Pb(Zr,Ti)O_(3)-Pb(Zn_(1/3)Nb_(2/3))O_(3) (PZT-PZN) based ceramics, as important piezoelectric materials, have a wide range of applications in fields such as sensors and actuators, thus the optimization of their piezoe...Pb(Zr,Ti)O_(3)-Pb(Zn_(1/3)Nb_(2/3))O_(3) (PZT-PZN) based ceramics, as important piezoelectric materials, have a wide range of applications in fields such as sensors and actuators, thus the optimization of their piezoelectric properties has been a hot research topic. This study investigated the effects of phase boundary engineering and domain engineering on (1-x)[0.8Pb(Zr_(0.5)Ti_(0.5))O_(3)-0.2Pb(Zn_(1/3)Nb_(2/3))O_(3)]-xBi(Zn_(0.5)Ti_(0.5))O_(3) ((1-x)(0.8PZT-0.2PZN)- xBZT) ceramic to obtain excellent piezoelectric properties. The crystal phase structure and microstructure of ceramic samples were characterized. The results showed that all samples had a pure perovskite structure, and the addition of BZT gradually increased the grain size. The addition of BZT caused a phase transition in ceramic samples from the morphotropic phase boundary (MPB) towards the tetragonal phase region, which is crucial for optimizing piezoelectric properties. By adjusting content of BZT and precisely controlling position of the phase boundary, the piezoelectric performance can be optimized. Domain structure is one of the key factors affecting piezoelectric performance. By using domain engineering techniques to optimize grain size and domain size, piezoelectric properties of ceramic samples have been significantly improved. Specifically, excellent piezoelectric properties (piezoelectric constant d_(33)=320 pC/N, electromechanical coupling factor kp=0.44) were obtained simultaneously for x=0.08. Based on experimental results and theoretical analysis, influence mechanisms of phase boundary engineering and domain engineering on piezoelectric properties were explored. The study shows that addition of BZT not only promotes grain growth, but also optimizes the domain structure, enabling the polarization reversal process easier, thereby improving piezoelectric properties. These research results not only provide new ideas for the design of high-performance piezoelectric ceramics, but also lay a theoretical foundation for development of related electronic devices.展开更多
Causality,the science of cause and effect,has made it possible to create a new family of models.Such models are often referred to as causal models.Unlike those of mathematical,numerical,empirical,or machine learning(M...Causality,the science of cause and effect,has made it possible to create a new family of models.Such models are often referred to as causal models.Unlike those of mathematical,numerical,empirical,or machine learning(ML)nature,causal models hope to tie the cause(s)to the effect(s)pertaining to a phenomenon(i.e.,data generating process)through causal principles.This paper presents one of the first works at creating causal models in the area of structural and construction engineering.To this end,this paper starts with a brief review of the principles of causality and then adopts four causal discovery algorithms,namely,PC(Peter-Clark),FCI(fast causal inference),GES(greedy equivalence search),and GRa SP(greedy relaxation of the sparsest permutation),have been used to examine four phenomena,including predicting the load-bearing capacity of axially loaded members,fire resistance of structural members,shear strength of beams,and resistance of walls against impulsive(blast)loading.Findings from this study reveal the possibility and merit of discovering complete and partial causal models.Finally,this study also proposes two simple metrics that can help assess the performance of causal discovery algorithms.展开更多
Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O soluti...Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O solution.The assembly and fluorescence behavior of PDI-COOH/Ca^(2+)were studied in detail by changing hydration state with different concentrations.Based on the differences in assembly morphology and stoichiometric ratios of PDICOOH/Ca^(2+),we proposed the fluorescence emission mechanism of PDI-COOH/Ca^(2+)in THF/H_(2)O and THF,respectively.This work reveals a novel strategy of aggregated state fluorescence enhancement and reminds us of the important role of water in molecular fluorescence emission and assembly.展开更多
(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under...(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.展开更多
Graphdiyne(GDY)is a two-dimensional carbon allotrope with exceptional physical and chemical properties that is gaining increasing attention.However,its efficient and scalable synthesis remains a significant challenge....Graphdiyne(GDY)is a two-dimensional carbon allotrope with exceptional physical and chemical properties that is gaining increasing attention.However,its efficient and scalable synthesis remains a significant challenge.We present a microwave-assisted approach for its continuous,large-scale production which enables synthesis at a rate of 0.6 g/h,with a yield of up to 90%.The synthesized GDY nanosheets have an average diameter of 246 nm and a thickness of 4 nm.We used GDY as a stable coating for potassium(K)metal anodes(K@GDY),taking advantage of its unique molecular structure to provide favorable paths for K-ion transport.This modification significantly inhibited dendrite formation and improved the cycling stability of K metal batteries.Full-cells with perylene-3,4,9,10-tetracarboxylic dianhydride(PTCDA)cathodes showed the clear superiority of the K@GDY anodes over bare K anodes in terms of performance,stability,and cycle life.The K@GDY maintained a stable voltage plateau and gave an excellent capacity retention after 600 cycles with nearly 100%Coulombic efficiency.This work not only provides a scalable and efficient way for GDY synthesis but also opens new possibilities for its use in energy storage and other advanced technologies.展开更多
The cross-domain capabilities of aerial-aquatic vehicles(AAVs)hold significant potential for future airsea integrated combat operations.However,the failure rate of AAVs is higher than that of unmanned systems operatin...The cross-domain capabilities of aerial-aquatic vehicles(AAVs)hold significant potential for future airsea integrated combat operations.However,the failure rate of AAVs is higher than that of unmanned systems operating in a single medium.To ensure the reliable and stable completion of tasks by AAVs,this paper proposes a tiltable quadcopter AAV to mitigate the potential issue of rotor failure,which can lead to high-speed spinning or damage during cross-media transitions.Experimental validation demonstrates that this tiltable quadcopter AAV can transform into a dual-rotor or triple-rotor configuration after losing one or two rotors,allowing it to perform cross-domain movements with enhanced stability and maintain task completion.This enhancement significantly improves its fault tolerance and task reliability.展开更多
The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to ...The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to achieving controllable stress-strain rate loading.In this study,we have,for the first time,combined one-dimensional fluid computational software with machine learning methods.We first elucidated the mechanisms by which GDI structures control stress and strain rates.Subsequently,we constructed a machine learning model to create a structure-property response surface.The results show that altering the loading velocity and interlayer thickness has a pronounced regulatory effect on stress and strain rates.In contrast,the impedance distribution index and target thickness have less significant effects on stress regulation,although there is a matching relationship between target thickness and interlayer thickness.Compared with traditional design methods,the machine learning approach offers a10^(4)—10^(5)times increase in efficiency and the potential to achieve a global optimum,holding promise for guiding the design of GDI.展开更多
