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层状化合物三氧化钼的制备及其电化学脱嵌锂性质研究 被引量:10

PROGRESS IN PREPARATION AND ELECTROCHEMICAL PROPERTIES OF LITHIUM INTERCALATION-DETERCALATION OF LAYERED MOLYBDENUM TRIOXIDES
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摘要 三氧化钼具有独特的层状结构,主要以三种相态存在:热力学稳定的正交相、热力学介稳的单斜相和六方相。本文介绍了三氧化钼的制备方法,概述了它们电化学脱嵌锂性质的研究现状,探讨了三氧化钼晶体作为电极活性材料的主要影响因素,提出了改进材料电化学性能的方法,展望了三氧化钼研究的发展趋势和应用前景。 Molybdenum trioxides, which exhibit a unique layered structure, form a rich family: the well - known thermodynamically stable normal phase α - MoO3 , metastable phase β - MoO3 and h - MoO3 s in preparation and electrochemical properties of lithium intercalation - detercalation of layered molybdenum trioxides has been introduced. The factors that might influence the electrochemical behaviors of these oxides have been discussed. Further work on improving the performance of materials is suggested. The main application and prospect of molybdenum trioxides are also given in brief.
出处 《中国钼业》 2007年第5期36-42,共7页 China Molybdenum Industry
基金 安徽省教育厅自然科学基金(No.2005KJ100)资助 安徽省高等学校‘十五’优秀人才建设经费资助 安徽大学人才队伍建设经费资助
关键词 三氧化钼 制备 电极材料 电化学性质 molybdenum trioxide preparation electrode material eletrochemical properties
作者简介 宋继梅(1963-),女,教授,博士,研究方向:无机材料化学。
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参考文献57

  • 1Anwar M, Hogarth C A and Thocharis C R. A study of the infrared absorption spectra of thin amorphous films of molybdenum trioxide[J]. J. Mater. Sci. , 1989, 24: 2387 - 2390.
  • 2Siokou A, Leftheriotis G, Papaefthimiou S, et al. Effect of the tungsten and molybdenum osidation states on the thermal coloration of amorphous WOs and MoO3 films [J]. Surface Sci. , 2001,482-485:294-299.
  • 3Lee Se - Hee, Seong Maeng Je, Tracy C Edwin, et al. Raman spectroscopic studies of electrochromic a - MoO3 thin films[ J ]. Solid State Ionics, 2002, 147 : 129 - 133.
  • 4Belatel H, Al- Kandari H, Al- Kharafi F, et al, Catalytic reactions of methylcyclohexane ( MCH), on partially reduced tungsten oxide (s) [J]. Applied Catalysis A : General, 2007, 318 : 227 - 233.
  • 5Epifani M, Imperatori P, Mirenghi L, et al. Synthesis and characterization of MoO3 thin films and powders from a molybdenum chloromethoxide [J]. Chem. Mater., 2004, 16:5495-5501.
  • 6Sian Tarsame S and Reddy G B. Optical structural and photoelectron spectroscopic studies on amorphous and crystalline molybdenum on amorphous and crystalline mo- lybdenum oside thin films [J]. Solar Energy Materials & Solar Cells, 2004, 82 : 375 - 386.
  • 7Mougin O, Dubois J, Mathieu F, et al. , Metastable hexagonal vanadium molybdate study [ J ]. J. Solid State Chem. , 2000, 152:353-360.
  • 8Yu A, Kumagai N, Liu Z L et al. , Preparation of sodium molybdenum oxides by a solution technique and their electrochemical performance in lithium intercalation [ J ]. Solid State Ionics, 1998, 106:11 -18.
  • 9He T and Yao J, Photochromism of molybdenum oxide [J]. J. Photochem. & Photobiology, 2003, 4:125 - 143.
  • 10Juarez Ramirez I and Martinez - de la Cruz A. Synthesis of β -MoO3 by vacuum drying and its structural and electrochemical characterization [ J ]. Mater. Lett. , 2003, 57 : 1034 - 1039.

二级参考文献8

  • 1郑汝骊 王恩波.-[J].化学通报,1984,(9):12-18.
  • 2WMoReTi/有色金属提取冶金手册编辑委员会.稀有高熔点金属(上)[M].北京:冶金工业出版社,1999..
  • 3国家统计局.2003年1-5月全国安全生产形势通报[Z].,..
  • 4Zhang B,Inorg Chem,1998年,37卷,1844页
  • 5Guo C,Chem Commun,1997年,801页
  • 6Nazar L F,J Am Chem Soc,1991年,113卷,5889页
  • 7储高升,卞国柱,张志成,陈家富.表面活性剂对制备MoO_2纳米微粉的影响[J].物理化学学报,1999,15(4):365-369. 被引量:5
  • 8汪学广,侯文华,颜其洁.氧化铬柱层状三氧化钼的合成[J].化学学报,2000,58(6):688-691. 被引量:8

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