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不同电极对外延BiFeO_3薄膜铁电性能的影响 被引量:4

Influence of Different Electrode on the Property of Epitaxial BiFeO_3 Thin Film
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摘要 采用磁控溅射的方法在SrRuO3/SrTiO3(001)衬底上外延生长BiFeO3薄膜,研究以不同金属或氧化物做顶电极时的铁电、铁磁性质和漏电流及其导电机制。X射线衍射图谱和Φ扫描图结果显示BiFeO3薄膜沿c轴外延生长,以Pt、Al做顶电极的薄膜剩余极化强度2Pr为68μC/cm2,生长Pt/SRO、FePt顶电极的薄膜剩余极化强度较小,2Pr为44μC/cm2,矫顽场2Ec约为370±20 kV/cm。薄膜的漏电流密度较小而且趋于饱和,在U=12 V时最大为1.94×10-3A/cm2,体传导普尔弗兰克导电为BiFeO3薄膜主要的导电机制。BFO薄膜展现出弱磁性,饱和磁化强度为9.3 emu/cm3,矫顽场为338 Oe。 Epitaxial BiFeO3(BFO) thin film have been grown on SrRuO3/SrTiO3(001) substrates by radio frequency magnetron sputtering.Ferroelectric,ferromagnetic,leakage current and its mechanisms were investigates with different metal and conductive oxide top electrode.X-ray diffraction measurement and Φ scan spectra indicates the formation of an epitaxial single-phase.BFO film is well crystallized.The remnant polarization(2Pr) of BFO film by Pt and Al top electrode are 68 μC/cm2.They are 44 μC/cm2 by Pt /SRO and FePt top electrode at a coercive field(2Ec) of 370±20 kV/cm.The film has low leakage current density with largest of 1.94×10-3 A/cm2 at 12 V and Poole-Frenkle emission is the main conduction mechanism in BFO film.Moreover,BFO thin film exhibits a weak ferromagnetic behavior with a saturation magnetization of 9.3 emu/cm3 and a coercive field of 338 Oe.
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2012年第6期1561-1565,共5页 Journal of Synthetic Crystals
基金 国家自然科学基金(60876055 11074063) 高等学校博士点基金(20091301110002) 河北省自然科学基金(E2009000207 E2008000620 08B010)
关键词 BIFEO3 磁控溅射 铁电性 外延生长 BiFeO3 magnetron sputtering ferroelectric epitaxial growth
作者简介 马继奎(1985-),男,甘肃省人,硕士。E—mail:majkts8y@163.com
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参考文献23

  • 1Nakashima S, Ricinshi D, Park J M, et al. Ferroelectric and Structural Properties of Stress-constrained and Stressrelaxed Polycrystalline BiFeO3 Thin Films [ J]. J. Appl. Phys. ,2009,105:061617.
  • 2彭增伟,刘保亭,魏大勇,马继奎,王宽冒,李曼,赵光.光照对BiFe_(0.95)Mn_(0.05)O_3薄膜铁电和输运性质的影响[J].人工晶体学报,2011,40(2):388-391. 被引量:3
  • 3Ramesh R, Spaldin N A. Multiferroics: Progress and Prospects in Thin Films[J]. Nature Mater,2007,6:21-29.
  • 4Wang J, Neaton J B, Zheng H, et al. Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures[ J]. Science,2003,2::1719-1722.
  • 5Catalan G, Scott J F, Physics and Applications of Bismuth Ferrite [ J ]. Adv. Mater. ,2009,21:2463-2485.
  • 6赵庆勋,张婷,马继奎,魏大勇,王宽冒,刘保亭.沉积温度对磁控溅射BiFeO3薄膜结构和性能的影响[J].人工晶体学报,2011,40(4):921-925. 被引量:10
  • 7Zheng R Y, Gao X S, Zhou Z H, et al. Multiferroic BiFeO3 Thin Films Deposited On SrRuO3 Buffer Layer by Rfsputtering[ J]. J. Appl. Phys. 2007,101:054104.
  • 8Yun K Y, Noda M, Okuyama M, et al. Structural and Multiferroic Properties of BiFeO3 Thin Films at Room Temperature [ J ]. J. Appl. Phys. 2004,96(6) :3399-3403.
  • 9Qi X, Dho J, Tomov R, et al. Greatly Reduced Leakage Current and Conduction Mechanism in Aliovalent-ion-doped BiFeO3 [ J ]. Appl. Phys. Lett. ,2005,86(6) :062903.
  • 10Chert F, Zhang Q F, Li J H, et al. Sol-gel Derived Multiferroic BiFeO3 Ceramics with Large Polarization and Weak Ferromagnetism[J]. Appl. Phys. Lett. ,2006,89(9) :092910.

