摘要
Inconel 740H是应用于先进超超临界火电机组的最佳候选材料之一,进一步提高其焊接接头的力学性能不仅有利于火电厂的安全运行,还能显著提高经济性。本工作采用OM、SEM和TEM系统地研究了Inconel 740H焊接接头不同温度蠕变后γ′贫化区的形成机理,并分析了其对力学性能的影响。结果表明,焊后热处理过程中小尺寸棒状γ′相仅在焊缝组织的晶界上不连续析出。不同温度蠕变后,焊缝内晶界比母材更早形成粗大棒状γ′相和γ′贫化区。其中,母材内晶界处粗大棒状γ′相的形成是由其晶界附近颗粒状γ′相的不连续粗化所致,而焊缝内晶界处粗大棒状γ′相的形成是由其晶界处不连续析出的棒状γ′相和晶界附近颗粒状γ′相2者的不连续粗化所致。晶界棒状γ′相的不连续粗化和M_(23)C_(6)相的析出导致晶界处形成γ′贫化区。700~800℃范围内,随蠕变温度的提高和蠕变时间的延长,焊缝内晶界棒状γ′相的尺寸和γ′贫化区的宽度增大,而棒状γ′相的数量随蠕变温度的提高先略有减少后增多。晶内颗粒状γ′相是影响IN 740H焊接接头硬度的主要因素。晶界棒状γ′相的不连续粗化与γ′贫化区的形成不仅会降低硬度,还会降低蠕变断裂强度。
In recent years,advanced ultra-supercritical(A-USC)power plants have developed rapidly to increase the thermal efficiency and decrease CO_(2) emission.Inconel 740H(IN 740H)is one of the Ni-based superalloys with the highest creep strength and good corrosion resistance at elevated temperatures.Owing to its excellent comprehensive properties,IN 740H is considered one of the best candidate materials for superheater and reheater in A-USC power plants.Further improving the mechanical properties of IN 740H welded joint enhances the safety and economic viability of the power plants.In this study,IN 740H tubes were welded by multipass tungsten inert gas hot-wire welding followed by a post weld heat treatment(PWHT)at 800 ℃ for 5 h.The formation mechanism of theγ′-denuded zone in the IN 740H welded joint after creep at different temperatures was systematically investigated using OM,SEM,and TEM,and its effect on the mechanical properties was analyzed.Results show that the small rod-likeγ′phase only discontinuously precipitates at grain boundaries in the weld metal during PWHT.After creep at different temperatures,an earlier formation of a coarse rod-likeγ′phase andγ′-denuded zone is observed at grain boundaries in the weld metal than in the base metal.The formation of the coarse rod-likeγ′phase at grain boundaries in the base metal results from the discontinuous coarsening of the sphericalγ′phase near grain boundaries,whereas that in the weld metal results from the discontinuous coarsening of the discontinuously precipitated rod-likeγ′phase at the grain boundaries and sphericalγ′phase near the grain boundaries.The discontinuous coarsening of the rod-likeγ′phase and precipitation of M23C6 carbides at grain boundaries lead to the formation of theγ′-denuded zone.Increasing the creep temperature and creep time when the temperature is in the range of 700-800 ℃ increases the size of the rod-likeγ′phase and width of theγ′-denuded zone at grain boundaries,whereas the number of rod-likeγ′phase initially decreases and then increases with the increase of creep temperature.The sphericalγ′phase in the grain interiors plays a vital role in changing the hardness of the IN 740H welded joint.The discontinuous coarsening of theγ′phase and the formation of theγ′-denuded zone at the grain boundaries not only decrease the hardness,but also deteriorate the creep rupture strength of the IN 740H welded joint.Controlling the discontinuous coarsening of the rod-likeγ′phase at grain boundaries,suppressing the formation of theγ′-denuded zone,and controlling the growth of the sphericalγ′phase in the grain interiors are necessary to improve the mechanical properties of the IN 740H welded joint.
作者
周任远
朱丽慧
ZHOU Renyuan;ZHU Lihui(School of Aerospace and Mechanical Engineering,Changzhou Institute of Technology,Changzhou 213031,China;School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China)
出处
《金属学报》
北大核心
2025年第5期744-756,共13页
Acta Metallurgica Sinica
基金
国家重点研发计划项目No.2016YFC0801904。
作者简介
通讯作者:周任远,男,1991年生,博士,zhoury@czu.cn,主要从事耐热钢及耐热合金方面的研究。
