Objective:Multiple myeloma(MM)is a hematologically malignant clonal plasma cell disease.This study aims to explore the association between immunophenotypes and prognosis in patients with MM,to determine whether the ex...Objective:Multiple myeloma(MM)is a hematologically malignant clonal plasma cell disease.This study aims to explore the association between immunophenotypes and prognosis in patients with MM,to determine whether the expression of CD45 and CD200 is related to the prognosis of newly diagnosed MM(NDMM)patients,and to evaluate the significance of the combined expression of CD45 and CD200 in NDMM.Methods:A total of 123 NDMM patients admitted to Shengjing Hospital of China Medical University from July 2015 to August 2019 were enrolled.Five key immunophenotypic markers(including CD38,CD138,CD45,CD56,and CD200)were screened through flow cytometry and identified using random forest analysis and univariate Cox regression analysis.Patients were divided into 3 groups:Group A,CD45 and CD200 double-positive;Group B,CD45 or CD200 single-positive;Group C,CD45 and CD200 double-negative.Kaplan-Meier curves were used to analyze overall survival(OS)and progression-free survival(PFS)across groups.Multivariate Cox regression was performed to evaluate prognostic factors,and a nomogram was constructed based on these results.Results:The OS and PFS of single-positive groups for CD38,CD138,CD45,CD56,and CD200 were all shorter than those of their respective single-negative groups(all P<0.05).Significant differences were observed in OS(P<0.001)and PFS(P=0.001)among Groups A,B,and C.Group A had shorter OS and PFS(all P=0.001)compared to the Group B+C(cases from Group B and Group C were combined).CD45 and CD200 double-positive was an independent prognostic factor for NDMM[hazard ratio(HR)=2.178,95%confidence interval(CI)1.048 to 4.529;P=0.037].The nomogram and calibration curves constructed from multivariate Cox regression analysis demonstrated good concordance(concordance index=0.706;95%CI 0.661 to 0.751).Conclusion:NDMM patients with double-positive expression of CD45 and CD200 have significantly shorter OS and PFS.Compared with the use of either marker alone,the combined assessment of CD45 and CD200 may provide better prognostic stratification for MM patients.展开更多
The boundness and compactness of products of multiplication,composition and differentiation on weighted Bergman spaces in the unit ball are studied.We define the differentiation operator on the space of holomorphic fu...The boundness and compactness of products of multiplication,composition and differentiation on weighted Bergman spaces in the unit ball are studied.We define the differentiation operator on the space of holomorphic functions in the unit ball by radial derivative.Then we extend the Sharma's results.展开更多
The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs b...The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs based on M-EMLs separated by polyethyleneimine ethoxylated(PEIE)layer with different stacking sequences of blue(B),green(G),and red(R)QDs layer were used to intuitively explore the injection,transportation and recombination processes of the charge carriers in QLEDs by using the time-resolved electroluminescence(TrEL)spectra.From the TrEL spectra mea-surements,green and red emissions were obtained first in the QLEDs with the EMLs sequences of G/PEIE/B/PEIE/R and B/PEIE/R/PEIE/G along the direction of light emission,respectively.While the QLEDs adopt EMLs sequences of B/PEIE/G/PEIE/R,the blue,green and red emissions were obtained nearly at the same time.The above phenomenon can be attributed to different charge carrier transmission and radiation recombination process in the EMLs due to different valence band offsets and conduction band offsets between R-,G-and B-QDs by using different sequences of EMLs.White emission with coordi-nates of(0.31,0.31)and correlated color temperature(CCT)of 5916 K was obtained in the QLEDs with the EMLs se-quences of B/PEIE/G/PEIE/R,which can be attributed to the relative uniform emission of B-,G-and R-QDs due to the effec-tive injection and radiation recombination of charge carriers in each of the EMLs.The above results have great significance for further understanding and improving the performance of QLEDs with M-EMLs.展开更多
