemical stability,but also enable efficient mass transport of external fluid species.We summarize the fabrication methods for 3D graphenes,with a particular focus on their applications in energy-related systems.Techniques including chemical reduction assembly,chemical vapor deposition,3D printing,chemical blowing,and zinc-tiered pyrolysis have been developed to change their pore structure and elemental composition,and ways in which they can be integrated with functional components.In terms of energy conversion and storage,they have found broad use in buffering mechanical impacts,suppressing noise,photothermal conversion,electromagnetic shielding and absorption.They have also been used in electrochemical energy systems such as supercapacitors,secondary batteries,and electrocatalysis.By reviewing recent progress in structural design and new applications,we also discuss the problems these materials face,including scalable fabrication and precise pore structure control,and possible new applications.展开更多
Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surf...Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surface area,and less active sites limits its solar energy utilization.Hydrothermal method was utilized to synthesize the bimetallic material of Cu_(x)Co_(1-x)in this work.Co was loaded onto the Cu surface due to the electrons generated by the surface plasmon resonance(SPR)effect occurring on the Cu surface.Cu_(x)Co_(1-x)exhibits high photocatalytic conversion of CO_(2)efficiency under irradiation,which mainly because the Co nanoparticles on the surface of Cu can be used as cocatalysts to enhance the photocharge transfer.Cu_(0.6)Co_(0.4)exhibits the comparatively best photocatalytic conversion efficiency of CO_(2)in the first 6 h light irradiation.The yields of CO and CH_(4)reached 35.26 and 2.71μmol/(g·h),respectively.Upon illumination,electrons were produced,with the majority of them moving towards the interface.This movement contributes to the increased lifetime of photogenerated electron-hole pairs,which in turn boosts the photocatalytic efficiency.The findings of this research provide significant insights for creating photocatalysts that are both highly effective and stable in CO_(2)reduction processes.展开更多
Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the...Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the requirements for applications in emerging fields such as renewable energy and electric vehicles due to limitations including a disordered structure and uncontrolled defects.With an aim of realizing devisable structures,adjustable functions,and performance breakthroughs,superstructured carbons is proposed and represent a category of carbon-based materials,characterized by precisely-built pores,networks,and interfaces.Superstructured carbons can overcome the limitations of traditional carbon materials and improve the performance of energy storage and conversion devices.We review the structure-activity relationships of superstructured carbons and recent research advances from three aspects including a precisely customized pore structure,a dense carbon network framework,and a multi-component highly coupled interface between the different components.Finally,we provide an outlook on the future development of and practical challenges in energy storage and conversion devices.展开更多
In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidati...In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidation methods such as ozonation system are used to manage MnS_(2)O_(6)in the leaching solution,replacing conventional methods.To ascertain the conversion rate and kinetics of MnS_(2)O_(6)during the ozonation process,we explored the factors influencing its removal rate,including ozone dosage,manganese dithionate concentration,sulfuric acid concentration,and reaction temperature.Batch experiments were conducted to determine the reaction rate constant of ozone(k)and activation energy(Ea)obtained from intermittent experimental data fitting,revealing a least-squares exponential conversion relationship between k and the MnS_(2)O_(6)removal amount,wherein an increase in the aforementioned factors led to an enhanced MnS_(2)O_(6)conversion rate,exceeding 99.3%.The formation mechanism of the ozone products proposed during the experiment was summarized and proposed as follows:1)Mn^(2+)was directly oxidized to MnO_(2),and 2)SO_(4)2−was obtained by the catalytic oxidation of S_(2)O_(6)^(2−)with HO•from O3 decomposition.According to the kinetics analysis,the pre-exponential factor and total activation energy of the ozonation kinetics equation were 1.0×10^(23) s^(−1) and 177.28 kJ/mol,respectively.Overall,the present study demonstrates that O_(3) as an oxidizing agent can effectively facilitate MnS_(2)O_(6)disproportionation while preventing the release of the secondary pollutant,SO_(2)gas.展开更多
Light conversion agents Eul-xLx（TTA）3Phen (L denotes (La3+, Gd3+, Y3+)) complexes were prepared, and the influence of doping ions on fluorescence properties was investigated by elementary analysis, FTIR and fluoresc...Light conversion agents Eul-xLx（TTA）3Phen (L denotes (La3+, Gd3+, Y3+)) complexes were prepared, and the influence of doping ions on fluorescence properties was investigated by elementary analysis, FTIR and fluorescent spectra. The results show that FTIR spectra of Eul-xLx（TTA）3Phen complex system are identical with that of EuTTA3Phen, which indicates that the complexes (Eul-xLx（TTA）3Phen) are similar in structure to （Eu （TTA）3Phen.） For the above doping elements, co-fluorescence enhancement has the following order: Gd3+>Y3+>La3+, and the optimum mole fractions of doping elements are 0.4, 0.2 and 0.5 respectively for Gd3+, Y3+, La3+. Among all the complexes, Eu0.6Gd0.4（TTA）3Phen complex has the strongest fluorescent intensity. Applying Eu0.6Gd0.4（TTA）3Phen complex to plastic and printing inks, bright red fluorescence plastic and printing inks are obtained when the content of europium reaches 0.1%（mass fraction）.展开更多
