摘要
Here,we report a mixed GAI and MAI(MGM)treatment method by forming a 2D alternating-cation-interlayer(ACI)phase(n=2)perovskite layer on the 3D perovskite,modulating the bulk and interfacial defects in the perovskite films simultaneously,leading to the suppressed nonradiative recombination,longer lifetime,higher mobility,and reduced trap density.Consequently,the devices’performance is enhanced to 24.5%and 18.7%for 0.12 and 64 cm^(2),respectively.In addition,the MGM treatment can be applied to a wide range of perovskite compositions,including MA-,FA-,MAFA-,and CsFAMA-based lead halide perovskites,making it a general method for preparing efficient perovskite solar cells.Without encapsulation,the treated devices show improved stabilities.
基金
supported by the National Key Research and Development Program of China(2021YFB3800103)
the Fundamental Research Funds for the Central Universities(000-0903069032)
the National Natural Science Foundation of China(52203237).
作者简介
Shirong Wang,wangshirong@tju.edu.cn;Jin Hyuck Heo,live2000jin@gmail.com;Fei Zhang,fei_zhang@tju.edu.cn。