[Background and purposes]Proton exchange membrane fuel cells(PEMFCs),which convert hydrogen energy directly into electrical energy and water,have received overwhelming attention,owing to their potential to significant...[Background and purposes]Proton exchange membrane fuel cells(PEMFCs),which convert hydrogen energy directly into electrical energy and water,have received overwhelming attention,owing to their potential to significantly reduce energy consumption,pollution emissions and reliance on fossil fuels.Bipolar plates are the major part and key component of PEMFCs stack,which provide mechanical strength,collect and conduct current segregate oxidants and reduce agents.They contribute 70-80%weight and 20-30%cost of a whole stack,while significantly affecting the power density.There are three types plates,including metal bipolar plate,graphite bipolar plate and composite bipolar plate.Stainless steel bipolar plates,as one of metal bipolar plate,exhibit promising manufacturability,competitive cost and durability among various metal materials.However,stainless steel would be corroded in the harsh acid(pH 2-5)and humid PEMFCs environment,whereas the leached ions will contaminate the membrane.In addition,the passivated film formed on the surface will increase the interfacial contact resistance(ICR).In order to improve the corrosion resistance and electrical conductivity of steel bipolar plates,surface coatings are essential.Metal nitride coatings,metal carbide coatings,polymer coatings and carbon-based coatings have been introduced in recent years.Carbon-based coatings,mainly including a-C(amorphous Carbon),Ta-C(Tetrahedral amorphous carbon)and DLC(diamond-like carbon),have attracted considerable attention from both academia and industry,owing to their superior performance,such as chemical inertness,mechanical hardness and electrical conductivity.However,Ta-C films as protective coating of PEMFCs have been rarely reported,due to the difficulty in production for industrial application.In this paper,multi-layer Ta-C composite films were produced by using customized industrial-scale vacuum equipment to address those issues.[Methods]Multiple layered Ta-C coatings were prepared by using PIS624 equipment,which assembled filtered cathodic arc evaporation,ion beam and magnetron sputtering into one equipment,while SS304 and silicon specimens were used as substrate for testing and analysis.Adhesion layer and intermediate layer were deposited by using magnetron sputtering at deposition temperature of 150℃and pressure of 3×10^(−1) Pa,while the sputtering current was set to be 5 A and bias power to be 300 V.The Ta-C layer was coated at arc current of 80-100 A,bias voltage of 1500 V and gas flow of 75 sccm.A scanning electron microscope(CIQTEK SEM3200)was used to characterize surface morphology,coating structure and cross-section profile of the coatings.Raman spectrometer(LabRam HR Evolution,HORIBA JOBIN YVON)was used to identify the bonding valence states.Electrochemical tests were performed by using an electrochemical work station(CHI760,Shanghai Chenhua Instrument Co.,Ltd.),with the traditional three electrode system,where saturated Ag/AgCl and platinum mesh were used as the reference electrode and counter electrode,respectively.All samples were mounted in plastic tube and sealed with epoxy resin,with an exposure area of 2.25 cm^(2),serving as the working electrode.Electrochemical measurements were carried out in simulated PEMFCs cathode environment in 0.5 mol·L^(−1) H_(2)SO_(4)+5 ppm F−solution,at operating temperature of 70℃.As the cathode environment was harsher than the anode environment,all the samples are stabilized at the open-circuit potential(OCP)for approximately 30 min before the EIS measurements.ICR between bipolar plates and GDL was a key parameter affecting performance of the PEMFCs stack.The test sample sandwiched between 2 pieces of carbon paper(simulate gas diffusion layer,GDL)was placed between 2 gold-plated copper electrodes at a compaction pressure of 1.4 MPa,which was considered to be the conventional compaction pressure in the PEMFCs.Under the same conditions,the resistance of a single carbon paper was measured as well.The ICR was calculated according to the formula ICR=1/2(R2−R1)×S,where S was the contact area between GDL and coated stainless steel BPPs.All data of ICR were measured three times for averaging.[Results]The coatings deposited by filtered cathodic arc technology were compact and smooth,which reduced coating porosity and favorable to corrosion resistance.The coating thickness of adhesion and intermediate layers were 180 nm,while the protective Ta-C coating thickness was about 300 nm,forming multiple coating to provide stronger protection for metal bipolar plates.Cr,Ti,Nb and Ta coatings were selected as adhesion layers for comparison.According to electrochemical test,Ta and Nb coatings have higher corrosion resistance.However,Ta and Nb materials would be costly when they are used for mass production.Relatively,Cr and Ti materials were cost effective.Hence,a comprehensive assessment was indispensable to decide the materials to be selected as adhesion layer.Ta-TiN and Ti-TiN combined adhesion and intermediate layer exhibited stronger corrosion resistance,with the corrosion current to be less than 10^(−6) A·cm^(−2).Ta-C protective coating deposited by using filtered cathodic arc technology indicated displayed higher corrosion resistance,with the average corrosion density to be about 1.26×10^(−7) A·cm^(−2).Ta-C coating also shown larger contact angle,with the highest hydrophobicity,which was one of the important advantages for Ta-C,in terms of corrosion resistance.According to Raman spectroscopy,the I(D)/I(G)=549.8/1126.7=0.487,with the estimated fraction of sp^(3) bonding to be in the range of 5154%.The intermediate layer TiN has higher conductivity than the CrN layer.Considering cost,corrosion performance and ICR result,the Ti-TiN layer combination is recommended for industrial scale application.