Zirconium alloy(Zr-4)is extensively utilized in nuclear fuel cladding materials due to its exceptional neutron economy,high ductility,and promising corrosion and irradiation resistance.Nevertheless,during the operatio...Zirconium alloy(Zr-4)is extensively utilized in nuclear fuel cladding materials due to its exceptional neutron economy,high ductility,and promising corrosion and irradiation resistance.Nevertheless,during the operational lifespan of the Zr-4 fuel tube,micro-oscillations induced by the high-speed flow of cooling water can cause wear between the cladding tube and grids.This leads to wear failure of the Zr-4 alloy tube,which seriously threatens the safe operation of nuclear stations.The application of protective coatings onto the surface of zirconium alloys serves to enhance their resistance against wear,while without changing of the existing reactor structure.In this study,FeCrAl/CrN and FeCrAl coatings were fabricated on the surface of Zr-4 alloy using dual-target co-sputtering technology.The effects of the CrN interlayer on the microstructure,mechanical properties,and tribological behavior of FeCrAl coating in air and B-Li water were investigated,and a comparative analysis with Zr-4 alloy was conducted.The results showed that the application of FeCrAl/CrN and FeCrAl coatings significantly enhanced the hardness and wear resistance of Zr-4 alloy.The introduction of the CrN interlayer increased the columnar grain size of the FeCrAl coating and caused a change in the preferred growth direction of the coating from(110)to(211).The CrN interlayer improved the hardness and wear resistance of the coating,it also led to a decrease in adhesion strength.The wear rates of FeCrAl/CrN coatings in air and B-Li water were the lowest,about 3.2×10^(-6) mm^(3)/(N·m)and 6.0×10^(-7) mm^(3)/(N·m),respectively.The lubricating effect of B-Li water effectively reduced the friction coefficient and wear rate of both FeCrAl/CrN and FeCrAl coatings.In air and B-Li water,the primary wear mechanisms for Zr-4 are adhesive wear and oxidative wear,while the main wear mechanisms for FeCrAl/CrN and FeCrAl coatings are abrasive wear and oxidative wear.These findings not only provided a theoretical basis for understanding the microstructure and wear performance of FeCrAl coatings but also offered important technical guidance for their practical application in the nuclear industry.展开更多
The effects of different warm rolling(WR)reductions on the microstructure and mechanical properties of low-Cr FeCrAl alloys at both room and elevated temperatures were investigated.The study revealed that when the WR ...The effects of different warm rolling(WR)reductions on the microstructure and mechanical properties of low-Cr FeCrAl alloys at both room and elevated temperatures were investigated.The study revealed that when the WR reduction is small,it effectively refines the grains and forms a large number of subgrains in the matrix,while also inducing the dissolution of the Laves phase.This enhances the mechanical properties of FeCrAl alloys primarily through grain refinement and solid solution strengthening.Conversely,with larger WR reductions,the grain refinement effect diminishes,but a significant number of Laves phases form in the matrix,strengthening the alloys primarily through precipitation strengthening.WR exhibited a remarkable enhancing effect on the comprehensive mechanical properties at both room and high temperatures,with a signi-ficant enhancement in ductility at high temperatures.Notably,a 10%WR reduction resulted in the optimal overall mechanical properties at both room and elevated temperatures.展开更多
The technology for green and macro-conversion of solid waste biomass to prepare high-quality activated carbon demands urgent development.This study proposes a technique for synthesizing carbon adsorbents using trace K...The technology for green and macro-conversion of solid waste biomass to prepare high-quality activated carbon demands urgent development.This study proposes a technique for synthesizing carbon adsorbents using trace KOH-catalyzed CO_(2) activation.Comprehensive investigations were conducted on three aspects:physicochemical structure evolution of biochar,mechanistic understanding of trace KOH-facilitated CO_(2) activation processes,and application characteristics for CO_(2) adsorption.Results demonstrate that biochar activated by trace KOH(<10%)and CO_(2) achieves comparable specific surface area(1244.09 m^(2)/g)to that obtained with 100%KOH activation(1425.10 m^(2)/g).The pore structure characteristics(specific surface area and pore volume)are governed by CO and CH4 generated through K-salt catalyzed reactions between CO_(2) and biochar.The optimal CO_(2) adsorption capacities of KBC adsorbent reached 4.70 mmol/g(0℃)and 7.25 mmol/g(25℃),representing the maximum values among comparable carbon adsorbents.The 5%KBC-CO_(2) sample exhibited CO_(2) adsorption capacities of 3.19 and 5.01 mmol/g under respective conditions,attaining current average performance levels.Notably,CO_(2)/N_(2) selectivity(85∶15,volume ratio)reached 64.71 at 0.02 bar with robust cycling stability.Molecular dynamics simulations revealed that oxygen-containing functional groups accelerate CO_(2) adsorption kinetics and enhance micropore storage capacity.This technical route offers simplicity,environmental compatibility,and scalability,providing critical references for large-scale preparation of high-quality carbon materials.展开更多
[Background]Traveling-wave tubes(TWTs)are widely applied in radar,imaging,and military systems owing to their excellent amplification characteristics.Miniaturization and integration are critical to the future of TWTs,...[Background]Traveling-wave tubes(TWTs)are widely applied in radar,imaging,and military systems owing to their excellent amplification characteristics.Miniaturization and integration are critical to the future of TWTs,with multi-channel slow-wave structures(SWSs)forming the foundation for their realization in high-power vacuum electronic devices.[Purpose]To provide design insights for multi-channel TWTs and simultaneously enhance their output power,a W-band folded-waveguide TWT with dual electron beams and H-plane power combining was proposed.[Methods]Three-dimensional electromagnetic simulations in CST were conducted to verify the highfrequency characteristics,electric field distribution,and amplification performance of the proposed SWS,thereby confirming the validity of the design.[Results]Results indicate that the designed TWT achieves a transmission bandwidth of 10 GHz.With an electron beam voltage of 17.9 kV and a current of 0.35 A,the output power reaches 450 W at 94 GHz,corresponding to an efficiency of 7.18%and a gain of 23.5 dB.Moreover,under fixed beam voltage and current,the TWT delivers over 200 W output power across 91–99 GHz,with a 3 dB bandwidth of 91–98.5 GHz.The particle voltage distribution after modulation further validates the mode analysis.[Conclusions]These results demonstrate the feasibility of compact dual-beam power-combining structures and provide useful guidance for the design of future multi-channel TWTs.展开更多
Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake gra...Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake graphite(FG)-modified MKPC coatings via spraying process,investigating the effects of FG size and dosage on phase composition,microstructure,mechanical properties,corrosion protection,and thermal conductivity.Results show that a low FG dosage(5 wt%)synergistically optimizes multifunctional performance.Compared to unmodified MKPC,FG2-1 exhibited exceptional impact resistance,associated with a 57%reduction in corrosion current density(icorr),a 356.3% increase in low-frequency impedance modulus(Z_(0.01 Hz))and a 37% increase in thermal conductivity.However,the coating with a high FG dosage(15 wt%)degraded performance due to defect accumulation and reduced crystallinity of KMgPO_(4)·6H_(2)O.This work advances the rational design of multifunctional inorganic coatings for extreme service environments requiring coupled corrosion protection and thermal management.展开更多
To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(...To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(6)](X_(2)pdt=(SCH_(2))_(2)CX_(2),X=Me,H)with aminodiphosphines(Ph_(2)PCH_(2))_(2)NY(Y=(CH_(2))_(2)OH,(CH_(2))_(3)OH)to obtain two new diiron aminophosphine complexes[Fe_(2)(L1)(μ-Me_(2)pdt)(CO)_(5)](1)and[Fe_(2)(L2)(μ-H_(2)pdt)(CO)_(5)](2),where L1=3-[(diphe-nylphosphaneyl)methyl]oxazolidine,L2=3-[(diphenylphosphaneyl)methyl]-1,3-oxazinane.Moreover,the structures of 1 and 2 have been fully confirmed by elemental analysis,spectroscopic techniques,and single-crystal X-ray diffraction.Using cyclic voltammetry(CV),we investigated the electrochemical redox performance and proton reduc-tion activities of 1 and 2 in acetic acid(HOAc).The CV study indicates that diiron aminophosphine complexes 1 and 2 can be considered to be hydrogenase-inspired diiron molecular electrocatalysts for the reduction of protons into H 2 generation in the presence of HOAc.CCDC:2443967,1;2443969,2.展开更多
