We used 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol（A） as the host molecule to selectively recognize the component 1,8-cineole（B） in the volatile oil of Flos Magnoliae（Xin Yi）. The inclusion compound（A+B） was f...We used 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol（A） as the host molecule to selectively recognize the component 1,8-cineole（B） in the volatile oil of Flos Magnoliae（Xin Yi）. The inclusion compound（A+B） was formed as crystalline, and the structure was confirmed by means of IR, （（）1H NMR）, and single crystal X-ray diffraction, with the 1∶2 molar ratios of the host to the guest. The component 1,8-cineole（B） was selectively isolated from the inclusion compound（A+B） by Kugelrohr vaccum technology, and then further characterized by IR, （）1H NMR and （）13C NMR. The whole components in the volatile oil of Flos Magnoliae（Xin Yi） and the isolation effect of 1,8-cineole isolated from inclusion crystals were analyzed by GC and GC-MS, respectively. The result indicate that the good isolation effect is given by the inclusion method, with purity and yield of the component 1,8-cineole（B） separated from the volatile oil of Flos Magnoliae are 100% and 85%, respectively.展开更多
0引言近十年来多元金属多硒化合物的合成是材料科学和固体化学领域中的研究热点[1].其合成方法有高温固相法、熔盐法和溶剂热法.固相合成反应一般是在高温(约800℃以上)的条件下进行的.1987年Ibers[2]等提出了反应性熔盐法(reactive mol...0引言近十年来多元金属多硒化合物的合成是材料科学和固体化学领域中的研究热点[1].其合成方法有高温固相法、熔盐法和溶剂热法.固相合成反应一般是在高温(约800℃以上)的条件下进行的.1987年Ibers[2]等提出了反应性熔盐法(reactive molten salt method),在中温(375℃)条件下成功地合成了多元金属硒(碲)化合物.展开更多
文摘We used 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol（A） as the host molecule to selectively recognize the component 1,8-cineole（B） in the volatile oil of Flos Magnoliae（Xin Yi）. The inclusion compound（A+B） was formed as crystalline, and the structure was confirmed by means of IR, （（）1H NMR）, and single crystal X-ray diffraction, with the 1∶2 molar ratios of the host to the guest. The component 1,8-cineole（B） was selectively isolated from the inclusion compound（A+B） by Kugelrohr vaccum technology, and then further characterized by IR, （）1H NMR and （）13C NMR. The whole components in the volatile oil of Flos Magnoliae（Xin Yi） and the isolation effect of 1,8-cineole isolated from inclusion crystals were analyzed by GC and GC-MS, respectively. The result indicate that the good isolation effect is given by the inclusion method, with purity and yield of the component 1,8-cineole（B） separated from the volatile oil of Flos Magnoliae are 100% and 85%, respectively.
文摘0引言近十年来多元金属多硒化合物的合成是材料科学和固体化学领域中的研究热点[1].其合成方法有高温固相法、熔盐法和溶剂热法.固相合成反应一般是在高温(约800℃以上)的条件下进行的.1987年Ibers[2]等提出了反应性熔盐法(reactive molten salt method),在中温(375℃)条件下成功地合成了多元金属硒(碲)化合物.