[Conclusions]Multiple layer coating structure of Ta-C film had stronger corrosion resistance;with more than 50%sp^(3) content,while it also had larger water contact angle and higher corrosion resistance than DLC film.The filtered arcing deposition technology was able to make the film to be more consistent and stable than normal arcing technology in terms of the preparation of Ta-C.The coating displayed corrosion density of 1.26×10^(−7) A·cm^(−2) and ICR of less than 5 mΩ·cm^(2),far beyond technical target of 2025 DOE(US Department of Energy).This indicated that the mass-production scale coating technology for PEMFC bipolar plates is highly possible.展开更多
Using the existing positioning technology can easily obtain high-precision positioning information,which can save resources and reduce complexity when used in the communication field.In this paper,we propose a locatio...Using the existing positioning technology can easily obtain high-precision positioning information,which can save resources and reduce complexity when used in the communication field.In this paper,we propose a location-based user scheduling and beamforming scheme for the downlink of a massive multi-user input-output system.Specifically,we combine an analog outer beamformer with a digital inner beamformer.An outer beamformer can be selected from a codebook formed by antenna steering vectors,and then a reduced-complexity inner beamformer based on iterative orthogonal matrices and right triangular matrices(QR)decomposition is applied to cancel interuser interference.Then,we propose a low-complexity user selection algorithm using location information in this paper.We first derive the geometric angle between channel matrices,which represent the correlation between users.Furthermore,we derive the asymptotic signal to interference-plus-noise ratio(SINR)of the system in the context of two-stage beamforming using random matrix theory(RMT),taking into account inter-channel correlations and energies.Simulation results show that the algorithm can achieve higher system and speed while reducing computational complexity.展开更多
Multiple quadrotors target encirclement is widely used in the intelligent field,as it can effectively monitor and control target behavior.However,it faces the danger of collision,as well as difficulties in localizatio...Multiple quadrotors target encirclement is widely used in the intelligent field,as it can effectively monitor and control target behavior.However,it faces the danger of collision,as well as difficulties in localization and tracking.Therefore,we propose a complete target encirclement method.Firstly,based on Hooke's law,a collision avoidance controller is designed to maintain a safe flying distance among quadrotors.Then,based on the consensus theory,a formation tracking controller is designed to meet the requirements of formation transformation and encirclement tasks,and a stability proof based on Lyapunov was provided.Besides,the target detection is designed based on YOLOv5s,and the target location model is constructed based on the principle of pinhole projection and triangle similarity.Finally,we conducted experiments on the built platform,with 3 reconnaissance quadrotors detecting and localization 3 target vehicles and 7 hunter quadrotors tracking them.The results show that the minimum average error for localization targets with reconnaissance quadrotors can reach 0.1354 m,while the minimum average error for tracking with hunter quadrotors is only 0.2960 m.No quadrotors collision occurred in the whole formation transformation and tracking experiment.In addition,compared with the advanced methods,the proposed method has better performance.展开更多
Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism stu...Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism study of high iron red mud were carried out under the coupling conditions of multiple physical field(microwave field,gas-solid flow field and temperature field)with biomass as the reducing agent.The test results showed that under the optimal conditions,an iron concentrate with a yield of 78.4%,an iron grade of 59.23%,and a recovery rate of 86.65%was obtained.The analyses of XRD,XPS,TEM,and SEM-EDS showed that during the roasting process,the hematite in the high-iron red mud was completely converted to magnetite,and the biomass produced the reductant that provided the magnetization reaction;A large number of cracks and pores appeared in the surface of the hematite reduction product particles,which helped to induce iron minerals to undergo effective mineral phase transformation.The above study provides ideas for the phase transformation and efficient recovery of iron minerals in red mud.展开更多
