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复合催化剂Ru/CoAl−LDH可见光深度还原低浓度CO_(2)及其性能增强机理
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作者 戴俊 贾凤婷 +3 位作者 杨娟 丰之翔 王大钊 冷冲冲 《煤炭学报》 北大核心 2025年第2期1325-1338,共14页
“双碳”目标下,利用清洁可再生的太阳能驱动CO_(2)资源化利用成为重要的研究课题,但已有报道多以高纯CO_(2)为研究对象,而实际燃煤电厂排放的烟气中CO_(2)体积分数仅为3%~15%,为规避高能耗的CO_(2)提浓过程,直接实现低浓度CO_(2)光催... “双碳”目标下,利用清洁可再生的太阳能驱动CO_(2)资源化利用成为重要的研究课题,但已有报道多以高纯CO_(2)为研究对象,而实际燃煤电厂排放的烟气中CO_(2)体积分数仅为3%~15%,为规避高能耗的CO_(2)提浓过程,直接实现低浓度CO_(2)光催化定向转化对节能减排及其资源化利用具有重要科学意义。采用共沉淀−水热法首先制得钴铝层状双氢氧化物(CoAl−LDH),通过表面浸渍耦合氢气热处理将钌纳米颗粒负载至CoAl−LDH表面,构筑出可见光催化剂Ru/CoAl−LDH,其独特的表面组成与结构特性有助于实现以水为氢源的低浓度CO_(2)深度光还原。利用X射线衍射、透射电镜、X射线光电子能谱与紫外可见漫反射光谱等测试技术对复合催化剂的结构组成和微观形貌进行测定分析,结果表明:负载的钌物种为零价金属态Ru,其负载未改变CoAl−LDH的纳米片状形貌,但可显著提升复合催化剂的光响应性能。以Ru/CoAl−LDH为光催化剂、水为电子给体和氢源、10%CO_(2)/N_(2)混合气体为模拟烟道气,在可见光照射下考察Ru负载量对还原产物生成量及深度还原产物甲烷选择性的影响,其中1.6%Ru/CoAl−LDH具有最优的CO_(2)光还原性能,可见光照射3 h后的甲烷产生量及选择性高达452.4μmol/g和86.3%,分别是单一CoAl−LDH的10.4倍和3.3倍。同时,借助CO_(2)吸附等温线、原位XPS、瞬态光电流与阻抗谱等测试结果探究了Ru/CoAl−LDH对低浓度CO_(2)深度光还原的性能增强机理。CoAl−LDH表面的—OH基团利于复合催化剂对低浓度CO_(2)的选择性吸附;CoAl−LDH优异的水氧化性能可为CO_(2)深度光还原提供充足的原位氢源,无需使用具有爆炸危险性的氢气;负载的Ru作为光电子受体,在增强光生电荷分离与迁移效率的同时,作为CO_(2)还原活性位能实现其多电子还原过程。因此,CoAl−LDH和助催化剂Ru的协同作用是低浓度CO_(2)深度光还原性能得以提升的主要原因,复合催化剂Ru/CoAl−LDH实现了可见光水氧化与低浓度CO_(2)深度还原的有效耦合,为本质安全且低能耗CO_(2)转化体系的构建提供了重要理论指导,也为燃煤烟气CO_(2)资源化利用提供了新思路。 展开更多
关键词 低浓度CO_(2) 深度光还原 钴铝层状双氢氧化物 钌负载 水氧化
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Heusler合金Mn_(2)CoAl(100)的表面结构和电磁性质
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作者 文林 江玲 +3 位作者 顾玉鑫 杜信 沈光先 吴波 《人工晶体学报》 北大核心 2025年第4期636-642,共7页
本文采用第一性原理计算,系统地研究了Heusler合金Mn_(2)CoAl块体的磁性及Mn_(2)CoAl(100)表面的原子弛豫、磁性、电子结构和表面原子极化行为。原子弛豫计算显示,MnAl端面呈现层间差异化位移特征,第一层Mn原子向端面内部弛豫而Al原子... 本文采用第一性原理计算,系统地研究了Heusler合金Mn_(2)CoAl块体的磁性及Mn_(2)CoAl(100)表面的原子弛豫、磁性、电子结构和表面原子极化行为。原子弛豫计算显示,MnAl端面呈现层间差异化位移特征,第一层Mn原子向端面内部弛豫而Al原子向真空层外移,第二层原子均向真空层移动,第三层原子则呈现内缩趋势;其余三种MnCo、MnMn和CoCo端面则表现出相似规律,其三层原子均向真空层外略微移动,四种端面的整体结构均未发生显著形变。在Mn_(2)CoAl(100)不同原子端面中,MnCo和CoCo端面的半金属带隙被表面态破坏,而MnAl和MnMn端面未受到表面态的明显影响,半金属带隙较大,分别保留了约92%和80%的极化率,预测其在隧道异质结中可能具有较好的应用潜力。 展开更多
关键词 HEUSLER合金 Mn_(2)coal 半金属性 表面 磁性 隧道异质结
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Effect of Demineralization on Pyrolysis Reactivity of Zhundong Coal by Reactive Force Field Molecular Dynamics(ReaxFF MD)Simulation
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作者 Qian Lin Tao Chao +2 位作者 Zhao Nanjin Kuang Panyang Guo Feiqiang 《燃烧科学与技术》 北大核心 2025年第4期353-366,共14页
It is important to understand the effects of demineralization on the reactivity of coal pyrolysis for demineralization coal in OCCSS systems.The molecular dynamics of the pyrolysis of ZD-R and ZD-D was investigated us... It is important to understand the effects of demineralization on the reactivity of coal pyrolysis for demineralization coal in OCCSS systems.The molecular dynamics of the pyrolysis of ZD-R and ZD-D was investigated using the ReaxFF MD method.It is indicated that the pyrolysis reactivity of ZD-D is enhanced.Acid demineralization treatment helps to enhance the cross-linking reaction of light tar C5-14 molecules in the main pyrolysis stage,generating light tar fragments with higher molecular mass.In the polycondensation pyrolysis stage,the acid demineralization treatment promotes the polycondensation reaction at high temperatures.The generation of H2 in ZD-R pyrolysis is primarily attributed to the N-H bond breaking in pyrrole at low temperatures.At high temperatures,it is predominantly associated with the hydrogen abstraction reaction between carboxyl functional groups and the dehydrogenation reaction of hydrogen bond breaking