The interrupted sampling repeater jamming（ISRJ） is an effective deception jamming method for coherent radar, especially for the wideband linear frequency modulation（LFM） radar. An electronic counter-countermeasure...The interrupted sampling repeater jamming（ISRJ） is an effective deception jamming method for coherent radar, especially for the wideband linear frequency modulation（LFM） radar. An electronic counter-countermeasure（ECCM） scheme is proposed to remove the ISRJ-based false targets from the pulse compression result of the de-chirping radar. Through the time-frequency（TF） analysis of the radar echo signal, it can be found that the TF characteristics of the ISRJ signal are discontinuous in the pulse duration because the ISRJ jammer needs short durations to receive the radar signal. Based on the discontinuous characteristics a particular band-pass filter can be generated by two alternative approaches to retain the true target signal and suppress the ISRJ signal. The simulation results prove the validity of the proposed ECCM scheme for the ISRJ.展开更多
A localized parametric time-sheared Gabor atom is derived by convolving a linear frequency modulated factor, modulating in frequency and translating in time to a dilated Gaussian function, which is the generalization ...A localized parametric time-sheared Gabor atom is derived by convolving a linear frequency modulated factor, modulating in frequency and translating in time to a dilated Gaussian function, which is the generalization of Gabor atom and is more delicate for matching most of the signals encountered in practice, especially for those having frequency dispersion characteristics. The time-frequency distribution of this atom concentrates in its time center and frequency center along energy curve, with the curve being oblique to a certain extent along the time axis. A novel parametric adaptive time-frequency distribution based on a set of the derived atoms is then proposed using a adaptive signal subspace decomposition method in frequency domain, which is non-negative time-frequency energy distribution and free of cross-term interference for multicomponent signals. The results of numerical simulation manifest the effectiveness of the approach in time-frequency representation and signal de-noising processing.展开更多
The cerium conversion film was applied to improving the corrosion resistance of Mg-Gd-Y-Zr magnesium alloy. The film was electrodeposited on the surface of the Mg-RE alloy in cerium nitrate solution. The compositions ...The cerium conversion film was applied to improving the corrosion resistance of Mg-Gd-Y-Zr magnesium alloy. The film was electrodeposited on the surface of the Mg-RE alloy in cerium nitrate solution. The compositions and morphologies were analyzed by X-ray diffraction(XRD), scanning election microscopy (SEM). The corrosion behaviors of the film were investigated electrochemical impedance spectroscopy (EIS), potentiodynamic polarization tests and immersion tests. The results show that the optimum parameters for electrochemical deposition are as follows: pH 10.0, time 30 min, 50 mmol/L Na2CO3 and temperature 25 ℃ by the designed experiments according to the orthogonal table L(9, 34). The corrosion protection efficiency is dependent on the deposition parameters. The cerium conversion film shows better corrosion protection behavior than chromate conversion film on Mg-Gd-Y-Zr magnesium alloy.展开更多
This paper considers the problem of target and jamming recognition for the pulse Doppler radar fuze(PDRF).To solve the problem,the matched filter outputs of the PDRF under the action of target and jamming are analyzed...This paper considers the problem of target and jamming recognition for the pulse Doppler radar fuze(PDRF).To solve the problem,the matched filter outputs of the PDRF under the action of target and jamming are analyzed.Then,the frequency entropy and peak-to-peak ratio are extracted from the matched filter output of the PDRF,and the time-frequency joint feature is constructed.Based on the time-frequency joint feature,the naive Bayesian classifier(NBC)with minimal risk is established for target and jamming recognition.To improve the adaptability of the proposed method in complex environments,an online update process that adaptively modifies the classifier in the duration of the work of the PDRF is proposed.The experiments show that the PDRF can maintain high recognition accuracy when the signal-to-noise ratio(SNR)decreases and the jamming-to-signal ratio(JSR)increases.Moreover,the applicable analysis shows that he ONBCMR method has low computational complexity and can fully meet the real-time requirements of PDRF.展开更多
A new method creating depth information for 2D/3D conversion was proposed. The distance between objects is determined by the distances between objects and light source position which is estimated by the analysis of th...A new method creating depth information for 2D/3D conversion was proposed. The distance between objects is determined by the distances between objects and light source position which is estimated by the analysis of the image. The estimated lighting value is used to normalize the image. A threshold value is determined by some weighted operation between the original image and the normalized image. By applying the threshold value to the original image, background area is removed. Depth information of interested area is calculated from the lighting changes. The final 3D images converted with the proposed method are used to verify its effectiveness.展开更多