This research focuses on detecting faults in flight vehicles with unstable subsystems operating asynchronously.By accounting for asynchronous switching,a switched model is established,and filters for fault detection(F...This research focuses on detecting faults in flight vehicles with unstable subsystems operating asynchronously.By accounting for asynchronous switching,a switched model is established,and filters for fault detection(FD)in unstable subsystems are developed.The FD challenge is then transformed into an H∞filtering issue.Utilizing the multiple discontinuous Lyapunov function(MDLF)approach and the mode-dependent average dwell time(MDADT)method,sufficient conditions are derived to ensure stability during both fast and slow switching.Furthermore,the existence and solutions for FD filters are provided through linear matrix inequalities(LMIs).The simulation outcomes demonstrated the excellent performance of the developed method in studied cases.展开更多
As the performance of the box-type multiple launch rocket system(BMLRS)improves,its mechanical structures,particularly the plane clearance design between the slider on the rocket and the guide inside the launch canist...As the performance of the box-type multiple launch rocket system(BMLRS)improves,its mechanical structures,particularly the plane clearance design between the slider on the rocket and the guide inside the launch canister,have grown increasingly complex.However,deficiencies still exist in the current launch modeling theory for BMLRS.In this study,a multi-rigid-flexible-body launch dynamics model coupling the launch platform and rocket was established using the multibody system transfer matrix method and the Newton-Euler formulation.Furthermore,considering the bending of the launch canister,a detection algorithm for slider-guide plane clearance contact was proposed.To quantify the contact force and friction effect between the slider and guide,the contact force model and modified Coulomb model were introduced.Both the modal and launch tests were conducted.Additionally,the modal convergence was verified.By comparing the modal experiments and simulation results,the maximum relative error of the eigenfrequency is 3.29%.thereby verifying the accuracy of the developed BMLRS dynamics model.Furthermore,the launch test validated the proposed plane clearance contact model.Moreover,the study investigated the influence of various model parameters on the dynamic characteristics of BMLRS,including launch canister bending stiffness,slider and guide material,slider-guide clearance,slider length and layout.This analysis of influencing factors provides a foundation for future optimization in BMLRS design.展开更多
本文研究了一种新的高频地波超视距雷达目标距离以及方位角超分辨问题.在该雷达系统中,各个发射阵元采用不同的发射载频,因此目标回波信号中存在目标距离与方位角的耦合,本文提出利用这种耦合关系,采用M U S IC(M u ltip le S igna l C ...本文研究了一种新的高频地波超视距雷达目标距离以及方位角超分辨问题.在该雷达系统中,各个发射阵元采用不同的发射载频,因此目标回波信号中存在目标距离与方位角的耦合,本文提出利用这种耦合关系,采用M U S IC(M u ltip le S igna l C lassifica tion)算法获得目标距离以及方位角的超分辩,从而提高在多目标环境下测距、测角精度.仿真结果验证了该方法的有效性.展开更多
N-methyl carbamate has been widely used in agriculture,and may be transformed into several metabolites,which can be more toxic and persistent than the parent.Thus carbamate residue in environment aroused a great deal ...N-methyl carbamate has been widely used in agriculture,and may be transformed into several metabolites,which can be more toxic and persistent than the parent.Thus carbamate residue in environment aroused a great deal public concern,especially in drinking water.In this paper,analytical methods for carbmate in water are reviewed,including pretreatment methods and instrument analysis methods,which is aimed to accelerate the proceeding of establishing Chinese standard method on carbamate in water and waste water.展开更多
提出了基于2q阶累积量的非圆信号测向MUSIC(Multiple Signal Classification)算法(称为NC-2q-MUSIC),作为2q-MUSIC算法利用非圆信息的一种扩展,在可测向信号数、分辨力和测角精度等方面的性能均优于2q-MUSIC算法.并且,q越大,NC-2q-MUSI...提出了基于2q阶累积量的非圆信号测向MUSIC(Multiple Signal Classification)算法(称为NC-2q-MUSIC),作为2q-MUSIC算法利用非圆信息的一种扩展,在可测向信号数、分辨力和测角精度等方面的性能均优于2q-MUSIC算法.并且,q越大,NC-2q-MUSIC算法的可测向信号数越大,分辨力越高,对模型误差也越不敏感.针对均布线阵(ULA:Uniform Linear Array)提出的NC-2q-MUSIC/ULA算法减小了计算量.仿真实验验证了NC-2q-MUSIC算法的优良性能.展开更多
由于MUSIC(MUltiple SIgnal Classification)算法需要大量的乘法运算和三角函数求值,导致其实时处理能力较弱。为此,该文首先对均匀线阵和均匀圆阵的阵列结构进行分析,提取导向矢量的一些性质。然后,利用Hermite矩阵的性质对复数乘法进...由于MUSIC(MUltiple SIgnal Classification)算法需要大量的乘法运算和三角函数求值,导致其实时处理能力较弱。为此,该文首先对均匀线阵和均匀圆阵的阵列结构进行分析,提取导向矢量的一些性质。然后,利用Hermite矩阵的性质对复数乘法进行分解,再组建两个实值向量以减少乘法运算次数。最后,利用导向矢量的性质提出一种基于查表的新算法。新算法既没有三角函数求值运算,又不需要大量的存储空间。仿真实验结果表明新算法在没有改变MUSIC算法谱估计的效果的前提下,将MUSIC算法的运算速率提高了50倍以上。因此,新算法具有广阔的应用前景。展开更多
首先阐明组合法求解有限板多孔MSD(multiple site damage)应力强度因子的基本原理,然后就组合法运用中比较难以解决的多孔边裂纹间的修正系数问题,提出一种基于复变函数法的有效解决方法。将完善后的组合法应用于有限板多孔MSD应力强度...首先阐明组合法求解有限板多孔MSD(multiple site damage)应力强度因子的基本原理,然后就组合法运用中比较难以解决的多孔边裂纹间的修正系数问题,提出一种基于复变函数法的有效解决方法。将完善后的组合法应用于有限板多孔MSD应力强度因子的求解,计算某型飞机典型铆接壁板无主裂纹和含主裂纹两种情况的数值算例。通过与有限元结果的比较可知,该方法的计算结果精确、可靠,计算过程简单、易行。提出的近似解析方法能很好地应用于任意分布的有限板多孔MSD裂纹结构,在工程断裂问题中有较好的应用价值。展开更多
基金supported by the National Natural Science Foundation,China(81870166).