[Background and purposes]In recent years,there has been growing attention in academia and industry on the development of high-performance electromagnetic wave(EMW)absorbing materials.However,creating lightweight broad...[Background and purposes]In recent years,there has been growing attention in academia and industry on the development of high-performance electromagnetic wave(EMW)absorbing materials.However,creating lightweight broadband absorbers remains a challenge in terms of practical applications.EMW absorbing materials primarily rely on the magnetic loss of magnetic materials and/or the dielectric loss of dielectric materials to convert EMW energy into thermal energy for dissipation.Among various magnetic materials,Fe_(3)O_(4) plays an irreplaceable role in EMW absorption due to its high saturation magnetization,low cost and compatible dielectric loss in the gigahertz frequency range.Nevertheless,the high density,large matching thickness and narrow absorption bandwidth of Fe_(3)O_(4) pose significant challenges for practical applications.In contrast,one-dimensional(1D)structures not only retain the characteristic properties of lightweight,chemical stability and high dielectric loss,but also exhibit anisotropic structures and large aspect ratios.Additionally,researchers have found that the minimum reflection loss(RL)of hollow carbon materials with mesopores is nearly four times that of non-porous hollow carbon materials and nine times that of dense carbon materials.According to Maxwell's EMW theory,composites consisting of Fe_(3)O_(4) and one-dimensional(1D)mesoporous carbon materials can leverage their respective advantages by optimizing the composition and structure of the composites to balance u,and Er,thereby enhancing EMW absorption performance.Additionally,numerous studies have demonstrated that composites composed of multi-component heterostructures significantly enhance the EAB.This enhancement is primarily ascribed to the numerous interface polarization losses generated by the additional heterostructure interfaces,which also improve the overall impedance matching of the composites.In this study,we leverage the advantages of magnetic/carbon composites,one-dimensional(1D)mesoporous carbon and multi-component heterostructures to prepare a composite of 1D mesoporous carbon-coated manganese oxide(Mn_(3)O_(4) and MnO,denoted as Mn_(x)O_(y))embedded with Fe_(3)0_(4) nanoparticles(Mn_(x)O_(y)/C@Fe_(3)O_(4)).This composite was synthesized and its formation mechanism and microstructure were analyzed in detail.At the same time,the influence of this Mn_(x)O_(y)/C@Fe_(3)O_(4) structure on EMW properties and absorbing performance was further discussed.[Methods]Firstly,MnO_(2) nanowires were synthesized by using a simple hydrothermal method.Then,the MnO_(2) nanowires served as templates for the synthesis of MnO_(2)/PDA@Fe^(3+)composites through the in-situ polymerization of dopamine and Fe^(3+)adsorption.Finally,1D mesoporous carbon-coated manganese oxide composite embedded with Fe_(3)O_(4) nanoparticles(Mn_(x)O_(y)/C@Fe_(3)O_(4))composites were obtained after heat treatment at 550℃ in N_(2).The crystal structure of the samples was analyzed using X-ray diffractometer with Cu Ka irradiation.Scanning electron microscopy(SEM)and high-resolution transmission electron microscopy(TEM)were used to observe microstructure and morphology of the samples.Nitrogen sorption measurements were obtained at 77 K on a Quantachrome surface area and pore size analyzer to measure the specific surface area and pore size distribution.XPS analysis was performed on X-ray photoelectron spectrometer with monochromatic Al Ka radiation.Magnetization curves of the samples were recorded with a Quantum Design physical property measurement system(PPMS-9)at room temperature.The electromagnetic parameters of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composites were measured using an Agilent N5230C network analyzer in the frequency range of 2-18 GHz.For electromagentic testing,the Mn,Oy/C@Fe34 composites and paraffin wax were mixed at 50°C according to the mass ratio of 15 wt.%,20 wt.%and 25 wt.%,and pressed in a special mold to make coaxial rings(inner diameter=3.04 mm,outer diameter-7 mm),which were denoted as S-1,S-2 and S-3,respectively.[Results]SEM images illustrate the preparation process of iD mesoporous carbon-coated manganese oxide embedded with Fe3O4 nanoparticles composites(Mn_(x)O_(y)/C@Fe_(3)O_(4)).Most of the manganese oxide(Mn,Oy)was reduced to granular after heat treatment,while the outer carbon layer remains its 1D morphology and the carbon layer is interspersed with Fe_(3)O_(4) nanoparticles.The diffraction peaks of MnO_(2) nanowires align well with the body-centered tetragonal a-MnO2.For the Mn_(x)O_(y)/C@Fe_(3)O_(4) composites,the signals of α-MnO_(2) disappears,followed by the emergence of Mn_(3)O_(4) and three prominent diffraction peaks for the cubic MnO.In addition,four weak diffraction peaks correspond to the magnetite Fe_(3)O_(4),consistent with the HRTEM results.The corresponding nitrogen adsorption-desorption isotherm and pore size distribution curve are presented to further analyze the mesoporous structure of composite.The surface composition and element valence states of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composite were investigated by using XPS.The polarization relaxation processes were analyzed according to the Debye theory which describes the relationship between e'and e".Besides the polarization loss,the contribution of the conduction loss plays an important role for the overall dielectric loss.The magnetization curve of Mn_(x)O_(y)/C@Fe_(3)O_(4) exhibits typical ferromagnetic behavior.The permittivity parameter(Co),defined as Co=u"(u)^(-2)f^(-1) determine the contribution of eddy current effect to magnetic loss.The tand values are all larger than those of tand,for the three samples,indicating that the loss capacity of Mn_(x)O_(y)/C@Fe_(3)O_(4) composites is mainly derived from the dielectric loss.Although tand,is smaller,it plays an important role in improving the impedance matching of Mn_(x)O_(y)/C@Fe_(3)O_(4) composites.When the filler loading is 15 wt.%,the RL of sample S-1 is about-10.0 dB at the thickness of 1.5 mm with narrow EAB.As the filler loading increased to 20 wt.%,the RL of sample S-2 reached-62.0 dB at a thickness of 2.2 mm and the EAB was 6.4 GHz at a small thickness of 1.7 mm.When the filler loading is further increased to 25 wt.%,the microwave absorption performance of sample S3 decreased significantly with a little region of RL<-10.0 dB at the thickness of 5.0 mm.The values of[Zin/Zol of the three samples at thicknesses of 1.5-5.0 mm were calculated.Due to good impedance matching of S-2,the incident EMW can enter the material and then can be dissipated through dipole polarization loss,interface polarization loss,conduction loss,eddy current loss and natural ferromagnetic resonance loss.[Conclusions]1D Mn_(x)O_(y)/C@Fe_(3)O_(4) was synthesized via a process involving the coating of polydopamine,adsorption of Fe(ll)salts and heat treatment,using MnO_(2) nanowires as templates.The multi-component heterostructure of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composite(Mn_(3)O_(4),MnO,Fe_(3)O_(4),and C)enhances the interfacial interactions between the different phases,providing increased interface polarization loss under the action of an alternating electromagnetic field.The numerous defects and terminal groups in the mesoporous carbon provide abundant dipole polarization centers.Additionally,the presence of mesopores reduces the weight of the material while increasing the multiple scattering losses of the electromagnetic waves within the material.The ID carbon structure in the matrix forms a conductive network between adjacent fibers,facilitating electron migration and transition,thereby enhancing conductive loss.The incorporation of magnetic Fe_(3)O_(4) nanoparticles introduces eddy current loss and natural ferromagnetic resonance loss,thus increasing magnetic loss.Moreover,the synergistic effect between dielectric and magnetic losses improves the impedance matching of the material,leading to excellent EMW absorption performance.展开更多
