期刊文献+

柴油机SCR系统尿素分解效率研究 被引量:12

Urea Decomposition Efficiency of Diesel Engine SCR System
在线阅读 下载PDF
导出
摘要 提出柴油机SCR系统尿素分解效率的理论计算方法。试验研究了柴油机SCR系统尿素分解效率、NOx转化效率以及NH3泄漏量的关系,分析了空速、氨氮比、SCR温度对三者的影响。结果表明,NOx的转化效率与尿素分解效率的变化趋势基本相同;在催化剂活性温度范围内,尿素水溶液最终分解出NH3的效率都在90%以上;随空速的增大,尿素分解效率先增大再减小;氨氮比为1时,NOx的转化效率较高,但是NH3的泄漏量超出限值;氨氮比对尿素分解效率几乎没有影响;排气温度上升时,尿素分解效率增大。空速和SCR温度是影响尿素分解效率的最大因素。提出的计算方法能够呈现尿素分解效率的变化趋势,为提高SCR系统工作效率提供了依据。 In order to perfect the work efficiency evaluation system of diesel SCR system and improve the work efficiency of SCR system,the theoretical urea decomposition efficiency calculation method of diesel engine SCR system was proposed. The urea decomposition efficiency,amount of leakage of NH3 and NOx conversion efficiency of SCR system for diesel engine were investigated on an engine test bench,the influence of space velocity,NH3/ NO ratio and SCR temperatures were analyzed. Experiment results showed that the changing trend of NOxconversion efficiency and urea decomposition efficiency was basically the same. In the catalyst activation temperature range,the urea decomposition efficiency was above 90%; with the increase of space velocity,the urea decomposition efficiency was increased first and then decreased. NH3/ NO ratio was 1 with high NOxconversion efficiency,but the amount of leakage of NH3 was exceeded the limit value. NH3/ NO ratio had little effect on the urea decomposition efficiency,and it was increased with the amount of leakage of NH3 increasing. When the exhaust gas temperature was raised,the urea decomposition efficiency increased. The space velocity and exhaust gas temperature were the most important factors influencing the urea decomposition efficiency, the level of urea decomposition efficiency was the comprehensive effect of both. Through the study on the factors affecting the decomposition efficiency of urea,to reduce the deposition of urea in the exhaust pipe and improve the removal efficiency of NOx. The proposed calculation method can exhibit a trend of urea decomposition efficiency and provide a basis for improving the work efficiency of SCR system.
出处 《农业机械学报》 EI CAS CSCD 北大核心 2015年第6期282-286,309,共6页 Transactions of the Chinese Society for Agricultural Machinery
基金 国家高技术研究发展计划(863计划)资助项目(2012AA111704) 国家自然科学基金资助项目(51306070)
关键词 柴油机 选择性催化还原 尿素 分解效率 影响因素 Diesel engine Selective catalytic reduction Urea Decomposition efficiency Influencing factors
作者简介 马军彦,博士生,主要从事柴油机排放控制研究,E—mail:junyanm@163.com 通讯作者:曲大为,讲师,博士,主要从事发动机电子控制研究,E-mail:eewang404@163.com
  • 相关文献

参考文献13

  • 1黄锦成,沈捷.车用内燃机排放与污染控制[M].北京:科学出版社,2012.
  • 2姜磊,葛蕴珊,李璞,刘志华.柴油机尿素SCR后处理系统排放特性试验研究[J].内燃机工程,2010,31(5):30-35. 被引量:26
  • 3Akira Nishioka, Yoshihiro Sukegawa, Kozo Katogi, et al. A study of a new aftertreatment system (2) :control of urea solution spray for urea-SCR [ C ]. SAE Paper 2006 - 01 - 0644,2006.
  • 4Vadim O Strots, Shyam Santhanam, Brad J Adelman, et al. Deposit formation in urea-SCR systems [ C ]. SAE Paper 2009 -01 - 2780,2009.
  • 5Guanyu Zheng, Adam Fila, Adam Kotrba. Investigation of urea deposits in urea SCR systems for medium and heavy duty trucks [ C]. SAE Paper 2010 -01 - 1941,2010.
  • 6冯向宇,葛蕴珊,马朝臣,韩秀坤,谭建伟,李加强.柴油机尿素SCR系统沉积物成因研究[J].内燃机工程,2014,35(6):1-6. 被引量:10
  • 7Johann C Wurzenberger,Roland Wanker. Multi-scale SCR modeling 1D kinetic analysis and 3D system simulation [ C ]. SAE Paper 2005 - 01 - 0948,2005.
  • 8Strugess M P, Benjamin S F, Roberts C A. Spatial conversion profiles within an SCR in a test exhaust system with injection of ammonia gas modelled in CFD using the porous medium approach[ C]. SAE Paper 2010 -01 -2089,2010.
  • 9Sehuler A, Votsmeier M, Kiwic P, et al. NH3-SCR on Fe zeolite catalysts--From model setup to NH3 dosing [ J ]. Chemical Engineering Journal, 2009,154 ( 1 - 3 ) : 333 - 340.
  • 10唐韬,赵彦光,华伦,帅石金.柴油机SCR系统尿素水溶液喷雾分解的试验研究[J].内燃机工程,2015,36(1):1-5. 被引量:24