文摘Objective:Multiple myeloma(MM)is a hematologically malignant clonal plasma cell disease.This study aims to explore the association between immunophenotypes and prognosis in patients with MM,to determine whether the expression of CD45 and CD200 is related to the prognosis of newly diagnosed MM(NDMM)patients,and to evaluate the significance of the combined expression of CD45 and CD200 in NDMM.Methods:A total of 123 NDMM patients admitted to Shengjing Hospital of China Medical University from July 2015 to August 2019 were enrolled.Five key immunophenotypic markers(including CD38,CD138,CD45,CD56,and CD200)were screened through flow cytometry and identified using random forest analysis and univariate Cox regression analysis.Patients were divided into 3 groups:Group A,CD45 and CD200 double-positive;Group B,CD45 or CD200 single-positive;Group C,CD45 and CD200 double-negative.Kaplan-Meier curves were used to analyze overall survival(OS)and progression-free survival(PFS)across groups.Multivariate Cox regression was performed to evaluate prognostic factors,and a nomogram was constructed based on these results.Results:The OS and PFS of single-positive groups for CD38,CD138,CD45,CD56,and CD200 were all shorter than those of their respective single-negative groups(all P<0.05).Significant differences were observed in OS(P<0.001)and PFS(P=0.001)among Groups A,B,and C.Group A had shorter OS and PFS(all P=0.001)compared to the Group B+C(cases from Group B and Group C were combined).CD45 and CD200 double-positive was an independent prognostic factor for NDMM[hazard ratio(HR)=2.178,95%confidence interval(CI)1.048 to 4.529;P=0.037].The nomogram and calibration curves constructed from multivariate Cox regression analysis demonstrated good concordance(concordance index=0.706;95%CI 0.661 to 0.751).Conclusion:NDMM patients with double-positive expression of CD45 and CD200 have significantly shorter OS and PFS.Compared with the use of either marker alone,the combined assessment of CD45 and CD200 may provide better prognostic stratification for MM patients.
基金Supported by Natural Science Foundation of Guangdong Province in China(2018KTSCX161)。
文摘The boundness and compactness of products of multiplication,composition and differentiation on weighted Bergman spaces in the unit ball are studied.We define the differentiation operator on the space of holomorphic functions in the unit ball by radial derivative.Then we extend the Sharma's results.
文摘The charge carrier transport and recombination dynamics in the quantum dots-based light-emitting diodes(QLEDs)featuring multiple emitting layers(M-EMLs)has a great impact on the device performance.In this work,QLEDs based on M-EMLs separated by polyethyleneimine ethoxylated(PEIE)layer with different stacking sequences of blue(B),green(G),and red(R)QDs layer were used to intuitively explore the injection,transportation and recombination processes of the charge carriers in QLEDs by using the time-resolved electroluminescence(TrEL)spectra.From the TrEL spectra mea-surements,green and red emissions were obtained first in the QLEDs with the EMLs sequences of G/PEIE/B/PEIE/R and B/PEIE/R/PEIE/G along the direction of light emission,respectively.While the QLEDs adopt EMLs sequences of B/PEIE/G/PEIE/R,the blue,green and red emissions were obtained nearly at the same time.The above phenomenon can be attributed to different charge carrier transmission and radiation recombination process in the EMLs due to different valence band offsets and conduction band offsets between R-,G-and B-QDs by using different sequences of EMLs.White emission with coordi-nates of(0.31,0.31)and correlated color temperature(CCT)of 5916 K was obtained in the QLEDs with the EMLs se-quences of B/PEIE/G/PEIE/R,which can be attributed to the relative uniform emission of B-,G-and R-QDs due to the effec-tive injection and radiation recombination of charge carriers in each of the EMLs.The above results have great significance for further understanding and improving the performance of QLEDs with M-EMLs.
