A three-dimensional diesel particulate filter(DPF)simulation model was developed by using AVL software FIRE to study the effects of four factors on soot particle distributions along the axial and radial directions in ...A three-dimensional diesel particulate filter(DPF)simulation model was developed by using AVL software FIRE to study the effects of four factors on soot particle distributions along the axial and radial directions in the DPF after the model accuracy was validated.An orthogonal test method was used to determine the importance and weights of the design of experiments(DoE)factors such as the expanding angle,the number of channels per square inch,and the exhaust mass flow rate.The effects of these factors on the uniformity of the soot particle distributions were also analyzed.The results show that when the soot loading time was 400 s,the soot particles inside the DPF along the axial direction exhibited a bowl shape,which was high on the both ends and low in the middle.The uniformity of the axial distribution of soot particles reduces significantly with an increase in the number of channels per square inch.The uniformity of the radial distribution reduced with an increase in the expanding angle of the divergent tube.Based on the impacts on the axial uniformity,the three most influencing factors in a descending order are the number of channels per square inch,the exhaust mass flow rate,and the expanding angle of the divergent tube.展开更多
A combined computational and experimental investigation to examine temperature and soot volume fraction in coflow ethylene-air diffusion flames was presented.A numerical simulation was conducted by using a relatively ...A combined computational and experimental investigation to examine temperature and soot volume fraction in coflow ethylene-air diffusion flames was presented.A numerical simulation was conducted by using a relatively detailed gas-phase chemistry and complex thermal and transport properties coupled with a semi-empirical two-equation soot model.Thermal radiation was calculated using the discrete ordinates method.An image processing technique and a decoupled reconstruction method were used to simultaneously measure the distributions of temperature and soot volume fraction.The results show that the maximum error for temperature does not exceed 10% between the prediction and the measurement.And the maximum error is 6.9% for soot volume fraction between prediction and measurement.Additional simulations were performed to explore the effects of global equivalence ratio on diffusion flames and the soot formation.The results display that the soot formation increases with decreasing the coflow air velocity.And the soot formation in each case appears in the annular region,where the temperature ranges from about 1 000 K to 2 000 K and the profile becomes taller and wider when the coflow air is decreased.展开更多
Combustion chamber components （cylinder head, cylinder liner, piston assembly and oil film） are treated as a coupled body. Based on the three-dimensional numerical simulation of heat transfer of the coupled body, a ...Combustion chamber components （cylinder head, cylinder liner, piston assembly and oil film） are treated as a coupled body. Based on the three-dimensional numerical simulation of heat transfer of the coupled body, a coupled three-dimensional calculation model for the in-cylinder working process and the combustion chamber components was built with domain decomposition and boundary coupling method, in which the coupled three-dimensional simulation of in-cylindcr working process and the combustion chamber components was adopted. The simulation was applied in the influence investigation of the space non-uniformity in heat transfer among combustion chamber components on the generation of in-cylinder emissions. The results show that the space non-uniformity in heat transfer among the combustion chamber components has great influence on the generation of in-cylinder NOx emissions. The heat transfer space non-uniformity of combustion chamber components has little effect on soot formation, and far less effect on soot formation than on NOx. Under two situations of different wall temperature distributions, the soot in cylinder is different by 1.3% when exhaust valves are open.展开更多