Objective To characterize transmembrane protein 68(TMEM68)in an alternative triacylglycerol(TAG)biosynthesis pathway,and determine the interplay between TMEM68 and the canonical TAG synthesis enzyme acyl-CoA:diacylgly...Objective To characterize transmembrane protein 68(TMEM68)in an alternative triacylglycerol(TAG)biosynthesis pathway,and determine the interplay between TMEM68 and the canonical TAG synthesis enzyme acyl-CoA:diacylglycerol acyltransferase(DGAT).Methods Effects of exogenous fatty acid and monoacylglycerol on TAG synthesis and lipid droplet(LD)formation in TMEM68 overexpression and knockout cells treated with DGAT inhibitor or not were investigated by comparing LD morphology,Oil Red O staining,and measurement of TAG levels.LDs were stained with fluorescence dye and observed by confocal fluorescence microscopy.TAG levels were determined with an enzyme-based triglyceride assay kit.Colocalization of TMEM68 and DGAT1 was detected by co-expression and confocal fluorescence microscopy and their interaction was determined by co-immunoprecipitation.RT-qPCR and immunoblotting assay were used to detect the expression of DGAT1.Results The synthesis of TAG catalyzed by TMEM68 was independent of DGAT activity.Surplus exogenous fatty acids and monoacylglycerol promoted TAG synthesis mainly through DGAT in human neuroblastoma cells.The LDs formed by TMEM68 were different in morphology from those by DGAT.In addition,TMEM68 and DGAT1 colocalized in the same endoplasmic reticulum(ER)compartment but did not interact physically.TMEM68 overexpression reduced the expression of DGAT1,the major DGAT enzyme involved in TAG synthesis,while TMEM68 knockout had little impact.Conclusion The TMEM68-mediated TAG synthesis pathway has distinct features from the canonical DGAT pathway,however,TMEM68 and DGAT may coregulate intracellular TAG levels.展开更多
Microstrip transmission lines connecting to the millimeter wave radar chip and antenna significantly affect the radiation efficiency and bandwidth of the antenna.Here,a wideband non-uniform wavy microstrip line for co...Microstrip transmission lines connecting to the millimeter wave radar chip and antenna significantly affect the radiation efficiency and bandwidth of the antenna.Here,a wideband non-uniform wavy microstrip line for complex impedance in automotive radar frequency range is proposed.Unlike the gradient transmission line,the wavy structure is composed of periodically semi-circular segments.By adjusting the radius of the semi-circular,the surface current is varied and concentrated on the semi-circular segments,allowing a wider tunability range of the resonant frequency.The results reveal that the bandwidth of the loaded wavy transmission line antenna improves to 9.37 GHz,which is 5.81 GHz wider than that of the loaded gradient line.The gain and the half power beam width of the loaded antenna are about 14.69 dB and 9.58°,respectively.The proposed non-uniform microstrip line scheme may open up a route for realizing wideband millimeter-wave automotive radar applications.展开更多
Microstrip traveling wave tubes(TWTs)have garnered significant attention due to their potential applications in communication,defense,and industrial systems.This paper presents a compact W-band dual-channel TWT,utiliz...Microstrip traveling wave tubes(TWTs)have garnered significant attention due to their potential applications in communication,defense,and industrial systems.This paper presents a compact W-band dual-channel TWT,utilizing a U-shaped microstrip meander-line slow-wave structure(SWS).High-frequency characteristics are analyzed through simulation and cold tests.The results demonstrate that adjusting structural parameters effectively optimizes the S-parameters.Particle-in-cell(PIC)simulations with an 18.8 kV,0.1 A electron beam predict an output power of 18 W with a gain of 14 dB.Experimental measurements of S-parameters are conducted using three substrate materials:Rogers 5880,quartz,and diamond.The quartz substrate exhibits the closest agreement with simulation results.The results advance the development of the microstrip-based TWTs for high-data-rate communication systems.展开更多
There is nonradiative recombination in waveguide region owing to severe carrier leakage,which in turn reduces output power and wall-plug efficiency.In this paper,we designed a novel epitaxial structure,which suppresse...There is nonradiative recombination in waveguide region owing to severe carrier leakage,which in turn reduces output power and wall-plug efficiency.In this paper,we designed a novel epitaxial structure,which suppresses carrier leakage by inserting n-Ga_(0.55)In_(0.45)P and p-GaAs_(0.6)P_(0.4) between barriers and waveguide layers,respectively,to modulate the energy band structure and to increase the height of barrier.The results show that the leakage current density reduces by 87.71%,compared to traditional structure.The nonradiative recombination current density of novel structure reduces to 37.411 A/cm^(2),and the output power reaches 12.80 W with wall-plug efficiency of 78.24%at an injection current density 5 A/cm^(2) at room temperature.In addition,the temperature drift coefficient of center wavelength is 0.206 nm/℃at the temperature range from 5℃to 65℃,and the slope of fitted straight line of threshold current with temperature variation is 0.00113.The novel epitaxial structure provides a theoretical basis for achieving high-power laser diode.展开更多
The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade tempe...The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed.展开更多
Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit...Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit lower toxicity and a more mature preparation process.Unlike hydrogen fuel cells,DEFCs provide superior storage and transport feasibility,as well as cost-effectiveness,significantly enhancing their commercial viability.However,the stable C-C bond in ethanol creates a high activation energy barrier,often resulting in incomplete electrooxidation.Current commercial platinum(Pt)-and palladium(Pd)-based catalysts demonstrate low C-C bond cleavage efficiency(<7.5%),severely limiting DEFC energy output and power density.Furthermore,high catalyst costs and insufficient activity impede large-scale commercialization.Recent advances in DEFC anode catalyst design have focused on optimizing material composition and elucidating catalytic mechanisms.This review systematically examines developments in ethanol electrooxidation catalysts over the past five years,highlighting strategies to improve C1 pathway selectivity and C-C bond activation.Key approaches,such as alloying,nanostructure engineering,and interfacial synergy effects,are discussed alongside their mechanistic implications.Finally,we outline current challenges and future prospects for DEFC commercialization.展开更多
基金National Natural Science Foundation of China (52202139, 52072178)。
文摘Pb(Zr,Ti)O_(3)-Pb(Zn_(1/3)Nb_(2/3))O_(3) (PZT-PZN) based ceramics, as important piezoelectric materials, have a wide range of applications in fields such as sensors and actuators, thus the optimization of their piezoelectric properties has been a hot research topic. This study investigated the effects of phase boundary engineering and domain engineering on (1-x)[0.8Pb(Zr_(0.5)Ti_(0.5))O_(3)-0.2Pb(Zn_(1/3)Nb_(2/3))O_(3)]-xBi(Zn_(0.5)Ti_(0.5))O_(3) ((1-x)(0.8PZT-0.2PZN)- xBZT) ceramic to obtain excellent piezoelectric properties. The crystal phase structure and microstructure of ceramic samples were characterized. The results showed that all samples had a pure perovskite structure, and the addition of BZT gradually increased the grain size. The addition of BZT caused a phase transition in ceramic samples from the morphotropic phase boundary (MPB) towards the tetragonal phase region, which is crucial for optimizing piezoelectric properties. By adjusting content of BZT and precisely controlling position of the phase boundary, the piezoelectric performance can be optimized. Domain structure is one of the key factors affecting piezoelectric performance. By using domain engineering techniques to optimize grain size and domain size, piezoelectric properties of ceramic samples have been significantly improved. Specifically, excellent piezoelectric properties (piezoelectric constant d_(33)=320 pC/N, electromechanical coupling factor kp=0.44) were obtained simultaneously for x=0.08. Based on experimental results and theoretical analysis, influence mechanisms of phase boundary engineering and domain engineering on piezoelectric properties were explored. The study shows that addition of BZT not only promotes grain growth, but also optimizes the domain structure, enabling the polarization reversal process easier, thereby improving piezoelectric properties. These research results not only provide new ideas for the design of high-performance piezoelectric ceramics, but also lay a theoretical foundation for development of related electronic devices.