in the aliphatic hydrocarbon structures.H2O is primarily attributed to the reaction of the hydroxyl group on the carboxyl group.CO_(2) is always related to the carboxyl group.CO is mainly related to the reduction reaction of carbonyl group,carboxyl group,and CO_(2).During the initial pyrolysis stage of ZD-D after acid demineralization treatment,the hydrogen abstraction reaction of the carboxyl functional group and the generation of CO molecules by the methoxy group are enhanced.The generation of H2 by the aliphatic structure is enhanced in the main pyrolysis stage.The ring-opening reaction of the phenoxy group to generate CO in the polycondensation pyrolysis stage is also facilitated. 展开更多
关键词 coal pyrolysis demineralization coal reaction mechanism ReaxFF MD
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Effect of water on dynamic mechanical properties of coal under different depth stress conditions
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作者 LI Sheng-wei GAO Ming-zhong +2 位作者 LI Ye-xue WANG Jun ZENG Gang 《Journal of Central South University》 2025年第1期220-228,共9页
Coal seam water injection in tunnels is an effective technical measure for preventing coal mine rock bursts.This study used the improved split Hopkinson pressure bar(SHPB)to apply three equal static stresses to water-... Coal seam water injection in tunnels is an effective technical measure for preventing coal mine rock bursts.This study used the improved split Hopkinson pressure bar(SHPB)to apply three equal static stresses to water-saturated coal to simulate the initial stress environment of coal at different depths.Then,dynamic mechanical experiments were conducted on the saturated coal at different depths to investigate the effects of water saturation and depth on the coal samples’dynamic mechanical properties.Under uniaxial compression and without lateral compression,the strength of coal samples decreased to varying degrees in the saturated state;under different depth conditions,the dynamic strength of coal in the saturated state decreased compared with that in the natural state.However,compared with that at 0 m,the reduction in the strength of coal under the saturated condition at 200,400,600,and 800 m was significantly reduced.The findings of this study provide a basic theoretical foundation for the prevention and control of dynamic coal mine disasters. 展开更多
关键词 coal mining depths water saturation SHPB dynamic compressive strength
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Bearing characteristics of anchor box beam support system in deep thick roof coal roadway and its application
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作者 WANG Qi WANG Ming-zi +1 位作者 JIANG Bei XU Chuan-jie 《Journal of Central South University》 2025年第5期1887-1902,共16页
Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam suppor... Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam support system with high strength is developed.The high-strength bearing characteristics and coupling yielding support mechanism of this support system are studied by the mechanical tests of composite members and the combined support system.The test results show that under the coupling effect of support members,the peak stress of the box-shaped support beam in the anchor box beam is reduced by 21.9%,and the average deformation is increased by 135.0%.The ultimate bending bearing capacity of the box-shaped support beam is 3.5 times that of traditional channel beam.The effective compressive stress zone applied by the high prestressed cable is expanded by 26.4%.On this basis,the field support comparison test by the anchor channel beam,the anchor I-shaped beam and the anchor box beam are carried out.Compared with those of the previous two,the surrounding rock convergence of the latter is decreased by 41.2%and 22.2%,respectively.The field test verifies the effectiveness of the anchor box beam support system. 展开更多