A new pathway of gas-to-liquid conversion, directly from methane and carbon dioxide, was established recently using a catalytic dielectric-barrier discharge (DBD) with zeolite. Direct fuel synthesis becomes possible a...A new pathway of gas-to-liquid conversion, directly from methane and carbon dioxide, was established recently using a catalytic dielectric-barrier discharge (DBD) with zeolite. Direct fuel synthesis becomes possible at reaction conditions close to ambient ones. The products from such direct fuel synthesis include alkanes, alkenes, oxygenates and Syngas (CO + H2). The product distribution is similar to that from Fischer-Tropsch(F-T) synthesis but it does not follow the Flory-Schulz kinetics. The presence of zealots within discharge plasmas improves the selectivity of lighter hydrocarbons.展开更多
The idea of Ku-band transceiver frequency conversion module design based on 3D micropackaging technology is proposed. By using the double frequency conversion technology,the dual transceiver circuit from Ku-band to L-...The idea of Ku-band transceiver frequency conversion module design based on 3D micropackaging technology is proposed. By using the double frequency conversion technology,the dual transceiver circuit from Ku-band to L-band is realized by combining with the local oscillator and the power control circuit to complete functions such as amplification, filtering and gain. In order to achieve the performance optimization and a high level of integration of the Ku-band monolithic microwave integrated circuits(MMIC) operating chip, the 3 D vertical interconnection micro-assembly technology is used. By stacking solder balls on the printed circuit board(PCB), the technology decreases the volume of the original transceiver to a miniaturized module. The module has a good electromagnetic compatibility through special structure designs. This module has the characteristics of miniaturization, low power consumption and high density, which is suitable for popularization in practical application.展开更多
Multi-radar signal separation is a critical process in modern reconnaissance systems. However, the complicated battlefield is typically confronted with increasing electronic equipment and complex radar waveforms. The ...Multi-radar signal separation is a critical process in modern reconnaissance systems. However, the complicated battlefield is typically confronted with increasing electronic equipment and complex radar waveforms. The intercepted signal is difficult to separate with conventional parameters because of severe overlapping in both time and frequency domains. On the contrary, time-frequency analysis maps the 1D signal into a 2D time-frequency plane, which provides a better insight into the signal than traditional methods. Particularly, the parameterized time-frequency analysis (PTFA) shows great potential in processing such non stationary signals. Five procedures for the PTFA are proposed to separate the overlapped multi-radar signal, including initiation, instantaneous frequency estimation with PTFA, signal demodulation, signal separation with adaptive filter and signal recovery. The proposed method is verified with both simulated and real signals, which shows good performance in the application on multi-radar signal separation.展开更多
This paper deals with the blind separation of nonstation-ary sources and direction-of-arrival （DOA） estimation in the under-determined case, when there are more sources than sensors. We assume the sources to be time...This paper deals with the blind separation of nonstation-ary sources and direction-of-arrival （DOA） estimation in the under-determined case, when there are more sources than sensors. We assume the sources to be time-frequency （TF） disjoint to a certain extent. In particular, the number of sources presented at any TF neighborhood is strictly less than that of sensors. We can identify the real number of active sources and achieve separation in any TF neighborhood by the sparse representation method. Compared with the subspace-based algorithm under the same sparseness assumption, which suffers from the extra noise effect since it can-not estimate the true number of active sources, the proposed algorithm can estimate the number of active sources and their cor-responding TF values in any TF neighborhood simultaneously. An-other contribution of this paper is a new estimation procedure for the DOA of sources in the underdetermined case, which combines the TF sparseness of sources and the clustering technique. Sim-ulation results demonstrate the validity and high performance of the proposed algorithm in both blind source separation （BSS） and DOA estimation.展开更多
Recent advances in electronics have increased the complexity of radar signal modulation.The quasi-linear frequency modulation(quasi-LFM)radar waveforms(LFM,Frank code,P1−P4 code)have similar time-frequency distributio...Recent advances in electronics have increased the complexity of radar signal modulation.The quasi-linear frequency modulation(quasi-LFM)radar waveforms(LFM,Frank code,P1−P4 code)have similar time-frequency distributions,and it is difficult to identify such signals using traditional time-frequency analysis methods.To solve this problem,this paper proposes an algorithm for automatic recognition of quasi-LFM radar waveforms based on fractional Fourier transform and time-frequency analysis.First of all,fractional Fourier transform and the Wigner-Ville distribution(WVD)are used to determine the number of main ridgelines and the tilt angle of the target component in WVD.Next,the standard deviation of the target component's width in the signal's WVD is calculated.Finally,an assembled classifier using neural network is built to recognize different waveforms by automatically combining the three features.Simulation results show that the overall recognition rate of the proposed algorithm reaches 94.17%under 0 dB.When the training data set and the test data set are mixed with noise,the recognition rate reaches 89.93%.The best recognition accuracy is achieved when the size of the training set is taken as 400.The algorithm complexity can meet the requirements of real-time recognition.展开更多