Diesel soot subjected to high exhaust temperature suffers from thermal ageing,which is difficult to be removed by regeneration process.Based on the thermogravimetric(TG)analysis and images by high resolution transmiss...Diesel soot subjected to high exhaust temperature suffers from thermal ageing,which is difficult to be removed by regeneration process.Based on the thermogravimetric(TG)analysis and images by high resolution transmission electron microscope(HRTEM),effects of thermal ageing temperature,ageing time and oxygen concentration on oxidation characteristic of soot are investigated.The activation energy of soot increases with the increase of ageing temperature and oxygen concentration.The activation energy increases rapidly when the ageing time is less than 45 min,and then it keeps in a value of 157 kJ/mol when the ageing time is between 45 and 60 min.Compared to the soot without thermal ageing,the shape of ageing soot particles presents shorter diameter and more regular circle by observing soot nanostructure.With the increase of ageing temperature,ageing time and oxygen concentration,the more stable structure of“shell and core”is shown in the basic carbon.The soot has an increased fringe length,decreased tortuosity and separation distance after thermal ageing process,which leads to the deepening of the disorder degree of soot nanostructures and reduction of soot oxidation activity.Consequently,the thermal ageing process should be avoided in order to optimize the active regeneration strategy.展开更多
This paper examines the effect of equalizing ignition delay in a compression ignition engine.Two sets of tests were conducted,i.e.a set of constant injection timing tests with start of fuel injection at 10°crank ...This paper examines the effect of equalizing ignition delay in a compression ignition engine.Two sets of tests were conducted,i.e.a set of constant injection timing tests with start of fuel injection at 10°crank angle degree(CAD)before top dead center(BTDC)and a set of constant ignition timing tests while also keeping the 10℃AD BTDC injection and adding ignition improver(2-ethylhexylnitrate-,2-EHN)to the fuel mixtures.Soot particles were characterized using DMS-500 instrument in terms of mass,size,and number.The experimental results showed that adding 2-EHN to the model fuel blends reduced the soot surface area,soot mass concentration and soot mean size.Replacing 20 vol%of a C 7-heptane with 20 vol%methyl-decanoate(an oxygenated C 11 molecule)did not affect the ignition delay or rate of fuel air premixing,the peak in-cylinder pressure or heat release rates.Toluene addition(0−22.5 vol%)to heptane increased the mean size of the soot particles generated by only 3%while also resulted in a slight increase in the peak cylinder pressure and peak heat release rates.Blending toluene and methyl-decanoate into heptane without adding 2-EHN increased the premix phase fraction by at least 13%.However,by adding 2-EHN(4×10^(−4)−1.5×10^(−3)),the premixed phase fraction decreased by at least 11%.展开更多
Gasoline soot particles pose a severe threat to the ecological environment and human health,but they can be potentially filtered out by using catalytic gasoline particulate filter(cGPF),whose core component is a catal...Gasoline soot particles pose a severe threat to the ecological environment and human health,but they can be potentially filtered out by using catalytic gasoline particulate filter(cGPF),whose core component is a catalyst coating.To develop more effective catalyst coatings with excellent activity,stability,and water resistance,a kind of composite oxide MnO_(x)/CeO_(2)-ZrO_(2) was synthesized using different methods,and its soot oxidation performance was evaluated under low O_(2) concentrations.Herein,MnO_(x)/CeO_(2)-ZrO_(2) prepared by impregnation(abbreviated as MCZ-IM)exhibits a T_(50)(temperature required for 50% soot conversion)of 329℃in 1%O_(2) and 370℃ in 0.5%O_(2),displaying better comprehensive performance when compared to catalysts prepared by high-energy ball milling(abbreviated as MCZ-HB)and co-precipitation(abbreviated as MCZ-CP).Structure-activity relationship reveals that soot oxidation under low O_(2) concentrations is weakly correlated with textural and structural properties,but strongly depends on the generation and migration of active oxygen species(AOS),especially superoxide(O_(2)^(-))and peroxide(O_(2)^(2-))anions,which are linked to redox properties,oxygen storage and release capacity,as well as amount of oxygen vacancies.The impregnation method enhances oxygen species adsorption,activation and desorption more effectively,endowing it with a more effective approach to enhancing AOS generation and mobility.Therefore,this study not only provides a preparation strategy for particulate matter oxidation catalysts applicable to actual operating conditions,but also offers insights into the migration of AOS at low O_(2) concentrations.展开更多