基金Major Science and technology projects of Anhui Province (202103a05020003)。
文摘[Background and purposes]Proton exchange membrane fuel cells(PEMFCs),which convert hydrogen energy directly into electrical energy and water,have received overwhelming attention,owing to their potential to significantly reduce energy consumption,pollution emissions and reliance on fossil fuels.Bipolar plates are the major part and key component of PEMFCs stack,which provide mechanical strength,collect and conduct current segregate oxidants and reduce agents.They contribute 70-80%weight and 20-30%cost of a whole stack,while significantly affecting the power density.There are three types plates,including metal bipolar plate,graphite bipolar plate and composite bipolar plate.Stainless steel bipolar plates,as one of metal bipolar plate,exhibit promising manufacturability,competitive cost and durability among various metal materials.However,stainless steel would be corroded in the harsh acid(pH 2-5)and humid PEMFCs environment,whereas the leached ions will contaminate the membrane.In addition,the passivated film formed on the surface will increase the interfacial contact resistance(ICR).In order to improve the corrosion resistance and electrical conductivity of steel bipolar plates,surface coatings are essential.Metal nitride coatings,metal carbide coatings,polymer coatings and carbon-based coatings have been introduced in recent years.Carbon-based coatings,mainly including a-C(amorphous Carbon),Ta-C(Tetrahedral amorphous carbon)and DLC(diamond-like carbon),have attracted considerable attention from both academia and industry,owing to their superior performance,such as chemical inertness,mechanical hardness and electrical conductivity.However,Ta-C films as protective coating of PEMFCs have been rarely reported,due to the difficulty in production for industrial application.In this paper,multi-layer Ta-C composite films were produced by using customized industrial-scale vacuum equipment to address those issues.[Methods]Multiple layered Ta-C coatings were prepared by using PIS624 equipment,which assembled filtered cathodic arc evaporation,ion beam and magnetron sputtering into one equipment,while SS304 and silicon specimens were used as substrate for testing and analysis.Adhesion layer and intermediate layer were deposited by using magnetron sputtering at deposition temperature of 150℃and pressure of 3×10^(−1) Pa,while the sputtering current was set to be 5 A and bias power to be 300 V.The Ta-C layer was coated at arc current of 80-100 A,bias voltage of 1500 V and gas flow of 75 sccm.A scanning electron microscope(CIQTEK SEM3200)was used to characterize surface morphology,coating structure and cross-section profile of the coatings.Raman spectrometer(LabRam HR Evolution,HORIBA JOBIN YVON)was used to identify the bonding valence states.Electrochemical tests were performed by using an electrochemical work station(CHI760,Shanghai Chenhua Instrument Co.,Ltd.),with the traditional three electrode system,where saturated Ag/AgCl and platinum mesh were used as the reference electrode and counter electrode,respectively.All samples were mounted in plastic tube and sealed with epoxy resin,with an exposure area of 2.25 cm^(2),serving as the working electrode.Electrochemical measurements were carried out in simulated PEMFCs cathode environment in 0.5 mol·L^(−1) H_(2)SO_(4)+5 ppm F−solution,at operating temperature of 70℃.As the cathode environment was harsher than the anode environment,all the samples are stabilized at the open-circuit potential(OCP)for approximately 30 min before the EIS measurements.ICR between bipolar plates and GDL was a key parameter affecting performance of the PEMFCs stack.The test sample sandwiched between 2 pieces of carbon paper(simulate gas diffusion layer,GDL)was placed between 2 gold-plated copper electrodes at a compaction pressure of 1.4 MPa,which was considered to be the conventional compaction pressure in the PEMFCs.Under the same conditions,the resistance of a single carbon paper was measured as well.The ICR was calculated according to the formula ICR=1/2(R2−R1)×S,where S was the contact area between GDL and coated stainless steel BPPs.All data of ICR were measured three times for averaging.[Results]The coatings deposited by filtered cathodic arc technology were compact and smooth,which reduced coating porosity and favorable to corrosion resistance.The coating thickness of adhesion and intermediate layers were 180 nm,while the protective Ta-C coating thickness was about 300 nm,forming multiple coating to provide stronger protection for metal bipolar plates.Cr,Ti,Nb and Ta coatings were selected as adhesion layers for comparison.According to electrochemical test,Ta and Nb coatings have higher corrosion resistance.However,Ta and Nb materials would be costly when they are used for mass production.Relatively,Cr and Ti materials were cost effective.Hence,a comprehensive assessment was indispensable to decide the materials to be selected as adhesion layer.Ta-TiN and Ti-TiN combined adhesion and intermediate layer exhibited stronger corrosion resistance,with the corrosion current to be less than 10^(−6) A·cm^(−2).Ta-C protective coating deposited by using filtered cathodic arc technology indicated displayed higher corrosion resistance,with the average corrosion density to be about 1.26×10^(−7) A·cm^(−2).Ta-C coating also shown larger contact angle,with the highest hydrophobicity,which was one of the important advantages for Ta-C,in terms of corrosion resistance.According to Raman spectroscopy,the I(D)/I(G)=549.8/1126.7=0.487,with the estimated fraction of sp^(3) bonding to be in the range of 5154%.The intermediate layer TiN has higher conductivity than the CrN layer.Considering cost,corrosion performance and ICR result,the Ti-TiN layer combination is recommended for industrial scale application.[Conclusions]Multiple layer coating structure of Ta-C film had stronger corrosion resistance;with more than 50%sp^(3) content,while it also had larger water contact angle and higher corrosion resistance than DLC film.The filtered arcing deposition technology was able to make the film to be more consistent and stable than normal arcing technology in terms of the preparation of Ta-C.The coating displayed corrosion density of 1.26×10^(−7) A·cm^(−2) and ICR of less than 5 mΩ·cm^(2),far beyond technical target of 2025 DOE(US Department of Energy).This indicated that the mass-production scale coating technology for PEMFC bipolar plates is highly possible.