This paper proposes a scheme to construct time- frequency codes based on protograph low density parity check （LDPC） codes in orthogonal frequency division multiplexing （OFDM） communication systems. This approach s...This paper proposes a scheme to construct time- frequency codes based on protograph low density parity check （LDPC） codes in orthogonal frequency division multiplexing （OFDM） communication systems. This approach synthesizes two techniques： protograph LDPC codes and OFDM. One symbol of encoded information by protograph LDPC codes corresponds to one sub-carrier, namely the length of encoded information equals to the number of sub-carriers. The design of good protograph LDPC codes with short lengths is given, and the proposed proto- graph LDPC codes can be of fast encoding, which can reduce the encoding complexity and simplify encoder hardware implementa- tion. The proposed approach provides a higher coding gain in the Rayleigh fading channel. The simulation results in the Rayleigh fading channel show that the bit error rate （BER） performance of the proposed time-frequency codes is as good as random LDPC- OFDM codes and is better than Tanner LDPC-OFDM codes under the condition of different fading coefficients.展开更多
As an important application research topic of the intelligent aviation multi-station, collaborative detecting must overcome the problem of scouting measurement with status of 'fragmentation', and the NP-hardne...As an important application research topic of the intelligent aviation multi-station, collaborative detecting must overcome the problem of scouting measurement with status of 'fragmentation', and the NP-hardness problem of matching association between target and measurement in the process of scouting to data-link, which has complicated technical architecture of network construction. In this paper, taking advantage of cooperation mechanism on signal level in the aviation multi-station sympathetic network, a method of obtaining target time difference of arrival (TDOA) measurement using multi-station collaborative detecting based on time-frequency association is proposed. The method can not only achieve matching between target and its measurement, but also obtain TDOA measurement by further evolutionary transaction through refreshing sequential pulse time of arrival (TOA) measurement matrix for matching and correlating. Simulation results show that the accuracy of TDOA measurement has significant superiority over TOA, and detection probability of false TDOA measurement introduced by noise and fake measurement can be reduced effectively.展开更多
Producing methanol from coke oven gas(COG) is one of the important applications of COG. Removal of sulfur from COG is a key step of this process. Conversion and reaction kinetics over a commercial Fe-Mo/Al2O3 catalyst...Producing methanol from coke oven gas(COG) is one of the important applications of COG. Removal of sulfur from COG is a key step of this process. Conversion and reaction kinetics over a commercial Fe-Mo/Al2O3 catalyst(T-202) were studied in a continuous flow fixed bed reactor under pressures of 1.6-2.8 MPa, space time of 1.32-3.55 s and temperatures of 240-360 °C. Though the COG contains about 0.6 mol/mol H2, hydrogenation of CO and CO2 is not significant on this catalyst. The conversions of unsaturated hydrocarbons depend on their molecular structures. Diolefins and alkynes can be completely hydrogenated even at relatively low temperature and pressure. Olefins, in contrast, can only be progressively hydrogenated with increasing temperature and pressure. The hydrodesulfurization(HDS) of CS2 on this catalyst is easy. Complete conversion of CS2 was observed in the whole range of the conditions used in this work. The original COS in the COG can also be easily converted to a low level. However, its complete HDS is difficult due to the relatively high concentration of CO in the COG and due to the limitation of thermodynamics. H2 S can react with unsaturated hydrocarbons to form ethyl mercaptan and thiophene, which are then progressively hydrodesulfurized with increasing temperature and pressure. Based on the experimental observations, reaction kinetic models for the conversion of ethylene and sulfur-containing compounds were proposed; the values of the parameters in the models were obtained by regression of the experimental data.展开更多
This paper proposes a new method for estimating the parameter of maneuvering targets based on sparse time-frequency transform in over-the-horizon radar（OTHR）. In this method, the sparse time-frequency distribution o...This paper proposes a new method for estimating the parameter of maneuvering targets based on sparse time-frequency transform in over-the-horizon radar（OTHR）. In this method, the sparse time-frequency distribution of the radar echo is obtained by solving a sparse optimization problem based on the short-time Fourier transform. Then Hough transform is employed to estimate the parameter of the targets. The proposed algorithm has the following advantages： Compared with the Wigner-Hough transform method, the computational complexity of the sparse optimization is low due to the application of fast Fourier transform（FFT）. And the computational cost of Hough transform is also greatly reduced because of the sparsity of the time-frequency distribution. Compared with the high order ambiguity function（HAF） method, the proposed method improves in terms of precision and robustness to noise. Simulation results show that compared with the HAF method, the required SNR and relative mean square error are 8 dB lower and 50 dB lower respectively in the proposed method. While processing the field experiment data, the execution time of Hough transform in the proposed method is only 4% of the Wigner-Hough transform method.展开更多
基金西南大学中央高校基本科研业务费项目(SWU-KT22030)重庆市教育委员会科学技术研究项目(KJQN202300205)Deutsche Forschungsgemeinschaft(DFG,German Research Foundation,457444676).