基金Project(52066008)supported by the National Natural Science Foundation,ChinaProject(2018FA030)supported by Yunnan Province Fundamental Research Key Project Foundation,China+1 种基金Project(2018ZE001)supported by Yunnan Province Major Science and Technology Project Foundation,ChinaProject(202005AG070057)supported by Yunnan Province Science and Technology Innovation Funds for key Laboratories,China。
文摘A three-dimensional diesel particulate filter(DPF)simulation model was developed by using AVL software FIRE to study the effects of four factors on soot particle distributions along the axial and radial directions in the DPF after the model accuracy was validated.An orthogonal test method was used to determine the importance and weights of the design of experiments(DoE)factors such as the expanding angle,the number of channels per square inch,and the exhaust mass flow rate.The effects of these factors on the uniformity of the soot particle distributions were also analyzed.The results show that when the soot loading time was 400 s,the soot particles inside the DPF along the axial direction exhibited a bowl shape,which was high on the both ends and low in the middle.The uniformity of the axial distribution of soot particles reduces significantly with an increase in the number of channels per square inch.The uniformity of the radial distribution reduced with an increase in the expanding angle of the divergent tube.Based on the impacts on the axial uniformity,the three most influencing factors in a descending order are the number of channels per square inch,the exhaust mass flow rate,and the expanding angle of the divergent tube.
基金Projects(50806024,50806023 and 50806026) supported by the National Natural Science Foundation of China
文摘A combined computational and experimental investigation to examine temperature and soot volume fraction in coflow ethylene-air diffusion flames was presented.A numerical simulation was conducted by using a relatively detailed gas-phase chemistry and complex thermal and transport properties coupled with a semi-empirical two-equation soot model.Thermal radiation was calculated using the discrete ordinates method.An image processing technique and a decoupled reconstruction method were used to simultaneously measure the distributions of temperature and soot volume fraction.The results show that the maximum error for temperature does not exceed 10% between the prediction and the measurement.And the maximum error is 6.9% for soot volume fraction between prediction and measurement.Additional simulations were performed to explore the effects of global equivalence ratio on diffusion flames and the soot formation.The results display that the soot formation increases with decreasing the coflow air velocity.And the soot formation in each case appears in the annular region,where the temperature ranges from about 1 000 K to 2 000 K and the profile becomes taller and wider when the coflow air is decreased.
基金Projects(50576008,50876016,51006015) supported by the National Natural Science Foundation of ChinaProject(20062180) supported by the Natural Science Foundation of Liaoning Province, ChinaProject(20100470070) supported by China Postdoctoral Science Foundation
文摘Combustion chamber components （cylinder head, cylinder liner, piston assembly and oil film） are treated as a coupled body. Based on the three-dimensional numerical simulation of heat transfer of the coupled body, a coupled three-dimensional calculation model for the in-cylinder working process and the combustion chamber components was built with domain decomposition and boundary coupling method, in which the coupled three-dimensional simulation of in-cylindcr working process and the combustion chamber components was adopted. The simulation was applied in the influence investigation of the space non-uniformity in heat transfer among combustion chamber components on the generation of in-cylinder emissions. The results show that the space non-uniformity in heat transfer among the combustion chamber components has great influence on the generation of in-cylinder NOx emissions. The heat transfer space non-uniformity of combustion chamber components has little effect on soot formation, and far less effect on soot formation than on NOx. Under two situations of different wall temperature distributions, the soot in cylinder is different by 1.3% when exhaust valves are open.
