摘要
以正硅酸乙酯(TEOS)为反应前驱体,采用溶胶-凝胶方法在金刚石微粉及碳纤维表面包覆一层非晶氧化硅凝胶膜,将二者以不同比例混合后在1350℃、5 GPa条件下进行高温高压(HTHP)处理,合成出了以氧化硅为界面结合相的金刚石-碳纤维复合块体材料,并发现组织中出现了原位生成的纳米针。利用扫描电镜(SEM)、扫描电镜能谱分析(EDS)、X-射线衍射(XRD)等手段研究分析了复合材料中金刚石/碳纤维间的界面组织结构特性。对HTHP合成样品进行了热重分析,结果表明,复合材料在580℃后失重明显,其抗氧化能力较金刚石原料微粉提高了80℃。
Using ethyl orthosilicate(TEOS)as the precursor,a layer of amorphous silica gel film was coated on the surface of diamond powder and carbon fiber.A functional diamond-carbon-fiber composite block with silicon oxide as interface bonding phase was synthesized by mixing the coated diamond and carbon fiber in different proportions and treated under high temperature of 1350℃and high pressure of 5 GPa,and the in-situ nanoneedles were found in the matrix of the composite.The interfacial microstructure of diamond-carbon-fiber composites was studied by means of scanning electron microscopy(SEM),energy dispersive electron microscopy(EDS)and X-ray diffraction(XRD).Thermogravimetric analysis(TG)of the HTHP synthetic samples was carried out,and the results show that the weight loss of the composite is obvious after 580℃and its anti-oxidation ability is 80℃higher than that of diamond powder.
作者
庞爱红
郭宇
庞诚宇
付玉博
董俊言
谭素玲
吴增凤
董书山
PANG Aihong;GUO Yu;PANG Chengyu;FU Yubo;DONG Junyan;TAN Suling;WU Zengfeng;DONG Shushan(Henan Hold Diamond&Technology Co.Ltd.,Henan Shangqiu 476200;State Key Laboratory of Superhard Materials,Jilin University,Jilin Changchun 130012)
出处
《超硬材料工程》
CAS
2023年第3期1-7,共7页
Superhard Material Engineering
关键词
金刚石
碳纤维
溶胶-凝胶法
金刚石复合功能材料
高温高压合成
Diamond,Carbon fiberSol-gel method
Diamond functional composite
High temperature and high pressure(HTHP)synthesis
作者简介
庞爱红(1973年-),女,工程师。主要研究方向:金刚石单晶及金刚石微粉的研发、生产、加工等。E-mail:holddiamond@163.com;通讯作者:董书山(1966年-),男,教授。主要研究方向:金属预合金粉末、超硬功能材料及制品等。E-mail:dongss@jlu.edu.cn。