文摘Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.
基金supported by National Natural Science Foundation of China(52272039,U23B2075,51972168)Key Research and Development Program in Jiangsu Province(BE2023085)Natural Science Foundation of Jiangsu Province of China(BK20231406)。
文摘Three-dimensional(3D)graphene monoliths are a new carbon material,that has tremendous potential in the fields of energy conversion and storage.They can solve the limitations of two-dimensional(2D)graphene sheets,including interlayer restacking,high contact resistance,and insufficient pore accessibility.By constructing interconnected porous networks,3D graphenes not only retain the intrinsic advantages of 2D graphene sheets,such as high specific surface area,excellent electrical and thermal conductivities,good mechanical properties,and outstanding chemical stability,but also enable efficient mass transport of external fluid species.We summarize the fabrication methods for 3D graphenes,with a particular focus on their applications in energy-related systems.Techniques including chemical reduction assembly,chemical vapor deposition,3D printing,chemical blowing,and zinc-tiered pyrolysis have been developed to change their pore structure and elemental composition,and ways in which they can be integrated with functional components.In terms of energy conversion and storage,they have found broad use in buffering mechanical impacts,suppressing noise,photothermal conversion,electromagnetic shielding and absorption.They have also been used in electrochemical energy systems such as supercapacitors,secondary batteries,and electrocatalysis.By reviewing recent progress in structural design and new applications,we also discuss the problems these materials face,including scalable fabrication and precise pore structure control,and possible new applications.
基金supported by the Doctoral Research Start-up Project of Yuncheng University(YQ-2023067)Project of Shanxi Natural Science Foundation(202303021211189)+2 种基金Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Provinces(20220036)Shanxi Province Intelligent Optoelectronic Sensing Application Technology Innovation CenterShanxi Province Optoelectronic Information Science and Technology Laboratory,Yuncheng University。
文摘Metal nanoparticles with high surface area and high electrochemical activity exhibit excellent catalytic performance in the photocatalytic reduction of carbon dioxide(CO_(2)).However,poor stability,small specific surface area,and less active sites limits its solar energy utilization.Hydrothermal method was utilized to synthesize the bimetallic material of Cu_(x)Co_(1-x)in this work.Co was loaded onto the Cu surface due to the electrons generated by the surface plasmon resonance(SPR)effect occurring on the Cu surface.Cu_(x)Co_(1-x)exhibits high photocatalytic conversion of CO_(2)efficiency under irradiation,which mainly because the Co nanoparticles on the surface of Cu can be used as cocatalysts to enhance the photocharge transfer.Cu_(0.6)Co_(0.4)exhibits the comparatively best photocatalytic conversion efficiency of CO_(2)in the first 6 h light irradiation.The yields of CO and CH_(4)reached 35.26 and 2.71μmol/(g·h),respectively.Upon illumination,electrons were produced,with the majority of them moving towards the interface.This movement contributes to the increased lifetime of photogenerated electron-hole pairs,which in turn boosts the photocatalytic efficiency.The findings of this research provide significant insights for creating photocatalysts that are both highly effective and stable in CO_(2)reduction processes.
文摘Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the requirements for applications in emerging fields such as renewable energy and electric vehicles due to limitations including a disordered structure and uncontrolled defects.With an aim of realizing devisable structures,adjustable functions,and performance breakthroughs,superstructured carbons is proposed and represent a category of carbon-based materials,characterized by precisely-built pores,networks,and interfaces.Superstructured carbons can overcome the limitations of traditional carbon materials and improve the performance of energy storage and conversion devices.We review the structure-activity relationships of superstructured carbons and recent research advances from three aspects including a precisely customized pore structure,a dense carbon network framework,and a multi-component highly coupled interface between the different components.Finally,we provide an outlook on the future development of and practical challenges in energy storage and conversion devices.
基金Project(2022M710619)supported by the Postdoctoral Science Foundation of ChinaProjects(2020YFH0213,2020YFG0039)supported by the Sichuan Science and Technology Program,China+1 种基金Projects(XJ2024001501,KCXTD2023-4)supported by the Basic Scientific Foundation and Innovation Team Funds of China West Normal UniversityProject(CSPC202403)supported by the Open Project Program of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,China。
文摘In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidation methods such as ozonation system are used to manage MnS_(2)O_(6)in the leaching solution,replacing conventional methods.To ascertain the conversion rate and kinetics of MnS_(2)O_(6)during the ozonation process,we explored the factors influencing its removal rate,including ozone dosage,manganese dithionate concentration,sulfuric acid concentration,and reaction temperature.Batch experiments were conducted to determine the reaction rate constant of ozone(k)and activation energy(Ea)obtained from intermittent experimental data fitting,revealing a least-squares exponential conversion relationship between k and the MnS_(2)O_(6)removal amount,wherein an increase in the aforementioned factors led to an enhanced MnS_(2)O_(6)conversion rate,exceeding 99.3%.The formation mechanism of the ozone products proposed during the experiment was summarized and proposed as follows:1)Mn^(2+)was directly oxidized to MnO_(2),and 2)SO_(4)2−was obtained by the catalytic oxidation of S_(2)O_(6)^(2−)with HO•from O3 decomposition.According to the kinetics analysis,the pre-exponential factor and total activation energy of the ozonation kinetics equation were 1.0×10^(23) s^(−1) and 177.28 kJ/mol,respectively.Overall,the present study demonstrates that O_(3) as an oxidizing agent can effectively facilitate MnS_(2)O_(6)disproportionation while preventing the release of the secondary pollutant,SO_(2)gas.