文摘Causality,the science of cause and effect,has made it possible to create a new family of models.Such models are often referred to as causal models.Unlike those of mathematical,numerical,empirical,or machine learning(ML)nature,causal models hope to tie the cause(s)to the effect(s)pertaining to a phenomenon(i.e.,data generating process)through causal principles.This paper presents one of the first works at creating causal models in the area of structural and construction engineering.To this end,this paper starts with a brief review of the principles of causality and then adopts four causal discovery algorithms,namely,PC(Peter-Clark),FCI(fast causal inference),GES(greedy equivalence search),and GRa SP(greedy relaxation of the sparsest permutation),have been used to examine four phenomena,including predicting the load-bearing capacity of axially loaded members,fire resistance of structural members,shear strength of beams,and resistance of walls against impulsive(blast)loading.Findings from this study reveal the possibility and merit of discovering complete and partial causal models.Finally,this study also proposes two simple metrics that can help assess the performance of causal discovery algorithms.
文摘Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O solution.The assembly and fluorescence behavior of PDI-COOH/Ca^(2+)were studied in detail by changing hydration state with different concentrations.Based on the differences in assembly morphology and stoichiometric ratios of PDICOOH/Ca^(2+),we proposed the fluorescence emission mechanism of PDI-COOH/Ca^(2+)in THF/H_(2)O and THF,respectively.This work reveals a novel strategy of aggregated state fluorescence enhancement and reminds us of the important role of water in molecular fluorescence emission and assembly.
文摘(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.
基金supported by National Natural Science Foundation of China(52302034,52402060,52202201,52021006)Beijing National Laboratory for Molecular Sciences(BNLMS-CXTD202001)+1 种基金Shenzhen Science and Technology Innovation Commission(KQTD20221101115627004)China Postdoctoral Science Foundation(2024T170972)。
文摘Graphdiyne(GDY)is a two-dimensional carbon allotrope with exceptional physical and chemical properties that is gaining increasing attention.However,its efficient and scalable synthesis remains a significant challenge.We present a microwave-assisted approach for its continuous,large-scale production which enables synthesis at a rate of 0.6 g/h,with a yield of up to 90%.The synthesized GDY nanosheets have an average diameter of 246 nm and a thickness of 4 nm.We used GDY as a stable coating for potassium(K)metal anodes(K@GDY),taking advantage of its unique molecular structure to provide favorable paths for K-ion transport.This modification significantly inhibited dendrite formation and improved the cycling stability of K metal batteries.Full-cells with perylene-3,4,9,10-tetracarboxylic dianhydride(PTCDA)cathodes showed the clear superiority of the K@GDY anodes over bare K anodes in terms of performance,stability,and cycle life.The K@GDY maintained a stable voltage plateau and gave an excellent capacity retention after 600 cycles with nearly 100%Coulombic efficiency.This work not only provides a scalable and efficient way for GDY synthesis but also opens new possibilities for its use in energy storage and other advanced technologies.
基金supported by Southern Marine Science and Engineering Guangdong Laboratory Grant No.SML2023SP229。
文摘The cross-domain capabilities of aerial-aquatic vehicles(AAVs)hold significant potential for future airsea integrated combat operations.However,the failure rate of AAVs is higher than that of unmanned systems operating in a single medium.To ensure the reliable and stable completion of tasks by AAVs,this paper proposes a tiltable quadcopter AAV to mitigate the potential issue of rotor failure,which can lead to high-speed spinning or damage during cross-media transitions.Experimental validation demonstrates that this tiltable quadcopter AAV can transform into a dual-rotor or triple-rotor configuration after losing one or two rotors,allowing it to perform cross-domain movements with enhanced stability and maintain task completion.This enhancement significantly improves its fault tolerance and task reliability.
基金supported by the Guangdong Major Project of Basic and Applied Basic Research(Grant No.2021B0301030001)the National Key Research and Development Program of China(Grant No.2021YFB3802300)the Foundation of National Key Laboratory of Shock Wave and Detonation Physics(Grant No.JCKYS2022212004)。
文摘The graded density impactor(GDI)dynamic loading technique is crucial for acquiring the dynamic physical property parameters of materials used in weapons.The accuracy and timeliness of GDI structural design are key to achieving controllable stress-strain rate loading.In this study,we have,for the first time,combined one-dimensional fluid computational software with machine learning methods.We first elucidated the mechanisms by which GDI structures control stress and strain rates.Subsequently,we constructed a machine learning model to create a structure-property response surface.The results show that altering the loading velocity and interlayer thickness has a pronounced regulatory effect on stress and strain rates.In contrast,the impedance distribution index and target thickness have less significant effects on stress regulation,although there is a matching relationship between target thickness and interlayer thickness.Compared with traditional design methods,the machine learning approach offers a10^(4)—10^(5)times increase in efficiency and the potential to achieve a global optimum,holding promise for guiding the design of GDI.