基金supported by the National Natural Science Foundation of China(61901341).
文摘Using the existing positioning technology can easily obtain high-precision positioning information,which can save resources and reduce complexity when used in the communication field.In this paper,we propose a location-based user scheduling and beamforming scheme for the downlink of a massive multi-user input-output system.Specifically,we combine an analog outer beamformer with a digital inner beamformer.An outer beamformer can be selected from a codebook formed by antenna steering vectors,and then a reduced-complexity inner beamformer based on iterative orthogonal matrices and right triangular matrices(QR)decomposition is applied to cancel interuser interference.Then,we propose a low-complexity user selection algorithm using location information in this paper.We first derive the geometric angle between channel matrices,which represent the correlation between users.Furthermore,we derive the asymptotic signal to interference-plus-noise ratio(SINR)of the system in the context of two-stage beamforming using random matrix theory(RMT),taking into account inter-channel correlations and energies.Simulation results show that the algorithm can achieve higher system and speed while reducing computational complexity.
基金the National Natural Science Foundation of China(Grant Nos.62303348 and 62173242)the Aeronautical Science Foundation of China(Grant No.2024M071048002)the National Science Fund for Distinguished Young Scholars(Grant No.62225308)to provide fund for conducting experiments.
文摘Multiple quadrotors target encirclement is widely used in the intelligent field,as it can effectively monitor and control target behavior.However,it faces the danger of collision,as well as difficulties in localization and tracking.Therefore,we propose a complete target encirclement method.Firstly,based on Hooke's law,a collision avoidance controller is designed to maintain a safe flying distance among quadrotors.Then,based on the consensus theory,a formation tracking controller is designed to meet the requirements of formation transformation and encirclement tasks,and a stability proof based on Lyapunov was provided.Besides,the target detection is designed based on YOLOv5s,and the target location model is constructed based on the principle of pinhole projection and triangle similarity.Finally,we conducted experiments on the built platform,with 3 reconnaissance quadrotors detecting and localization 3 target vehicles and 7 hunter quadrotors tracking them.The results show that the minimum average error for localization targets with reconnaissance quadrotors can reach 0.1354 m,while the minimum average error for tracking with hunter quadrotors is only 0.2960 m.No quadrotors collision occurred in the whole formation transformation and tracking experiment.In addition,compared with the advanced methods,the proposed method has better performance.
基金Project(MMCS2023OF02)supported by the Open Foundation of State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures,ChinaProject(AA23073018)supported by the Guangxi Science and Technology,ChinaProject(2024M751861)supported by the China Postdoctoral Science Foundation。
文摘Red mud is a solid waste discharged in the process of alumina production,and how to realize the efficient recovery of its iron is an urgent problem to be solved.In this study,the iron extraction test and mechanism study of high iron red mud were carried out under the coupling conditions of multiple physical field(microwave field,gas-solid flow field and temperature field)with biomass as the reducing agent.The test results showed that under the optimal conditions,an iron concentrate with a yield of 78.4%,an iron grade of 59.23%,and a recovery rate of 86.65%was obtained.The analyses of XRD,XPS,TEM,and SEM-EDS showed that during the roasting process,the hematite in the high-iron red mud was completely converted to magnetite,and the biomass produced the reductant that provided the magnetization reaction;A large number of cracks and pores appeared in the surface of the hematite reduction product particles,which helped to induce iron minerals to undergo effective mineral phase transformation.The above study provides ideas for the phase transformation and efficient recovery of iron minerals in red mud.
基金the National Natural Science Foundation of China(Grant Nos.62303380,62176214,62101590,62003268)the Aeronautical Science Foundation of China(Grant No.201907053001).
