The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic fiel...The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic field on the structure capability after thermal plastic forming, the experimental methods were adopted to compare the microcosmic structure of the LY12 aluminium alloy test pieces before and after the powerful alternate magnetic field treatment. The mechanism of the structure refining was analyzed theoretically. According to the effect rule of the alternate magnetic field on critical grain growth work and the magnetic vibration-constriction mechanism, the structure dynamics factors were analyzed. The results show that, after a certain powerful alternate magnetic field treatment, the mechanical capability of the LY12 aluminium alloy after thermal plastic forming can be reinforced, the structure intertwist deriving from the thermal plastic forming becomes even and the branch crystal is also smashed, consequently refines the structure. The powerful alternate magnetic field treatment can be regarded as an effective method to improve metal structure performance after heat plastic forming.展开更多
This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as poly...This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as polymer binder. Thermal decomposition of PBXs was undertaken by applying simultaneous thermal analysis(STA) and differential scanning calorimetry(DSC) to investigate influence of the HMX amount on thermal behavior and its kinetics. Thermogravimetric analysis(TGA) indicated that the thermal decomposition of PBXs based on mixture of HMX and TATB was occurred in a three-steps. The first step was mainly due to decomposition of HMX. The second step was ascribed due to decomposition of TATB, while the third step was occurred due to decomposition of the polymer matrices. The thermal decomposition % was increased with increasing HMX amount. The kinetics related to thermal decomposition were investigated under non-isothermal for a single heating rate measurement. The variation in the activation energy of PBXs based on mixture of HMX and TATB was observed with varying the HMX amount. The kinetics from the results of TGA data at various heating rates under non-isothermal conditions were also calculated by Flynn—Wall—Ozawa(FWO) and Kissinger-Akahira-Sunose(KAS)methods. The activation energies calculated by employing FWO method were very close to those obtained by KAS method. The mean activation energy calculated by FWO and KAS methods was also a good agreement with the activation energy obtained from single heating rate measurement in the first step decomposition.展开更多
Preparation of cast double-propellant grains depends on the ability of nitrocellulose powder to swell and coalesce into a coherent mass when treated with a suitable solvent.The cast double-base process has been develo...Preparation of cast double-propellant grains depends on the ability of nitrocellulose powder to swell and coalesce into a coherent mass when treated with a suitable solvent.The cast double-base process has been developed into a highly versatile technique for manufacturing solid rocket charges.Propellants manufactured by this process provide a wide range of energies and burning rates.Successful preparation of cast double-base propellant grains has been performed using compatible casting liquid with the casting powder.BuNENA was used as an energetic plasticizer for manufacturing of casting powder.Burning rate measurements have been performed using closed bomb SV-2to investigate the burning behavior along a wide range of operating pressure.Plateau burning had been detected in pressure range(50-70)×105 Pa for the composition included BuNENA.DTA and TGA thermal analysis were conducted to evaluate the thermal behavior of the prepared cast double-base propellants.Results from DTA were used to calculate the apparent activation energy.展开更多
基金Project(50675190) supported by the National Natural Science Foundation of China
文摘The powerful alternate magnetic field treatment is an effective not-heat treatment, which improves the coriaceous performance of the material. In order to reveal the effect rule of the powerful alternate magnetic field on the structure capability after thermal plastic forming, the experimental methods were adopted to compare the microcosmic structure of the LY12 aluminium alloy test pieces before and after the powerful alternate magnetic field treatment. The mechanism of the structure refining was analyzed theoretically. According to the effect rule of the alternate magnetic field on critical grain growth work and the magnetic vibration-constriction mechanism, the structure dynamics factors were analyzed. The results show that, after a certain powerful alternate magnetic field treatment, the mechanical capability of the LY12 aluminium alloy after thermal plastic forming can be reinforced, the structure intertwist deriving from the thermal plastic forming becomes even and the branch crystal is also smashed, consequently refines the structure. The powerful alternate magnetic field treatment can be regarded as an effective method to improve metal structure performance after heat plastic forming.
基金DRDO(TBR-1251)for funding and awarding the Project
文摘This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as polymer binder. Thermal decomposition of PBXs was undertaken by applying simultaneous thermal analysis(STA) and differential scanning calorimetry(DSC) to investigate influence of the HMX amount on thermal behavior and its kinetics. Thermogravimetric analysis(TGA) indicated that the thermal decomposition of PBXs based on mixture of HMX and TATB was occurred in a three-steps. The first step was mainly due to decomposition of HMX. The second step was ascribed due to decomposition of TATB, while the third step was occurred due to decomposition of the polymer matrices. The thermal decomposition % was increased with increasing HMX amount. The kinetics related to thermal decomposition were investigated under non-isothermal for a single heating rate measurement. The variation in the activation energy of PBXs based on mixture of HMX and TATB was observed with varying the HMX amount. The kinetics from the results of TGA data at various heating rates under non-isothermal conditions were also calculated by Flynn—Wall—Ozawa(FWO) and Kissinger-Akahira-Sunose(KAS)methods. The activation energies calculated by employing FWO method were very close to those obtained by KAS method. The mean activation energy calculated by FWO and KAS methods was also a good agreement with the activation energy obtained from single heating rate measurement in the first step decomposition.
文摘Preparation of cast double-propellant grains depends on the ability of nitrocellulose powder to swell and coalesce into a coherent mass when treated with a suitable solvent.The cast double-base process has been developed into a highly versatile technique for manufacturing solid rocket charges.Propellants manufactured by this process provide a wide range of energies and burning rates.Successful preparation of cast double-base propellant grains has been performed using compatible casting liquid with the casting powder.BuNENA was used as an energetic plasticizer for manufacturing of casting powder.Burning rate measurements have been performed using closed bomb SV-2to investigate the burning behavior along a wide range of operating pressure.Plateau burning had been detected in pressure range(50-70)×105 Pa for the composition included BuNENA.DTA and TGA thermal analysis were conducted to evaluate the thermal behavior of the prepared cast double-base propellants.Results from DTA were used to calculate the apparent activation energy.
