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氧化锆陶瓷与不锈钢钎焊的研究 被引量:4

JOINING OF ZIRCONIA CERAMIC TO STAINLESS STEEL
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摘要 采用Ag-Cu-Ti活性钎料,研究了氧化锆陶瓷与ICr18Ni9Ti不锈钢的钎焊,探讨了软性中间层Cu对接头强度的影响规律,分析了陶瓷与钎料的界面反应,结果表明:陶瓷与钎料间存在一明显反应层,厚度约为4.4μm,反应产物为δ-TiO和γ-AsTi3,并按ZrO2/δ-TiO/δ-TiO+γ-AgTi3/γ-AgTi3/Ag-Cu呈层状过渡分布,中间层Cu对陶瓷与不锈钢钎焊接头强度有很大的影响,当厚度合适时,Cu通过蠕变或屈服机制显著降低了接头残余应力,提高了接头强度;太薄或太厚的中间层对接头强度的改善作用不大。 The brazing of zirconia ceramic to 1Cr18Ni9Ti stainless steel was performed usingAg5 7Cu38Ti5 filler metal in vacuum,The effects of a soft interlayer copper on the jointstrength were investigated,and the interfacial reaction between the ceramic and the fillermetal was also analysed.It was shown that an interfacial reaction layer about 4. 4 μm thickwas found between the ceramic and the filler metal,and the reaction products were δ-TiO andγ-AgTi3.A layer of transition structures with a ZrO2/δ-TiO/S-TiO + γ-AgTi3/γ-AgTi3/Ag-Cu was formed at the interface,Interlayer Cu had a great influence on the joint strength ofceramic to stainless steel bonding,With a suitable thickness,Cu can considerably relax theresidual stress in the joints by a creep or yield mechanism during cooling from joining tem-perature,and increase the joint strength.When Cu was too thin or too thick,its improvementon the joint strength was little;
出处 《西安交通大学学报》 EI CAS CSCD 北大核心 1995年第2期85-89,共5页 Journal of Xi'an Jiaotong University
关键词 氧化锆陶瓷 不锈钢 钎焊 中间层 zirconia ceramic stainless steel joining interlayer
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参考文献3

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  • 2Xian A P,J Am Ceram Soc,1990年,73卷,11期,3462页
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同被引文献36

  • 1朱胜,霍辛斯基,徐滨士.射频溅射薄膜改善氮化铝陶瓷与金属连接性研究[J].中国表面工程,1998,11(4):5-9. 被引量:4
  • 2王仲礼.陶瓷与金属的焊接技术[J].焊接技术,1996,25(5):17-19. 被引量:6
  • 3黄小丽,林实,肖纪美,楚建新.ZrO_2与40Cr钢钎焊中的缓冲层[J].材料科学与工程,1996,14(3):58-61. 被引量:5
  • 4Samandi M, Gudze M, Evans P. Application of ion implantation to ceramic/metal joining [J]. Nuclear Instruments and Methods in Physics Research B, 1997, (127/128): 669.
  • 5Piekoszewski J, Krajewski A, Prokert F, et al. Brazing of alumina ceramics modified by pulsed plasma beams combined with arc PVD treatment [J]. Vacuum, 2003, (70):307.
  • 6Durov A V, Kostjuk B D, Shevchenko A V, et al. Joining of zirconia to metal with Cu-Ga-Ti and Cu-Sn-Pb-Ti fillers[J]. Mater Sci Eng,2000, (A290): 186.
  • 7Travessa D, Ferrante M, den Ouden G. Diffusion bonding of aluminum oxide to stainless steel using stress relief interlayers [J]. Mater Sci Eng, 2002, (A337) :287.
  • 8Shin-ichi Matsuoka. Ultrasonic welding of ceramics/metals using inserts [J]. J Mater Proc Techn, 1998, (75) :259.
  • 9董雪.氧化锆陶瓷在空气炉中钎焊的研究[J].大连:大连交通大学,2004.
  • 10ZHANG Y, FENG D, HE Z Y, et al.Progress in joining ceramics to metals[J].Journal of Iron and Steel Research, International.2006, 13 ( 2 ) : 01-05.

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