二级参考文献43

  • 1徐万劲.磁控溅射技术进展及应用(上)[J].现代仪器,2005,11(5):1-5. 被引量:48
  • 2朱劲松,吕笑梅,朱曼,译.铁电存储器[M].北京:清华大学出版社,2004.
  • 3Luo W B,Zhu J,Li Y R,et al.Effects of Chemical Fluctuations on Microstructures and Properties of Multiferroic BiFeO3 Thin Films[J].Appl.Phys.Lett.,2007,91:082501.
  • 4Béa H,Bibes M,Barthélémy A,et al.Influence of Parasitic Phases on the Properties of BiFeO3 Epitaxial Thin Films[J].Appl.Phys.Lett.,2005,87:072508.
  • 5Béa H,Bibes M,Fusil S,et al.Investigation on the Origin of the Magnetic Moment of BiFeO3 Thin Films by Advanced X-ray Characterizations[J].Phys.Rev.B,2006,74:020101.
  • 6Yun K Y,Noda M,Okuyama M,et al.Prominent Ferroelectricity of BiFeO3 Thin Films Prepared by Pulsed-laser Deposition[J].Appl.Phys.Lett.,2003,83(19):3981-3983.
  • 7Ederer C,Spaldin N.Effect of Epitaxial Strain on the Spontaneous Polarization of thin Film Ferroelectrics[J].Phys.Rev.Lett.,2005,95(25):257601.
  • 8Wang Y,Nan C W.Enhanced Ferroelectricity in Ti-doped Multiferroie BiFeO3 Thin Films[J].Appl.Phys.Lett.,2006,89(5):052903.
  • 9Pabst G W,Martin L W,Chu Y H,et al.Leakage Mechanisms in BiFeO3 Thin Films[J].Appl.Phys.Lett.,2007,90:072902.
  • 10Yang H,Jain M,Suvorova N A,et al.Temperature-dependent Leakage Mechanisms of Pt/BiFeO3/SrRuO3 Thin Film Capacitors[J].Appl.Phys.Lett.,2007,91(7):072911.

共引文献12

同被引文献55

  • 1Wang J, Neaton J B, Zheng H, et al. Epitaxial BiFeO3 Muhiferroic Thin Film Heterostructures[ J]. Science,2003,299:1719-1722.
  • 2Neaton J B, Ederer C, Waghmare U V, et al. First-Principles Study of Spontaneous Polarization in Muhiferroic BiFeO3 [ J ]. Physics Review B, 2005,71:0141131-0141138.
  • 3Zhao T, Scholl A, Zavaliche F, et al. Electrical Control of Antiferromagnetic Domains in Muhiferroic BiFeO3 Films at Room Temperature [ J ]. Nature Materials ,2006,5:823--829.
  • 4Chu H Y, Martin L W, Holcomb M B, et al. Electric-Field Control of Local Ferromagnetism Using a Magnetoelectric Multiferroic [ J ]. Nature Materials, 2008,7 : 478 -482.
  • 5Jang H W, Baek S H, Ortiz D, et al. Epitaxial (001) BiFeO3 Membranes with Substantially Reduced Fatigue and Leakage [ J ]. Applied Physics Letters ,2008,92:0629101-0629103.
  • 6Lou X J, Zhang M, Redfem S A T, et al. Local Phase Decomposition as a Cause of Polarization Fatigue in Ferroelectric Thin Films[J]. Physics Review Letter,2006,97 : 1776011-1776014.
  • 7Shannigrahi S R, Huang A, Chandrasekhar N, et al. Sc Modified Multiferroic BiFeO3 Thin Films Prepared Through a Sol-Gel Process [ J ]. Applied Physics Letter,2007,90:0229011- 0229013.
  • 8Kawae T, Terauchi Y, Tsuda H, et al. Improved Leakage and Ferroelectric Properties of Mn and Ti Codoped BiFeO3 Thin Films[ J]. Applied Physics Letters ,2009,95 : 1129041-1129043.
  • 9Xu D, Shi L, Wu Z, et al. Microstructure and Electrical Properties of ZnO-Bi2 03 -Based Varistor Ceramics by Different Sintering Processes [ J ]. Journal of the European Ceramic Society,2009,29 : 1789-1794.
  • 10Zhong Z, Ishiwara H. Variation of Leakage Current Mechanisms by Ion Substitution in BiFeO3 Thin Films[J].Applied Physics Letters,2009,95:1129021-1129023.

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