摘要
Sodium-ion batteries(SIBs)have been extensively studied as the potential alter-native to lithium-ion batteries(LIBs)due to the abundant natural reserves and low price of sodium resources.Nevertheless,Na+ions possess a larger radius than Li+,resulting in slow diffusion dynamics in electrode materials,and thus seeking appropriate anode materials to meet high performance standards has become a trend in the field of SIBs.In this context,owing to the advantages of high theoretical capacity and proper redox potential,metal phosphides(MPs)are considered to be the promising materials to make up for the gap of SIBs anode materials.In this review,the recent development of MPs anode materials for SIBs is reviewed and analyzed comprehensively and deeply,including the synthesis method,advanced modification strategy,electrochemical performance,and Na storage mechanism.In addition,to promote the wide application of the emerg-ing MPs anodes for SIBs,several research emphases in the future are pointed out to overcome challenges toward the commercial application.
出处
《SusMat》
2021年第3期359-392,共34页
可持续发展材料（英文）
基金
National Natural Science Founda-tion of China,Grant/Award Numbers:51925207,U1910210,51872277,51972067,51802044,51902062,51802043
Funda-mental Research Funds for the Central Universities,Grant/Award Number:WK2060140026
the DNL cooperation Fund,CAS,Grant/Award Number:DNL180310
National Synchrotron Radi-ation Laboratory,Grant/Award Num-ber:KY2060000173
Guangdong Nat-ural Science Funds for Distinguished Young Scholar,Grant/Award Number:2019B151502039。
作者简介
Correspondence:Xianhong Rui,School of Materials and Energy,Guangdong University of Technol-ogy,Guangzhou 510006,China.Email:xhrui@gdut.edu.cn;Correspondence:Yan Yu,Hefei National Laboratory for Physical Sciences at the Microscale,Department of Materials Science and Engineering,CAS Key Laboratory of Mate-rials for Energy Conversion,University of Science and Technology of China,Hefei,Anhui 230026,China.Email:yanyumse@ustc.edu.cn。
