摘要
制备了环氧树脂改性沥青和掺杂纳米SiO_(2)的环氧树脂改性沥青,研究了基体沥青、环氧树脂改性沥青、掺杂纳米SiO_(2)的环氧树脂改性沥青的耐紫外线老化性能。采用物化指标测试、FT-IR和SEM等方法,研究了添加1%,2%和5%(质量分数)纳米SiO_(2)对环氧树脂改性沥青耐紫外线老化性能的影响。结果表明,加入纳米SiO_(2)后,改性沥青的软化点和粘度增加;基体沥青、PA-5%EP、PA-EP-1%SiO_(2)、PA-EP-3%SiO_(2)和PA-EP-5%SiO_(2)的FT-IR光谱几乎在所有峰的位置都是相同的,改性沥青与基体沥青相比,结构没有明显变化;当加入纳米SiO_(2)含量为5%(质量分数)时,改性沥青的粘附力显著提高,此时,纳米SiO_(2)颗粒较为均匀地分散到基体沥青的宏观分子网络中,形成了稳定的结构;纳米SiO_(2)的加入能很好地改善沥青的耐紫外线老化效果,PA-EP-5%SiO_(2)样品的耐紫外线老化性能最优。
Epoxy resin modified asphalt and epoxy resin modified asphalt doped with nano-SiO_(2) are prepared.The properties of UV aging resistant of matrix asphalt,epoxy resin modified asphalt and epoxy resin modified asphalt doped with nano-SiO_(2) are studied.The effects of 1 wt%,2 wt%and 5 wt%nano-SiO_(2) on UV aging resistant of epoxy resin modified asphalt are studied by means of physicochemical index test,FT-IR and SEM.The results show that the softening point and viscosity of modified asphalt increase with the addition of nano-SiO_(2).The FT-IR spectra of matrix asphalt,PA-5%EP,PA-EP-1%SiO_(2),PA-EP-3%SiO_(2) and PA-EP-5%SiO_(2) are almost the same in all peaks compared with matrix asphalt.The structure of modified asphalt has no obvious change.When the content of nano-SiO_(2) is 5 wt%,the adhesion of modified asphalt is significantly improved.At this time,nano-SiO_(2) particles are more evenly dispersed in the macro molecular network of the matrix asphalt,forming a stable structure.The addition of nano-SiO_(2) could improve the UV aging resistant of asphalt,and PA-EP-5%SiO_(2) has the best UV aging resistant.
作者
王逸波
焦彬如
WANG Yibo;JIAO Binru(Department of Architectural and Environmental Engineering, Changzhou University Huaide College,Jingjiang 214500, China;Ningbo Tech University, Ningbo 315100, China)
出处
《功能材料》
EI
CAS
CSCD
北大核心
2021年第3期3140-3144,共5页
Journal of Functional Materials
基金
江苏省自然科学基金青年基金资助项目(BK20190934)。
作者简介
王逸波(1991—),男,江苏常州人,讲师,主要从事道路工程结构与新材料研究;通讯作者:王逸波,E-mail:1225824789@qq.com。