文摘Zirconium alloy(Zr-4)is extensively utilized in nuclear fuel cladding materials due to its exceptional neutron economy,high ductility,and promising corrosion and irradiation resistance.Nevertheless,during the operational lifespan of the Zr-4 fuel tube,micro-oscillations induced by the high-speed flow of cooling water can cause wear between the cladding tube and grids.This leads to wear failure of the Zr-4 alloy tube,which seriously threatens the safe operation of nuclear stations.The application of protective coatings onto the surface of zirconium alloys serves to enhance their resistance against wear,while without changing of the existing reactor structure.In this study,FeCrAl/CrN and FeCrAl coatings were fabricated on the surface of Zr-4 alloy using dual-target co-sputtering technology.The effects of the CrN interlayer on the microstructure,mechanical properties,and tribological behavior of FeCrAl coating in air and B-Li water were investigated,and a comparative analysis with Zr-4 alloy was conducted.The results showed that the application of FeCrAl/CrN and FeCrAl coatings significantly enhanced the hardness and wear resistance of Zr-4 alloy.The introduction of the CrN interlayer increased the columnar grain size of the FeCrAl coating and caused a change in the preferred growth direction of the coating from(110)to(211).The CrN interlayer improved the hardness and wear resistance of the coating,it also led to a decrease in adhesion strength.The wear rates of FeCrAl/CrN coatings in air and B-Li water were the lowest,about 3.2×10^(-6) mm^(3)/(N·m)and 6.0×10^(-7) mm^(3)/(N·m),respectively.The lubricating effect of B-Li water effectively reduced the friction coefficient and wear rate of both FeCrAl/CrN and FeCrAl coatings.In air and B-Li water,the primary wear mechanisms for Zr-4 are adhesive wear and oxidative wear,while the main wear mechanisms for FeCrAl/CrN and FeCrAl coatings are abrasive wear and oxidative wear.These findings not only provided a theoretical basis for understanding the microstructure and wear performance of FeCrAl coatings but also offered important technical guidance for their practical application in the nuclear industry.
文摘The effects of different warm rolling(WR)reductions on the microstructure and mechanical properties of low-Cr FeCrAl alloys at both room and elevated temperatures were investigated.The study revealed that when the WR reduction is small,it effectively refines the grains and forms a large number of subgrains in the matrix,while also inducing the dissolution of the Laves phase.This enhances the mechanical properties of FeCrAl alloys primarily through grain refinement and solid solution strengthening.Conversely,with larger WR reductions,the grain refinement effect diminishes,but a significant number of Laves phases form in the matrix,strengthening the alloys primarily through precipitation strengthening.WR exhibited a remarkable enhancing effect on the comprehensive mechanical properties at both room and high temperatures,with a signi-ficant enhancement in ductility at high temperatures.Notably,a 10%WR reduction resulted in the optimal overall mechanical properties at both room and elevated temperatures.
基金supported by the National Natural Science Foundation of China(52376103,542B2081).
文摘The technology for green and macro-conversion of solid waste biomass to prepare high-quality activated carbon demands urgent development.This study proposes a technique for synthesizing carbon adsorbents using trace KOH-catalyzed CO_(2) activation.Comprehensive investigations were conducted on three aspects:physicochemical structure evolution of biochar,mechanistic understanding of trace KOH-facilitated CO_(2) activation processes,and application characteristics for CO_(2) adsorption.Results demonstrate that biochar activated by trace KOH(<10%)and CO_(2) achieves comparable specific surface area(1244.09 m^(2)/g)to that obtained with 100%KOH activation(1425.10 m^(2)/g).The pore structure characteristics(specific surface area and pore volume)are governed by CO and CH4 generated through K-salt catalyzed reactions between CO_(2) and biochar.The optimal CO_(2) adsorption capacities of KBC adsorbent reached 4.70 mmol/g(0℃)and 7.25 mmol/g(25℃),representing the maximum values among comparable carbon adsorbents.The 5%KBC-CO_(2) sample exhibited CO_(2) adsorption capacities of 3.19 and 5.01 mmol/g under respective conditions,attaining current average performance levels.Notably,CO_(2)/N_(2) selectivity(85∶15,volume ratio)reached 64.71 at 0.02 bar with robust cycling stability.Molecular dynamics simulations revealed that oxygen-containing functional groups accelerate CO_(2) adsorption kinetics and enhance micropore storage capacity.This technical route offers simplicity,environmental compatibility,and scalability,providing critical references for large-scale preparation of high-quality carbon materials.
基金National Key Research and Development Program of China(2022YFF0707602)National Natural Science Foundation of China(62471097,62471115,62471101)National Natural Science Foundation of Sichuan(2025ZNSFSC0537)。
文摘[Background]Traveling-wave tubes(TWTs)are widely applied in radar,imaging,and military systems owing to their excellent amplification characteristics.Miniaturization and integration are critical to the future of TWTs,with multi-channel slow-wave structures(SWSs)forming the foundation for their realization in high-power vacuum electronic devices.[Purpose]To provide design insights for multi-channel TWTs and simultaneously enhance their output power,a W-band folded-waveguide TWT with dual electron beams and H-plane power combining was proposed.[Methods]Three-dimensional electromagnetic simulations in CST were conducted to verify the highfrequency characteristics,electric field distribution,and amplification performance of the proposed SWS,thereby confirming the validity of the design.[Results]Results indicate that the designed TWT achieves a transmission bandwidth of 10 GHz.With an electron beam voltage of 17.9 kV and a current of 0.35 A,the output power reaches 450 W at 94 GHz,corresponding to an efficiency of 7.18%and a gain of 23.5 dB.Moreover,under fixed beam voltage and current,the TWT delivers over 200 W output power across 91–99 GHz,with a 3 dB bandwidth of 91–98.5 GHz.The particle voltage distribution after modulation further validates the mode analysis.[Conclusions]These results demonstrate the feasibility of compact dual-beam power-combining structures and provide useful guidance for the design of future multi-channel TWTs.
基金National Key Research and Development Program of China(2024YFB3714804)National Natural Science Foundation of China(52171277)+1 种基金Baima Lake Laboratory Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(LBMHZ24E020001)Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(2022SZ-TD006).
文摘Magnesium potassium phosphate cement(MKPC)coatings exhibit potential for carbon steel protection but face challenges in practical application due to the preparation process and properties.This study develops flake graphite(FG)-modified MKPC coatings via spraying process,investigating the effects of FG size and dosage on phase composition,microstructure,mechanical properties,corrosion protection,and thermal conductivity.Results show that a low FG dosage(5 wt%)synergistically optimizes multifunctional performance.Compared to unmodified MKPC,FG2-1 exhibited exceptional impact resistance,associated with a 57%reduction in corrosion current density(icorr),a 356.3% increase in low-frequency impedance modulus(Z_(0.01 Hz))and a 37% increase in thermal conductivity.However,the coating with a high FG dosage(15 wt%)degraded performance due to defect accumulation and reduced crystallinity of KMgPO_(4)·6H_(2)O.This work advances the rational design of multifunctional inorganic coatings for extreme service environments requiring coupled corrosion protection and thermal management.
