摘要
在介绍2,5-呋喃二甲酸(2,5-FDCA)基本特性和原料来源的基础上,综述了以5-羟甲基糠醛(5-HMF)、糠醛/糠酸、呋喃、己糖二酸、果糖、二甘醇酸为起始原料制备2,5-FDCA的工艺的研究进展。此外,重点阐述了不同催化体系下5-HMF工艺路线的研究现状,认为以5-HMF为起始原料制备2,5-FDCA的工艺路线具有良好的工业化前景,而且该路线催化体系的筛选及工艺条件的优选有进一步研究的价值。
On the basis of introducing the basic characteristics and raw material sources of 2,5-furandicarboxylic acid(2,5-FDCA),the research progress of the process of preparing 2,5-FDCA using 5-hydroxymethyl furfural(5-HMF),furfural/furoic acid,furan,hexaric acid,fructose and diglycolic acid as staring materials is reviewed.In addition,the current research status of 5-HMF process routes under different catalytic systems is highlighted.It is considered that the process route for preparing 2,5-FDCA using 5-HMF as the starting material has good prospects for industrialization,and the screening of catalytic systems and the optimization of process conditions of this route have the value of further research.
作者
程新泰
宋文生
王俊锴
刘继纯
勾明雷
Cheng Xintai;Song Wensheng;Wang Junkai;Liu Jichun;Gou Minglei(Chemical Engineering and Pharmaceutics,Henan University of Science and Technology,Luoyang 471023,China)
出处
《化学推进剂与高分子材料》
CAS
2022年第4期14-19,共6页
Chemical Propellants & Polymeric Materials
基金
国家自然科学基金河南省联合基金项目(U1704144)。
关键词
呋喃二甲酸
5-羟甲基糠醛
己糖二酸
糠醛
制备
furandicarboxylic acid
5-hydroxymethyl furfural
hexaric acid
furfural
preparation
作者简介
程新泰(1996-),男,在读硕士,从事聚氨酯材料研究。cxintai@126.com;通信作者:宋文生(1965-),男,副教授,硕士生导师,从事高分子材料合成与应用研究。wssong_tju@126.com。