文摘This research focuses on detecting faults in flight vehicles with unstable subsystems operating asynchronously.By accounting for asynchronous switching,a switched model is established,and filters for fault detection(FD)in unstable subsystems are developed.The FD challenge is then transformed into an H∞filtering issue.Utilizing the multiple discontinuous Lyapunov function(MDLF)approach and the mode-dependent average dwell time(MDADT)method,sufficient conditions are derived to ensure stability during both fast and slow switching.Furthermore,the existence and solutions for FD filters are provided through linear matrix inequalities(LMIs).The simulation outcomes demonstrated the excellent performance of the developed method in studied cases.
基金supported by National Natural Science Foundation of China(Grant No.92266201).
文摘As the performance of the box-type multiple launch rocket system(BMLRS)improves,its mechanical structures,particularly the plane clearance design between the slider on the rocket and the guide inside the launch canister,have grown increasingly complex.However,deficiencies still exist in the current launch modeling theory for BMLRS.In this study,a multi-rigid-flexible-body launch dynamics model coupling the launch platform and rocket was established using the multibody system transfer matrix method and the Newton-Euler formulation.Furthermore,considering the bending of the launch canister,a detection algorithm for slider-guide plane clearance contact was proposed.To quantify the contact force and friction effect between the slider and guide,the contact force model and modified Coulomb model were introduced.Both the modal and launch tests were conducted.Additionally,the modal convergence was verified.By comparing the modal experiments and simulation results,the maximum relative error of the eigenfrequency is 3.29%.thereby verifying the accuracy of the developed BMLRS dynamics model.Furthermore,the launch test validated the proposed plane clearance contact model.Moreover,the study investigated the influence of various model parameters on the dynamic characteristics of BMLRS,including launch canister bending stiffness,slider and guide material,slider-guide clearance,slider length and layout.This analysis of influencing factors provides a foundation for future optimization in BMLRS design.
文摘本文研究了一种新的高频地波超视距雷达目标距离以及方位角超分辨问题.在该雷达系统中,各个发射阵元采用不同的发射载频,因此目标回波信号中存在目标距离与方位角的耦合,本文提出利用这种耦合关系,采用M U S IC(M u ltip le S igna l C lassifica tion)算法获得目标距离以及方位角的超分辩,从而提高在多目标环境下测距、测角精度.仿真结果验证了该方法的有效性.
文摘N-methyl carbamate has been widely used in agriculture,and may be transformed into several metabolites,which can be more toxic and persistent than the parent.Thus carbamate residue in environment aroused a great deal public concern,especially in drinking water.In this paper,analytical methods for carbmate in water are reviewed,including pretreatment methods and instrument analysis methods,which is aimed to accelerate the proceeding of establishing Chinese standard method on carbamate in water and waste water.
文摘提出了基于2q阶累积量的非圆信号测向MUSIC(Multiple Signal Classification)算法(称为NC-2q-MUSIC),作为2q-MUSIC算法利用非圆信息的一种扩展,在可测向信号数、分辨力和测角精度等方面的性能均优于2q-MUSIC算法.并且,q越大,NC-2q-MUSIC算法的可测向信号数越大,分辨力越高,对模型误差也越不敏感.针对均布线阵(ULA:Uniform Linear Array)提出的NC-2q-MUSIC/ULA算法减小了计算量.仿真实验验证了NC-2q-MUSIC算法的优良性能.
文摘由于MUSIC(MUltiple SIgnal Classification)算法需要大量的乘法运算和三角函数求值,导致其实时处理能力较弱。为此,该文首先对均匀线阵和均匀圆阵的阵列结构进行分析,提取导向矢量的一些性质。然后,利用Hermite矩阵的性质对复数乘法进行分解,再组建两个实值向量以减少乘法运算次数。最后,利用导向矢量的性质提出一种基于查表的新算法。新算法既没有三角函数求值运算,又不需要大量的存储空间。仿真实验结果表明新算法在没有改变MUSIC算法谱估计的效果的前提下,将MUSIC算法的运算速率提高了50倍以上。因此,新算法具有广阔的应用前景。
文摘首先阐明组合法求解有限板多孔MSD(multiple site damage)应力强度因子的基本原理,然后就组合法运用中比较难以解决的多孔边裂纹间的修正系数问题,提出一种基于复变函数法的有效解决方法。将完善后的组合法应用于有限板多孔MSD应力强度因子的求解,计算某型飞机典型铆接壁板无主裂纹和含主裂纹两种情况的数值算例。通过与有限元结果的比较可知,该方法的计算结果精确、可靠,计算过程简单、易行。提出的近似解析方法能很好地应用于任意分布的有限板多孔MSD裂纹结构,在工程断裂问题中有较好的应用价值。
