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Tailoring cobalt-free La_(0.5)Sr_(0.5)FeO_(3-δ)cathode with a nonmetal cation-doping strategy for high-performance proton-conducting solid oxide fuel cells 被引量:8

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摘要 A nonmetal doping strategy was exploited for the conventional La_(0.5)Sr_(0.5)FeO_(3-δ)(LSF)cathode,allowing high performance for proton-conducting solid oxide fuel cells(H-SOFCs).Unlike previous studies focusing on the utilization of metal oxides as dopants,phosphorus,which is a nonmetal element,was used as the cation dopant for LSF by partially replacing Fe ions to form the new La_(0.5)Sr_(0.5)Fe_(0.9)P_(0.1)O_(3-δ)(LSFP)compound.The H-SOFC using the LSFP cathode showed a two-fold peak power density as compared to that using the LSF cathode.Both experimental studies and first-principle calculations were used to unveil the mechanisms for the high performance of the LSFP cells.
出处 《SusMat》 2022年第5期607-616,共10页 可持续发展材料(英文)
基金 the National Natural Science Foundation of China,Grant/Award Number:51972183 the Hundred Youth Talents Program of Hunan the Startup Funding for Talents at University of South China。
作者简介 Correspondence:Lei Bi,School of Resource Environment and Safety Engineering,University of South China,Hengyang 421001,Hunan,China.Email:lei.bi@usc.edu.cn,ORCID:https://orcid.org/0000-0001-9479-0776;Correspondence:Enrico Traversa,School of Materials and Energy,University of Electronic Science and Technology of China,2006 Xiyuan Rd,Chengdu 611731,Sichuan,China.Email:traversa@uestc.edu.cn。
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