文摘Light conversion agents Eul-xLx（TTA）3Phen (L denotes (La3+, Gd3+, Y3+)) complexes were prepared, and the influence of doping ions on fluorescence properties was investigated by elementary analysis, FTIR and fluorescent spectra. The results show that FTIR spectra of Eul-xLx（TTA）3Phen complex system are identical with that of EuTTA3Phen, which indicates that the complexes (Eul-xLx（TTA）3Phen) are similar in structure to （Eu （TTA）3Phen.） For the above doping elements, co-fluorescence enhancement has the following order: Gd3+>Y3+>La3+, and the optimum mole fractions of doping elements are 0.4, 0.2 and 0.5 respectively for Gd3+, Y3+, La3+. Among all the complexes, Eu0.6Gd0.4（TTA）3Phen complex has the strongest fluorescent intensity. Applying Eu0.6Gd0.4（TTA）3Phen complex to plastic and printing inks, bright red fluorescence plastic and printing inks are obtained when the content of europium reaches 0.1%（mass fraction）.
基金supported by the National Natural Science Foundation of China(61271442)
文摘The interrupted sampling repeater jamming（ISRJ） is an effective deception jamming method for coherent radar, especially for the wideband linear frequency modulation（LFM） radar. An electronic counter-countermeasure（ECCM） scheme is proposed to remove the ISRJ-based false targets from the pulse compression result of the de-chirping radar. Through the time-frequency（TF） analysis of the radar echo signal, it can be found that the TF characteristics of the ISRJ signal are discontinuous in the pulse duration because the ISRJ jammer needs short durations to receive the radar signal. Based on the discontinuous characteristics a particular band-pass filter can be generated by two alternative approaches to retain the true target signal and suppress the ISRJ signal. The simulation results prove the validity of the proposed ECCM scheme for the ISRJ.
基金This project was supported by the National Natural Science Foundation of China (60472102)Shanghai Leading Academic Discipline Project (T0103).
文摘A localized parametric time-sheared Gabor atom is derived by convolving a linear frequency modulated factor, modulating in frequency and translating in time to a dilated Gaussian function, which is the generalization of Gabor atom and is more delicate for matching most of the signals encountered in practice, especially for those having frequency dispersion characteristics. The time-frequency distribution of this atom concentrates in its time center and frequency center along energy curve, with the curve being oblique to a certain extent along the time axis. A novel parametric adaptive time-frequency distribution based on a set of the derived atoms is then proposed using a adaptive signal subspace decomposition method in frequency domain, which is non-negative time-frequency energy distribution and free of cross-term interference for multicomponent signals. The results of numerical simulation manifest the effectiveness of the approach in time-frequency representation and signal de-noising processing.
基金Project (5133001E) supported by the Major State Basic Research and Development Program of China
文摘The cerium conversion film was applied to improving the corrosion resistance of Mg-Gd-Y-Zr magnesium alloy. The film was electrodeposited on the surface of the Mg-RE alloy in cerium nitrate solution. The compositions and morphologies were analyzed by X-ray diffraction(XRD), scanning election microscopy (SEM). The corrosion behaviors of the film were investigated electrochemical impedance spectroscopy (EIS), potentiodynamic polarization tests and immersion tests. The results show that the optimum parameters for electrochemical deposition are as follows: pH 10.0, time 30 min, 50 mmol/L Na2CO3 and temperature 25 ℃ by the designed experiments according to the orthogonal table L(9, 34). The corrosion protection efficiency is dependent on the deposition parameters. The cerium conversion film shows better corrosion protection behavior than chromate conversion film on Mg-Gd-Y-Zr magnesium alloy.
基金supported by the National Natural Science Foundation of China(Grant No.61973037 and No.61673066).
