摘要
水盐体系共晶点的数据可以为盐湖卤水低温加工工艺开发提供必要的理论依据,采用低温冷却法,针对四元同离子体系K+//Cl-,SO_4^(2-),NO_3^--H_2O和四元交互体系Na+,K+//SO_4^(2-),NO_3--H_2O及其相关的6个三元子体系,测定研究了其冰点、共晶点以及析盐规律,绘制出了共晶点温度-液相组成图。研究结果表明:通过测定多元水盐体系降温过程中的时间-温度图,可以判断盐类析出规律、测定冰和盐的共晶点温度;上述体系中,常温下存在的复盐钾芒硝,在共晶点温度下均不再出现,水盐体系相关系得以简化;用棱柱图可以简单直观地表达三元体系、四元同离子体系和四元交互体系的相、冰点或共晶点的温度和溶液组成的关系;在三元体系的共晶点温度-液相组成图中,存在两条单盐与冰的共晶线、一个两种盐与冰的共晶点、一个冰析出面;在四元同离子体系和四元交互体系共晶点温度-液相组成图中,分别有3个和4个单盐与冰的共晶面、3条和5条两种盐与冰的共晶线、1个和2个3种盐与冰的共晶点。
For the quaternary salt-water systems, such as the homo-ion system K^＋//Cl^-, SO4^2-, NO3^--H2O and interaction system Na^＋, K^＋//SO4^2-, NO3^--H2 O, as well as their six ternary subsystems, the freezing points, eutectic points and the crystallization regularities of salts were studied by cooling method. According to experimental data, the eutectic point temperature-liquid composition diagrams for these systems were plotted. The results were as follows：（1） The crystallization regularity of salts and the eutectic point temperatures can be obtained by measuring the time-temperature curves for multicomponent salt-water systems during cooling process;（2） In these systems above, 3K2SO4·Na2SO4 existing under normal temperature did not appear at the eutectic point temperature. As a result, the phase relationships in these systems were simplified;（3） The prism can be used to describe the relationships among the phases, freezing points or eutectic points and the compositions of liquids for the ternary systems, the quaternary homo-ion systems and interaction systems concisely and visually;（4） In the eutectic point temperature-liquid composition diagrams, for ternary systems without double-salts, there were two eutectic curves with single salt and ice, one eutectic point with two salts and ice, and one ice crystallizing region. For the quaternary homo-ion systems and interaction systems, there were three and four eutectic regions with single salt and ice, three and five eutectic curves with two salts and ice, and one and two eutectic points with three salts and ice, respectively.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2016年第5期1687-1693,共7页
CIESC Journal
基金
国家自然科学基金项目(21166022)~~
关键词
水盐体系
共晶点
温度
相
salt-water system
eutectic point
temperature
phase
作者简介
王雪莹（1988-），女，硕士研究生。
联系人：黄雪莉。