文摘To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(6)](X_(2)pdt=(SCH_(2))_(2)CX_(2),X=Me,H)with aminodiphosphines(Ph_(2)PCH_(2))_(2)NY(Y=(CH_(2))_(2)OH,(CH_(2))_(3)OH)to obtain two new diiron aminophosphine complexes[Fe_(2)(L1)(μ-Me_(2)pdt)(CO)_(5)](1)and[Fe_(2)(L2)(μ-H_(2)pdt)(CO)_(5)](2),where L1=3-[(diphe-nylphosphaneyl)methyl]oxazolidine,L2=3-[(diphenylphosphaneyl)methyl]-1,3-oxazinane.Moreover,the structures of 1 and 2 have been fully confirmed by elemental analysis,spectroscopic techniques,and single-crystal X-ray diffraction.Using cyclic voltammetry(CV),we investigated the electrochemical redox performance and proton reduc-tion activities of 1 and 2 in acetic acid(HOAc).The CV study indicates that diiron aminophosphine complexes 1 and 2 can be considered to be hydrogenase-inspired diiron molecular electrocatalysts for the reduction of protons into H 2 generation in the presence of HOAc.CCDC:2443967,1;2443969,2.
基金National Natural Science Foundation of China (52371171, 52222106, 51971008, 52121001)Fund of National Key Laboratory of Scattering and Radiation (Beijing Institute of Environmental Features)。
文摘[Background and purposes]In recent years,there has been growing attention in academia and industry on the development of high-performance electromagnetic wave(EMW)absorbing materials.However,creating lightweight broadband absorbers remains a challenge in terms of practical applications.EMW absorbing materials primarily rely on the magnetic loss of magnetic materials and/or the dielectric loss of dielectric materials to convert EMW energy into thermal energy for dissipation.Among various magnetic materials,Fe_(3)O_(4) plays an irreplaceable role in EMW absorption due to its high saturation magnetization,low cost and compatible dielectric loss in the gigahertz frequency range.Nevertheless,the high density,large matching thickness and narrow absorption bandwidth of Fe_(3)O_(4) pose significant challenges for practical applications.In contrast,one-dimensional(1D)structures not only retain the characteristic properties of lightweight,chemical stability and high dielectric loss,but also exhibit anisotropic structures and large aspect ratios.Additionally,researchers have found that the minimum reflection loss(RL)of hollow carbon materials with mesopores is nearly four times that of non-porous hollow carbon materials and nine times that of dense carbon materials.According to Maxwell's EMW theory,composites consisting of Fe_(3)O_(4) and one-dimensional(1D)mesoporous carbon materials can leverage their respective advantages by optimizing the composition and structure of the composites to balance u,and Er,thereby enhancing EMW absorption performance.Additionally,numerous studies have demonstrated that composites composed of multi-component heterostructures significantly enhance the EAB.This enhancement is primarily ascribed to the numerous interface polarization losses generated by the additional heterostructure interfaces,which also improve the overall impedance matching of the composites.In this study,we leverage the advantages of magnetic/carbon composites,one-dimensional(1D)mesoporous carbon and multi-component heterostructures to prepare a composite of 1D mesoporous carbon-coated manganese oxide(Mn_(3)O_(4) and MnO,denoted as Mn_(x)O_(y))embedded with Fe_(3)0_(4) nanoparticles(Mn_(x)O_(y)/C@Fe_(3)O_(4)).This composite was synthesized and its formation mechanism and microstructure were analyzed in detail.At the same time,the influence of this Mn_(x)O_(y)/C@Fe_(3)O_(4) structure on EMW properties and absorbing performance was further discussed.[Methods]Firstly,MnO_(2) nanowires were synthesized by using a simple hydrothermal method.Then,the MnO_(2) nanowires served as templates for the synthesis of MnO_(2)/PDA@Fe^(3+)composites through the in-situ polymerization of dopamine and Fe^(3+)adsorption.Finally,1D mesoporous carbon-coated manganese oxide composite embedded with Fe_(3)O_(4) nanoparticles(Mn_(x)O_(y)/C@Fe_(3)O_(4))composites were obtained after heat treatment at 550℃ in N_(2).The crystal structure of the samples was analyzed using X-ray diffractometer with Cu Ka irradiation.Scanning electron microscopy(SEM)and high-resolution transmission electron microscopy(TEM)were used to observe microstructure and morphology of the samples.Nitrogen sorption measurements were obtained at 77 K on a Quantachrome surface area and pore size analyzer to measure the specific surface area and pore size distribution.XPS analysis was performed on X-ray photoelectron spectrometer with monochromatic Al Ka radiation.Magnetization curves of the samples were recorded with a Quantum Design physical property measurement system(PPMS-9)at room temperature.The electromagnetic parameters of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composites were measured using an Agilent N5230C network analyzer in the frequency range of 2-18 GHz.For electromagentic testing,the Mn,Oy/C@Fe34 composites and paraffin wax were mixed at 50°C according to the mass ratio of 15 wt.%,20 wt.%and 25 wt.%,and pressed in a special mold to make coaxial rings(inner diameter=3.04 mm,outer diameter-7 mm),which were denoted as S-1,S-2 and S-3,respectively.[Results]SEM images illustrate the preparation process of iD mesoporous carbon-coated manganese oxide embedded with Fe3O4 nanoparticles composites(Mn_(x)O_(y)/C@Fe_(3)O_(4)).Most of the manganese oxide(Mn,Oy)was reduced to granular after heat treatment,while the outer carbon layer remains its 1D morphology and the carbon layer is interspersed with Fe_(3)O_(4) nanoparticles.The diffraction peaks of MnO_(2) nanowires align well with the body-centered tetragonal a-MnO2.For the Mn_(x)O_(y)/C@Fe_(3)O_(4) composites,the signals of α-MnO_(2) disappears,followed by the emergence of Mn_(3)O_(4) and three prominent diffraction peaks for the cubic MnO.In addition,four weak diffraction peaks correspond to the magnetite Fe_(3)O_(4),consistent with the HRTEM results.The corresponding nitrogen adsorption-desorption isotherm and pore size distribution curve are presented to further analyze the mesoporous structure of composite.The surface composition and element valence states of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composite were investigated by using XPS.The polarization relaxation processes were analyzed according to the Debye theory which describes the relationship between e'and e".Besides the polarization loss,the contribution of the conduction loss plays an important role for the overall dielectric loss.The magnetization curve of Mn_(x)O_(y)/C@Fe_(3)O_(4) exhibits typical ferromagnetic behavior.The permittivity parameter(Co),defined as Co=u"(u)^(-2)f^(-1) determine the contribution of eddy current effect to magnetic loss.The tand values are all larger than those of tand,for the three samples,indicating that the loss capacity of Mn_(x)O_(y)/C@Fe_(3)O_(4) composites is mainly derived from the dielectric loss.Although tand,is smaller,it plays an important role in improving the impedance matching of Mn_(x)O_(y)/C@Fe_(3)O_(4) composites.When the filler loading is 15 wt.%,the RL of sample S-1 is about-10.0 dB at the thickness of 1.5 mm with narrow EAB.As the filler loading increased to 20 wt.%,the RL of sample S-2 reached-62.0 dB at a thickness of 2.2 mm and the EAB was 6.4 GHz at a small thickness of 1.7 mm.When the filler loading is further increased to 25 wt.%,the microwave absorption performance of sample S3 decreased significantly with a little region of RL<-10.0 dB at the thickness of 5.0 mm.The values of[Zin/Zol of the three samples at thicknesses of 1.5-5.0 mm were calculated.Due to good impedance matching of S-2,the incident EMW can enter the material and then can be dissipated through dipole polarization loss,interface polarization loss,conduction loss,eddy current loss and natural ferromagnetic resonance loss.[Conclusions]1D Mn_(x)O_(y)/C@Fe_(3)O_(4) was synthesized via a process involving the coating of polydopamine,adsorption of Fe(ll)salts and heat treatment,using MnO_(2) nanowires as templates.The multi-component heterostructure of the Mn_(x)O_(y)/C@Fe_(3)O_(4) composite(Mn_(3)O_(4),MnO,Fe_(3)O_(4),and C)enhances the interfacial interactions between the different phases,providing increased interface polarization loss under the action of an alternating electromagnetic field.The numerous defects and terminal groups in the mesoporous carbon provide abundant dipole polarization centers.Additionally,the presence of mesopores reduces the weight of the material while increasing the multiple scattering losses of the electromagnetic waves within the material.The ID carbon structure in the matrix forms a conductive network between adjacent fibers,facilitating electron migration and transition,thereby enhancing conductive loss.The incorporation of magnetic Fe_(3)O_(4) nanoparticles introduces eddy current loss and natural ferromagnetic resonance loss,thus increasing magnetic loss.Moreover,the synergistic effect between dielectric and magnetic losses improves the impedance matching of the material,leading to excellent EMW absorption performance.