文摘This paper considers the problem of target and jamming recognition for the pulse Doppler radar fuze(PDRF).To solve the problem,the matched filter outputs of the PDRF under the action of target and jamming are analyzed.Then,the frequency entropy and peak-to-peak ratio are extracted from the matched filter output of the PDRF,and the time-frequency joint feature is constructed.Based on the time-frequency joint feature,the naive Bayesian classifier(NBC)with minimal risk is established for target and jamming recognition.To improve the adaptability of the proposed method in complex environments,an online update process that adaptively modifies the classifier in the duration of the work of the PDRF is proposed.The experiments show that the PDRF can maintain high recognition accuracy when the signal-to-noise ratio(SNR)decreases and the jamming-to-signal ratio(JSR)increases.Moreover,the applicable analysis shows that he ONBCMR method has low computational complexity and can fully meet the real-time requirements of PDRF.
文摘A new method creating depth information for 2D/3D conversion was proposed. The distance between objects is determined by the distances between objects and light source position which is estimated by the analysis of the image. The estimated lighting value is used to normalize the image. A threshold value is determined by some weighted operation between the original image and the normalized image. By applying the threshold value to the original image, background area is removed. Depth information of interested area is calculated from the lighting changes. The final 3D images converted with the proposed method are used to verify its effectiveness.
基金Supported by the National Nadural Science Foudation of Chinaand Ministry of Science and Technology of China, ABBCorporate R
文摘A new pathway of gas-to-liquid conversion, directly from methane and carbon dioxide, was established recently using a catalytic dielectric-barrier discharge (DBD) with zeolite. Direct fuel synthesis becomes possible at reaction conditions close to ambient ones. The products from such direct fuel synthesis include alkanes, alkenes, oxygenates and Syngas (CO + H2). The product distribution is similar to that from Fischer-Tropsch(F-T) synthesis but it does not follow the Flory-Schulz kinetics. The presence of zealots within discharge plasmas improves the selectivity of lighter hydrocarbons.
文摘The idea of Ku-band transceiver frequency conversion module design based on 3D micropackaging technology is proposed. By using the double frequency conversion technology,the dual transceiver circuit from Ku-band to L-band is realized by combining with the local oscillator and the power control circuit to complete functions such as amplification, filtering and gain. In order to achieve the performance optimization and a high level of integration of the Ku-band monolithic microwave integrated circuits(MMIC) operating chip, the 3 D vertical interconnection micro-assembly technology is used. By stacking solder balls on the printed circuit board(PCB), the technology decreases the volume of the original transceiver to a miniaturized module. The module has a good electromagnetic compatibility through special structure designs. This module has the characteristics of miniaturization, low power consumption and high density, which is suitable for popularization in practical application.
文摘Multi-radar signal separation is a critical process in modern reconnaissance systems. However, the complicated battlefield is typically confronted with increasing electronic equipment and complex radar waveforms. The intercepted signal is difficult to separate with conventional parameters because of severe overlapping in both time and frequency domains. On the contrary, time-frequency analysis maps the 1D signal into a 2D time-frequency plane, which provides a better insight into the signal than traditional methods. Particularly, the parameterized time-frequency analysis (PTFA) shows great potential in processing such non stationary signals. Five procedures for the PTFA are proposed to separate the overlapped multi-radar signal, including initiation, instantaneous frequency estimation with PTFA, signal demodulation, signal separation with adaptive filter and signal recovery. The proposed method is verified with both simulated and real signals, which shows good performance in the application on multi-radar signal separation.
基金supported by the National Natural Science Foundation of China(61072120)
文摘This paper deals with the blind separation of nonstation-ary sources and direction-of-arrival （DOA） estimation in the under-determined case, when there are more sources than sensors. We assume the sources to be time-frequency （TF） disjoint to a certain extent. In particular, the number of sources presented at any TF neighborhood is strictly less than that of sensors. We can identify the real number of active sources and achieve separation in any TF neighborhood by the sparse representation method. Compared with the subspace-based algorithm under the same sparseness assumption, which suffers from the extra noise effect since it can-not estimate the true number of active sources, the proposed algorithm can estimate the number of active sources and their cor-responding TF values in any TF neighborhood simultaneously. An-other contribution of this paper is a new estimation procedure for the DOA of sources in the underdetermined case, which combines the TF sparseness of sources and the clustering technique. Sim-ulation results demonstrate the validity and high performance of the proposed algorithm in both blind source separation （BSS） and DOA estimation.
基金This work was supported by the National Natural Science Foundation of China(91538201)the Taishan Scholar Project of Shandong Province(ts201511020)the project supported by Chinese National Key Laboratory of Science and Technology on Information System Security(6142111190404).
文摘Recent advances in electronics have increased the complexity of radar signal modulation.The quasi-linear frequency modulation(quasi-LFM)radar waveforms(LFM,Frank code,P1−P4 code)have similar time-frequency distributions,and it is difficult to identify such signals using traditional time-frequency analysis methods.To solve this problem,this paper proposes an algorithm for automatic recognition of quasi-LFM radar waveforms based on fractional Fourier transform and time-frequency analysis.First of all,fractional Fourier transform and the Wigner-Ville distribution(WVD)are used to determine the number of main ridgelines and the tilt angle of the target component in WVD.Next,the standard deviation of the target component's width in the signal's WVD is calculated.Finally,an assembled classifier using neural network is built to recognize different waveforms by automatically combining the three features.Simulation results show that the overall recognition rate of the proposed algorithm reaches 94.17%under 0 dB.When the training data set and the test data set are mixed with noise,the recognition rate reaches 89.93%.The best recognition accuracy is achieved when the size of the training set is taken as 400.The algorithm complexity can meet the requirements of real-time recognition.
