在强光照射下,CdS量子点易发生光腐蚀现象,通过金属掺杂和复合的方式可以提高CdS的光催化性能和光稳定性。采用水热法合成了Zn掺杂CdS/g-C_(3)N_(4)复合纳米材料(Zn-CdS/g-C_(3)N_(4))。利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、...在强光照射下,CdS量子点易发生光腐蚀现象,通过金属掺杂和复合的方式可以提高CdS的光催化性能和光稳定性。采用水热法合成了Zn掺杂CdS/g-C_(3)N_(4)复合纳米材料(Zn-CdS/g-C_(3)N_(4))。利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)和傅里叶变换红外光谱(FT-IR)等手段对Zn-CdS/g-C_(3)N_(4)复合材料的形貌、结构和组成等进行了表征。结果表明,Zn-CdS纳米颗粒附着在g-C_(3)N_(4)表面上,从而形成Zn-CdS/g-C_(3)N_(4)复合材料,且复合后材料带隙减小,光生电子-空穴复合率降低。在500 W Xe灯照射下,研究了Zn-CdS/g-C_(3)N_(4)对罗丹明B(RhB)的光催化降解性能。在最优条件下,光照40 min后,所制备的Zn-CdS/g-C_(3)N_(4)对RhB的光催化降解效率达99%。此外,所合成的Zn-CdS/g-C_(3)N_(4)复合材料光稳定性较高、可再生性好。这归因于Zn和Cd的协同作用以及与g-C_(3)N_(4)的复合,促进了光生载流子的分离和转移。展开更多
The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper...The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper presents a new approach to rank the alternatives by G1-coefficient of variation method.The focus of this approach is the use of the combination weighing,which is able to compensate for the deficiencies in the method of evaluation index single weighing.In the case study,an appropriate evaluation index system was established to determine the evaluation value of each ventilation mode.Then the proposed approach was used to select the best development face ventilation mode.The result shows that the proposed approach is able to rank the alternative development face ventilation mode reasonably,the combination weighing method had the advantages of both subjective and objective weighing methods in that it took into consideration of both the experience and wisdom of experts,and the new changes in objective conditions.This approach provides a more reasonable and reliable procedure to analyse and evaluate different ventilation modes.展开更多
文摘在强光照射下,CdS量子点易发生光腐蚀现象,通过金属掺杂和复合的方式可以提高CdS的光催化性能和光稳定性。采用水热法合成了Zn掺杂CdS/g-C_(3)N_(4)复合纳米材料(Zn-CdS/g-C_(3)N_(4))。利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)和傅里叶变换红外光谱(FT-IR)等手段对Zn-CdS/g-C_(3)N_(4)复合材料的形貌、结构和组成等进行了表征。结果表明,Zn-CdS纳米颗粒附着在g-C_(3)N_(4)表面上,从而形成Zn-CdS/g-C_(3)N_(4)复合材料,且复合后材料带隙减小,光生电子-空穴复合率降低。在500 W Xe灯照射下,研究了Zn-CdS/g-C_(3)N_(4)对罗丹明B(RhB)的光催化降解性能。在最优条件下,光照40 min后,所制备的Zn-CdS/g-C_(3)N_(4)对RhB的光催化降解效率达99%。此外,所合成的Zn-CdS/g-C_(3)N_(4)复合材料光稳定性较高、可再生性好。这归因于Zn和Cd的协同作用以及与g-C_(3)N_(4)的复合,促进了光生载流子的分离和转移。
基金Projects(51504286,51374242)supported by the National Natural Science Foundation of ChinaProject(2015M572270)supported by China Postdoctoral Science FoundationProject(2015RS4004)supported by the Science and Technology Plan of Hunan Province,China
文摘The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper presents a new approach to rank the alternatives by G1-coefficient of variation method.The focus of this approach is the use of the combination weighing,which is able to compensate for the deficiencies in the method of evaluation index single weighing.In the case study,an appropriate evaluation index system was established to determine the evaluation value of each ventilation mode.Then the proposed approach was used to select the best development face ventilation mode.The result shows that the proposed approach is able to rank the alternative development face ventilation mode reasonably,the combination weighing method had the advantages of both subjective and objective weighing methods in that it took into consideration of both the experience and wisdom of experts,and the new changes in objective conditions.This approach provides a more reasonable and reliable procedure to analyse and evaluate different ventilation modes.