基金Project(51676167)supported by the National Natural Science Foundation of ChinaProject(17TD0035)supported by the Sichuan Provincial Scientific Research Innovation Team Program,ChinaProjects(2017TD0026,2015TD0021)supported by Science&Technology Department of Sichuan Province,China。
文摘Diesel soot subjected to high exhaust temperature suffers from thermal ageing,which is difficult to be removed by regeneration process.Based on the thermogravimetric(TG)analysis and images by high resolution transmission electron microscope(HRTEM),effects of thermal ageing temperature,ageing time and oxygen concentration on oxidation characteristic of soot are investigated.The activation energy of soot increases with the increase of ageing temperature and oxygen concentration.The activation energy increases rapidly when the ageing time is less than 45 min,and then it keeps in a value of 157 kJ/mol when the ageing time is between 45 and 60 min.Compared to the soot without thermal ageing,the shape of ageing soot particles presents shorter diameter and more regular circle by observing soot nanostructure.With the increase of ageing temperature,ageing time and oxygen concentration,the more stable structure of“shell and core”is shown in the basic carbon.The soot has an increased fringe length,decreased tortuosity and separation distance after thermal ageing process,which leads to the deepening of the disorder degree of soot nanostructures and reduction of soot oxidation activity.Consequently,the thermal ageing process should be avoided in order to optimize the active regeneration strategy.
文摘This paper examines the effect of equalizing ignition delay in a compression ignition engine.Two sets of tests were conducted,i.e.a set of constant injection timing tests with start of fuel injection at 10°crank angle degree(CAD)before top dead center(BTDC)and a set of constant ignition timing tests while also keeping the 10℃AD BTDC injection and adding ignition improver(2-ethylhexylnitrate-,2-EHN)to the fuel mixtures.Soot particles were characterized using DMS-500 instrument in terms of mass,size,and number.The experimental results showed that adding 2-EHN to the model fuel blends reduced the soot surface area,soot mass concentration and soot mean size.Replacing 20 vol%of a C 7-heptane with 20 vol%methyl-decanoate(an oxygenated C 11 molecule)did not affect the ignition delay or rate of fuel air premixing,the peak in-cylinder pressure or heat release rates.Toluene addition(0−22.5 vol%)to heptane increased the mean size of the soot particles generated by only 3%while also resulted in a slight increase in the peak cylinder pressure and peak heat release rates.Blending toluene and methyl-decanoate into heptane without adding 2-EHN increased the premix phase fraction by at least 13%.However,by adding 2-EHN(4×10^(−4)−1.5×10^(−3)),the premixed phase fraction decreased by at least 11%.
基金Advanced Materials-National Science and Technology Major Project(2024ZD0606500)National Natural Science Foundation of China(21902110)Sichuan Provincial Science Foundation(2023NSFSC0093)。
文摘Gasoline soot particles pose a severe threat to the ecological environment and human health,but they can be potentially filtered out by using catalytic gasoline particulate filter(cGPF),whose core component is a catalyst coating.To develop more effective catalyst coatings with excellent activity,stability,and water resistance,a kind of composite oxide MnO_(x)/CeO_(2)-ZrO_(2) was synthesized using different methods,and its soot oxidation performance was evaluated under low O_(2) concentrations.Herein,MnO_(x)/CeO_(2)-ZrO_(2) prepared by impregnation(abbreviated as MCZ-IM)exhibits a T_(50)(temperature required for 50% soot conversion)of 329℃in 1%O_(2) and 370℃ in 0.5%O_(2),displaying better comprehensive performance when compared to catalysts prepared by high-energy ball milling(abbreviated as MCZ-HB)and co-precipitation(abbreviated as MCZ-CP).Structure-activity relationship reveals that soot oxidation under low O_(2) concentrations is weakly correlated with textural and structural properties,but strongly depends on the generation and migration of active oxygen species(AOS),especially superoxide(O_(2)^(-))and peroxide(O_(2)^(2-))anions,which are linked to redox properties,oxygen storage and release capacity,as well as amount of oxygen vacancies.The impregnation method enhances oxygen species adsorption,activation and desorption more effectively,endowing it with a more effective approach to enhancing AOS generation and mobility.Therefore,this study not only provides a preparation strategy for particulate matter oxidation catalysts applicable to actual operating conditions,but also offers insights into the migration of AOS at low O_(2) concentrations.
