摘要
杯芳烃是一种具有独特空穴结构和良好性能的大环超分子主体化合物,在超分子材料、离子传感器等研究领域具有广泛应用.以邻苯三酚、异戊醛为原料合成了2,8,14,20-四异丁基-邻苯三酚杯[4]芳烃.运用红外光谱,核磁共振氢谱、碳谱以及X-射线单晶衍射对其结构进行了表征.
Calixarenes,macrocyclic compounds with interior cavity and remarkable property,have been widely used in many research fields,such as supramolecular materials and ion transducer.By using pyrogallol and isovaleraldehyde as raw materials,2,8,14,20-tetra-iso-butyl-pyrogallol[4]arene was successfully prepared.The structure of the product was confirmed by IR,1H NMR,13C NMR and single crystal X-ray analysis.
出处
《湖南师范大学自然科学学报》
CAS
北大核心
2012年第1期52-55,共4页
Journal of Natural Science of Hunan Normal University
基金
国家自然科学基金资助项目(20871046)
湖南省教育厅基金资助项目(11B077)
湖南师范大学优秀人才培养计划资助项目(ET20903)
关键词
芳烃
晶体
结构
pyrogallol[4]arene
crystal
structure