二级参考文献46

  • 1黄齐飞,宋崇林,范国梁,吕刚,李小娟,赵瑞芬.钙钛矿型催化剂La_(1-x)K_x CoO_(3-λ)的表征特性及对柴油机尾气中NO_x催化性能的研究[J].燃烧科学与技术,2006,12(5):413-418. 被引量:4
  • 2彭小圣,林赫,黄震,上官文峰.La-Mn-O钙钛矿催化剂成分对NO_x和碳烟同时催化去除的影响[J].高校化学工程学报,2006,20(5):831-836. 被引量:12
  • 3李儒龙,帅石金,董红义,王建昕,石小燕,贺泓.乙醇选择性催化还原NO_x后处理系统在重型柴油机上的应用研究[J].内燃机工程,2007,28(1):1-5. 被引量:8
  • 4Helden V R,Verbeek R,Willems F,et al.Optimization of urea SCR deNOx system for HD diesel engines[C]//SAE 2004-01-0154,2004.
  • 5Lambert C,Cavataio G,Cheng Y S,et al.Urea-SCR and DPF system for tier 2 diesel light-duty trucks[R].Michigan:US Department of Energy Diesel Engine Emission Reduction (DEER) conference,2006.
  • 6Hesser M,Luders H,Henning R S.SCR technology for NOx reduction:series experience and state of development[R].Chicago:US Department of Energy Diesel Engine Emission Reduction (DEER) conference,2005.
  • 7Koebel M,Strutz E O.Thermal and hydrolytic decomposition of urea for automotive selective catalytic reduction systems:thermochemical and practical aspects[J].Industrial & Engineering Chemistry Research,2003,42(12):2093-2100.
  • 8Kusaka J,Sueoka M,Takada K,et al.A basic study on a urea-selective catalytic reduction system for a medium-duty diesel engine[J].International Journal of Engine Research,2005(6):11-19.
  • 9Kleemann,Elsener M,Koebel M,et al.Hydrolysis of isocyanic acid on SCR catalysts[J].Industrial & Engineering Chemistry Research,2000,39(11):4120-4126.
  • 10Lambert C,Hammerle R.Technical advantages of SCR technologies for light-duty and heavy-duty diesel vehicle applications[C]//SAE 2004-01-1292,2004.

共引文献68

同被引文献69

  • 1张文娟,帅石金,董红义,王志,王建昕.尿素SCR-NO_x催化器流动、还原剂喷雾及表面化学反应三维数值模拟[J].内燃机学报,2007,25(5):433-438. 被引量:23
  • 2张纪元,李国祥,孙少军,王意宝,陶建忠,赵彦光.重型柴油机Urea-SCR系统尿素沉积物的试验研究[J].车用发动机,2012(4):43-47. 被引量:15
  • 3帅石金,张文娟,董红义,王建昕,王志.柴油机尿素SCR催化器优化设计[J].车用发动机,2007(1):44-47. 被引量:37
  • 4贺泓,翁端,资新运.柴油车尾气排放污染控制技术综述[J].环境科学,2007,28(6):1169-1177. 被引量:155
  • 5CHO J M, CHOI J W, HONG S H, el al. The methodology to improve tile performance of a selecti,e catalytic reduction system installed in HRSG using computational fluid dynamics aualysis [ J ]. Environmental Engineering Science, 2006,23 (5) :863 -873.
  • 6CHEN Ming, WILL Shazan. Modelling and optimization of SCR-exhaust aftertreatment system [ C]. SAE Paper 2005 -01 -0969, 2005.
  • 7DIETER H E Seher, MICHAEl, Reichelt, STEFAN Wickert. Control strategy fbr NO -emission reduction with SCR [ C ]. SAE Paper 2003 - Ol - 3362,2003.
  • 8AVL List GmbH. FIRE v-2011-1agrangian multiphase module [ M]. Graz :AVL List GmbH, 2011.
  • 9ZUKERMANA R, VRADMANA L, HERSKOWITZA M, et al. Modeling and simulation of a smart catalytic converter combining NOx storage ammonia production and SCR[ J]. Chemical Engineering Journal, 2009,155 (1) :419 -426.
  • 10STROTS V O, SANTHANAM S, ADELMAN B J, et al. Deposit formation in urea-SCR[ C]. SAE Parper 2009 -01 -2780, 2009.

引证文献12

二级引证文献41

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部