文摘Objective To characterize transmembrane protein 68(TMEM68)in an alternative triacylglycerol(TAG)biosynthesis pathway,and determine the interplay between TMEM68 and the canonical TAG synthesis enzyme acyl-CoA:diacylglycerol acyltransferase(DGAT).Methods Effects of exogenous fatty acid and monoacylglycerol on TAG synthesis and lipid droplet(LD)formation in TMEM68 overexpression and knockout cells treated with DGAT inhibitor or not were investigated by comparing LD morphology,Oil Red O staining,and measurement of TAG levels.LDs were stained with fluorescence dye and observed by confocal fluorescence microscopy.TAG levels were determined with an enzyme-based triglyceride assay kit.Colocalization of TMEM68 and DGAT1 was detected by co-expression and confocal fluorescence microscopy and their interaction was determined by co-immunoprecipitation.RT-qPCR and immunoblotting assay were used to detect the expression of DGAT1.Results The synthesis of TAG catalyzed by TMEM68 was independent of DGAT activity.Surplus exogenous fatty acids and monoacylglycerol promoted TAG synthesis mainly through DGAT in human neuroblastoma cells.The LDs formed by TMEM68 were different in morphology from those by DGAT.In addition,TMEM68 and DGAT1 colocalized in the same endoplasmic reticulum(ER)compartment but did not interact physically.TMEM68 overexpression reduced the expression of DGAT1,the major DGAT enzyme involved in TAG synthesis,while TMEM68 knockout had little impact.Conclusion The TMEM68-mediated TAG synthesis pathway has distinct features from the canonical DGAT pathway,however,TMEM68 and DGAT may coregulate intracellular TAG levels.
基金Supported by the National Natural Science Foundation of China( 61974104)。
文摘Microstrip transmission lines connecting to the millimeter wave radar chip and antenna significantly affect the radiation efficiency and bandwidth of the antenna.Here,a wideband non-uniform wavy microstrip line for complex impedance in automotive radar frequency range is proposed.Unlike the gradient transmission line,the wavy structure is composed of periodically semi-circular segments.By adjusting the radius of the semi-circular,the surface current is varied and concentrated on the semi-circular segments,allowing a wider tunability range of the resonant frequency.The results reveal that the bandwidth of the loaded wavy transmission line antenna improves to 9.37 GHz,which is 5.81 GHz wider than that of the loaded gradient line.The gain and the half power beam width of the loaded antenna are about 14.69 dB and 9.58°,respectively.The proposed non-uniform microstrip line scheme may open up a route for realizing wideband millimeter-wave automotive radar applications.
基金National Natural Science Foundation of China(62471097,62471115,62471101)Natural Science Foundation of Sichuan Province(2025ZNSFSC0537)Stable Support Porject of 12th Research Institute of China Electronics Technology Group Corporation。
文摘Microstrip traveling wave tubes(TWTs)have garnered significant attention due to their potential applications in communication,defense,and industrial systems.This paper presents a compact W-band dual-channel TWT,utilizing a U-shaped microstrip meander-line slow-wave structure(SWS).High-frequency characteristics are analyzed through simulation and cold tests.The results demonstrate that adjusting structural parameters effectively optimizes the S-parameters.Particle-in-cell(PIC)simulations with an 18.8 kV,0.1 A electron beam predict an output power of 18 W with a gain of 14 dB.Experimental measurements of S-parameters are conducted using three substrate materials:Rogers 5880,quartz,and diamond.The quartz substrate exhibits the closest agreement with simulation results.The results advance the development of the microstrip-based TWTs for high-data-rate communication systems.
文摘There is nonradiative recombination in waveguide region owing to severe carrier leakage,which in turn reduces output power and wall-plug efficiency.In this paper,we designed a novel epitaxial structure,which suppresses carrier leakage by inserting n-Ga_(0.55)In_(0.45)P and p-GaAs_(0.6)P_(0.4) between barriers and waveguide layers,respectively,to modulate the energy band structure and to increase the height of barrier.The results show that the leakage current density reduces by 87.71%,compared to traditional structure.The nonradiative recombination current density of novel structure reduces to 37.411 A/cm^(2),and the output power reaches 12.80 W with wall-plug efficiency of 78.24%at an injection current density 5 A/cm^(2) at room temperature.In addition,the temperature drift coefficient of center wavelength is 0.206 nm/℃at the temperature range from 5℃to 65℃,and the slope of fitted straight line of threshold current with temperature variation is 0.00113.The novel epitaxial structure provides a theoretical basis for achieving high-power laser diode.
基金Supported by the Major Science and Technology Project of Jilin Province(20220301010GX)the International Scientific and Technological Cooperation(20240402071GH).
文摘The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed.
基金supported by the National Natural Science Foundation of China(22472023,22202037)the Jilin Province Science and Technology Development Program(20250102077JC)the Fundamental Research Funds for the Central Universities(2412024QD014,2412023QD019).
文摘Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit lower toxicity and a more mature preparation process.Unlike hydrogen fuel cells,DEFCs provide superior storage and transport feasibility,as well as cost-effectiveness,significantly enhancing their commercial viability.However,the stable C-C bond in ethanol creates a high activation energy barrier,often resulting in incomplete electrooxidation.Current commercial platinum(Pt)-and palladium(Pd)-based catalysts demonstrate low C-C bond cleavage efficiency(<7.5%),severely limiting DEFC energy output and power density.Furthermore,high catalyst costs and insufficient activity impede large-scale commercialization.Recent advances in DEFC anode catalyst design have focused on optimizing material composition and elucidating catalytic mechanisms.This review systematically examines developments in ethanol electrooxidation catalysts over the past five years,highlighting strategies to improve C1 pathway selectivity and C-C bond activation.Key approaches,such as alloying,nanostructure engineering,and interfacial synergy effects,are discussed alongside their mechanistic implications.Finally,we outline current challenges and future prospects for DEFC commercialization.