基金supported by the Beijing Natural Science Foundation of China (4102050)the National Natural Science of Foundation of China (NSFC)-Korea Science and Engineering Foundation (KOSF) Joint Research Project of China and Korea (60811140343)
文摘This paper proposes a scheme to construct time- frequency codes based on protograph low density parity check （LDPC） codes in orthogonal frequency division multiplexing （OFDM） communication systems. This approach synthesizes two techniques： protograph LDPC codes and OFDM. One symbol of encoded information by protograph LDPC codes corresponds to one sub-carrier, namely the length of encoded information equals to the number of sub-carriers. The design of good protograph LDPC codes with short lengths is given, and the proposed proto- graph LDPC codes can be of fast encoding, which can reduce the encoding complexity and simplify encoder hardware implementa- tion. The proposed approach provides a higher coding gain in the Rayleigh fading channel. The simulation results in the Rayleigh fading channel show that the bit error rate （BER） performance of the proposed time-frequency codes is as good as random LDPC- OFDM codes and is better than Tanner LDPC-OFDM codes under the condition of different fading coefficients.
基金supported by the National Natural Science Foundation of China(61472443)the Basic Research Priorities Program of Shaanxi Province Natural Science Foundation of China(2013JQ8042)
文摘As an important application research topic of the intelligent aviation multi-station, collaborative detecting must overcome the problem of scouting measurement with status of 'fragmentation', and the NP-hardness problem of matching association between target and measurement in the process of scouting to data-link, which has complicated technical architecture of network construction. In this paper, taking advantage of cooperation mechanism on signal level in the aviation multi-station sympathetic network, a method of obtaining target time difference of arrival (TDOA) measurement using multi-station collaborative detecting based on time-frequency association is proposed. The method can not only achieve matching between target and its measurement, but also obtain TDOA measurement by further evolutionary transaction through refreshing sequential pulse time of arrival (TOA) measurement matrix for matching and correlating. Simulation results show that the accuracy of TDOA measurement has significant superiority over TOA, and detection probability of false TDOA measurement introduced by noise and fake measurement can be reduced effectively.
文摘Producing methanol from coke oven gas(COG) is one of the important applications of COG. Removal of sulfur from COG is a key step of this process. Conversion and reaction kinetics over a commercial Fe-Mo/Al2O3 catalyst(T-202) were studied in a continuous flow fixed bed reactor under pressures of 1.6-2.8 MPa, space time of 1.32-3.55 s and temperatures of 240-360 °C. Though the COG contains about 0.6 mol/mol H2, hydrogenation of CO and CO2 is not significant on this catalyst. The conversions of unsaturated hydrocarbons depend on their molecular structures. Diolefins and alkynes can be completely hydrogenated even at relatively low temperature and pressure. Olefins, in contrast, can only be progressively hydrogenated with increasing temperature and pressure. The hydrodesulfurization(HDS) of CS2 on this catalyst is easy. Complete conversion of CS2 was observed in the whole range of the conditions used in this work. The original COS in the COG can also be easily converted to a low level. However, its complete HDS is difficult due to the relatively high concentration of CO in the COG and due to the limitation of thermodynamics. H2 S can react with unsaturated hydrocarbons to form ethyl mercaptan and thiophene, which are then progressively hydrodesulfurized with increasing temperature and pressure. Based on the experimental observations, reaction kinetic models for the conversion of ethylene and sulfur-containing compounds were proposed; the values of the parameters in the models were obtained by regression of the experimental data.
基金supported by the National Natural Science Foundation of China(611011726137118461301262)
文摘This paper proposes a new method for estimating the parameter of maneuvering targets based on sparse time-frequency transform in over-the-horizon radar（OTHR）. In this method, the sparse time-frequency distribution of the radar echo is obtained by solving a sparse optimization problem based on the short-time Fourier transform. Then Hough transform is employed to estimate the parameter of the targets. The proposed algorithm has the following advantages： Compared with the Wigner-Hough transform method, the computational complexity of the sparse optimization is low due to the application of fast Fourier transform（FFT）. And the computational cost of Hough transform is also greatly reduced because of the sparsity of the time-frequency distribution. Compared with the high order ambiguity function（HAF） method, the proposed method improves in terms of precision and robustness to noise. Simulation results show that compared with the HAF method, the required SNR and relative mean square error are 8 dB lower and 50 dB lower respectively in the proposed method. While processing the field experiment data, the execution time of Hough transform in the proposed method is only 4% of the Wigner-Hough transform method.
