Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass...Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass loadings crucial for practical use.The root of these challenges lies in the mechanical instability of the material,which subsequently leads to the structural failure of the electrode.Here,we present a novel synthesis of a composite combining expanded graphite and silicon nanoparticles.This composite features a unique interlayer-bonded graphite structure,achieved through the application of a modified spark plasma sintering method.Notably,this innovative structure not only facilitates efficient ion and electron transport but also provides exceptional mechanical strength(Vickers hardness:up to658 MPa,Young's modulus:11.6 GPa).This strength effectively accommodates silicon expansion,resulting in an impressive areal capacity of 2.9 mA h cm^(-2)(736 mA h g^(-1)) and a steady cycle life(93% after 100cycles).Such outsta nding performance is paired with features appropriate for large-scale industrial production of silicon batteries,such as active mass loading of at least 3.9 mg cm^(-2),a high-tap density electrode material of 1.68 g cm^(-3)(secondary clusters:1.12 g cm^(-3)),and a production yield of up to 1 kg per day.展开更多
The engineblock production lines need high speed tapping with tungsten carbide taps. In the tapping process, the machining precision and the tool life of taps are directly influenced by tapping forces. And the paramet...The engineblock production lines need high speed tapping with tungsten carbide taps. In the tapping process, the machining precision and the tool life of taps are directly influenced by tapping forces. And the parameter optimization of tap structures is also correlated with the variation of tapping forces. Therefore, the study of tapping forces is necessary in developing new style taps. Several experiments about some novel carbide taps are performed on a vertical machining center by a Kistler dynamometer system in blind tapping both gray cast iron and ductile cast iron. And the variations of tapping forces are analyzed in tapping-in and tapping-out periods. It indicates that cutting forces hardly vary with the tap wear in tapping cast iron. Contrarily, tapping forces are closely correlated with the holding method. Besides, it also depends on the helix angle, the flute numbers and the plasticity of the work material to some extent.展开更多
The fifth generation （5G） wireless communication is currently a hot research topic and wireless communication systems on high speed railways （HSR） are important applications of 5G technologies. Existing stud- ies ...The fifth generation （5G） wireless communication is currently a hot research topic and wireless communication systems on high speed railways （HSR） are important applications of 5G technologies. Existing stud- ies about 5G wireless systems on high speed railways （HSR） often utilize ideal channel parameters and are usually based on simple scenarios. In this paper, we evaluate the down- link throughput of 5G HSR communication systems on three typical scenarios including urban, cutting and viaduct with three different channel estimators. The channel parameters of each scenario are generated with tapped delay line （TDL） models through ray-tracing sim- ulations, which can be considered as a good match to practical situations. The channel estimators including least square （LS）, linear minimum mean square error （LMMSE）, and our proposed historical information based ba- sis expansion model （HiBEM）. We analyze the performance of the HiBEM estimator in terms of mean square error （MSE） and evaluate the system throughputs with different channel estimates over each scenario. Simulation results are then provided to corroborate our proposed studies. It is shown that our HiBEM estimator outperforms other estimators and that the sys-tem throughput can reach the highest point in the viaduct scenario.展开更多
基金supported by the National Research Foundation, Prime Minister’s Office, Singapore, under its Competitive Research Programme (CRP award number NRF-CRP22-2019-008)Medium-Sized Centre Programme (CA2DM)+1 种基金the Ministry of Education of Singapore, under its Research Centre of Excellence award to the Institute for Functional Intelligent Materials (I-FIM, Project No. EDUNC-33-18-279-V12)by the EDB Singapore, under its Space Technology Development Programme (S2219013-STDP)。
文摘Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass loadings crucial for practical use.The root of these challenges lies in the mechanical instability of the material,which subsequently leads to the structural failure of the electrode.Here,we present a novel synthesis of a composite combining expanded graphite and silicon nanoparticles.This composite features a unique interlayer-bonded graphite structure,achieved through the application of a modified spark plasma sintering method.Notably,this innovative structure not only facilitates efficient ion and electron transport but also provides exceptional mechanical strength(Vickers hardness:up to658 MPa,Young's modulus:11.6 GPa).This strength effectively accommodates silicon expansion,resulting in an impressive areal capacity of 2.9 mA h cm^(-2)(736 mA h g^(-1)) and a steady cycle life(93% after 100cycles).Such outsta nding performance is paired with features appropriate for large-scale industrial production of silicon batteries,such as active mass loading of at least 3.9 mg cm^(-2),a high-tap density electrode material of 1.68 g cm^(-3)(secondary clusters:1.12 g cm^(-3)),and a production yield of up to 1 kg per day.
文摘The engineblock production lines need high speed tapping with tungsten carbide taps. In the tapping process, the machining precision and the tool life of taps are directly influenced by tapping forces. And the parameter optimization of tap structures is also correlated with the variation of tapping forces. Therefore, the study of tapping forces is necessary in developing new style taps. Several experiments about some novel carbide taps are performed on a vertical machining center by a Kistler dynamometer system in blind tapping both gray cast iron and ductile cast iron. And the variations of tapping forces are analyzed in tapping-in and tapping-out periods. It indicates that cutting forces hardly vary with the tap wear in tapping cast iron. Contrarily, tapping forces are closely correlated with the holding method. Besides, it also depends on the helix angle, the flute numbers and the plasticity of the work material to some extent.
基金supported by the National Natural Science Foundation of China(Grant Nos.61522109,61671253,61571037and 91738201)the Fundamental Research Funds for the Central Universities(No.2016JBZ006)+1 种基金the Natural Science Foundation of Jiangsu Province(Grant Nos.BK20150040and BK20171446)the Key Project of Natural Science Research of Higher Education Institutions of Jiangsu Province(No.15KJA510003)
文摘The fifth generation （5G） wireless communication is currently a hot research topic and wireless communication systems on high speed railways （HSR） are important applications of 5G technologies. Existing stud- ies about 5G wireless systems on high speed railways （HSR） often utilize ideal channel parameters and are usually based on simple scenarios. In this paper, we evaluate the down- link throughput of 5G HSR communication systems on three typical scenarios including urban, cutting and viaduct with three different channel estimators. The channel parameters of each scenario are generated with tapped delay line （TDL） models through ray-tracing sim- ulations, which can be considered as a good match to practical situations. The channel estimators including least square （LS）, linear minimum mean square error （LMMSE）, and our proposed historical information based ba- sis expansion model （HiBEM）. We analyze the performance of the HiBEM estimator in terms of mean square error （MSE） and evaluate the system throughputs with different channel estimates over each scenario. Simulation results are then provided to corroborate our proposed studies. It is shown that our HiBEM estimator outperforms other estimators and that the sys-tem throughput can reach the highest point in the viaduct scenario.
