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双核配合物[Cu_2(L-Asp)(phen)_3(NO_3)](NO_3)·4H_2O的合成及晶体结构 被引量:2

Synthesis and Crystal Structure of Binuclear Complex [Cu_2(L-Asp)(phen)_3(NO_3)](NO_3)·4H_2O
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摘要 The new complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O (L-Asp=L-aspartic acid and phen=1,10-phenanthroline) has been synthesized and its crystal structure ha s been determined. The complex crystallizes in the monoclinic with space group P 21/c, The cell parameters are: a=1.261 3(2) nm, b=1.500 8(4) nm, c=2.230 7(4) nm , 穋m-3. The complex contains tw o six-coordinated copper ions, and these two copper ions are connected together by L-aspartate to give rise to a binuclear structure. Hydrogen bonds The new complex [Cu2(L-Asp)(phen)3(NO3)](NO3)·4H2O (L-Asp=L-aspartic acid and phen=1,10-phenanthroline) has been synthesized and its crystal structure ha s been determined. The complex crystallizes in the monoclinic with space group P 21/c, The cell parameters are: a=1.261 3(2) nm, b=1.500 8(4) nm, c=2.230 7(4) nm , 穋m-3. The complex contains tw o six-coordinated copper ions, and these two copper ions are connected together by L-aspartate to give rise to a binuclear structure. Hydrogen bonds and
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2004年第12期1429-1432,共4页 Chinese Journal of Inorganic Chemistry
基金 广西自然科学基金资助项目(No.9912044)
关键词 双核配合物 铜配合物 合成 晶体结构 天冬氨酸 L-aspartic acid 1,10-phenanthroline copper(II) complex c rystal structure
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