关键词 thick roof coal roadway anchor box beam bearing characteristics combined support field application
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Brittleness evaluation of gas-bearing coal based on statistical damage constitution model and energy evolution mechanism
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作者 XUE Yi WANG Lin-chao +5 位作者 LIU Yong RANJITH P G CAO Zheng-zheng SHI Xu-yang GAO Feng KONG Hai-ling 《Journal of Central South University》 2025年第2期566-581,共16页
Accurate assessment of coal brittleness is crucial in the design of coal seam drilling and underground coal mining operations.This study proposes a method for evaluating the brittleness of gas-bearing coal based on a ... Accurate assessment of coal brittleness is crucial in the design of coal seam drilling and underground coal mining operations.This study proposes a method for evaluating the brittleness of gas-bearing coal based on a statistical damage constitutive model and energy evolution mechanisms.Initially,integrating the principle of effective stress and the Hoek-Brown criterion,a statistical damage constitutive model for gas-bearing coal is established and validated through triaxial compression tests under different gas pressures to verify its accuracy and applicability.Subsequently,employing energy evolution mechanism,two energy characteristic parameters(elastic energy proportion and dissipated energy proportion)are analyzed.Based on the damage stress thresholds,the damage evolution characteristics of gas bearing coal were explored.Finally,by integrating energy characteristic parameters with damage parameters,a novel brittleness index is proposed.The results demonstrate that the theoretical curves derived from the statistical damage constitutive model closely align with the test curves,accurately reflecting the stress−strain characteristics of gas-bearing coal and revealing the stress drop and softening characteristics of coal in the post-peak stage.The shape parameter and scale parameter represent the brittleness and macroscopic strength of the coal,respectively.As gas pressure increases from 1 to 5 MPa,the shape parameter and the scale parameter decrease by 22.18%and 60.45%,respectively,indicating a reduction in both brittleness and strength of the coal.Parameters such as maximum damage rate and peak elastic energy storage limit positively correlate with coal brittleness.The brittleness index effectively captures the brittleness characteristics and reveals a decrease in brittleness and an increase in sensitivity to plastic deformation under higher gas pressure conditions. 展开更多
关键词 gas pressure statistical damage constitutive model energy evolution mechanism brittleness evaluation gas bearing coal
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绣球花状CoAl双金属氢氧化物的合成及作为高性能超级电容器电极材料的研究
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作者 张悦 高春莉 +2 位作者 徐迈 朱传高 王凤武 《现代化工》 北大核心 2025年第2期129-135,145,共8页
采用一步热液法在泡沫镍表面均匀生长3D绣球花状结构CoAl-LDHs。对比了不同形貌的CoAl-LDHs对电化学性能的影响。结果表明,当电流密度为1 A/g时,绣球花状的CoAl-LDHs的比电容为982.2 F/g,比块状的CoAl-LDHs的比电容(251.1 F/g)大。将绣... 采用一步热液法在泡沫镍表面均匀生长3D绣球花状结构CoAl-LDHs。对比了不同形貌的CoAl-LDHs对电化学性能的影响。结果表明,当电流密度为1 A/g时,绣球花状的CoAl-LDHs的比电容为982.2 F/g,比块状的CoAl-LDHs的比电容(251.1 F/g)大。将绣球花状的电极材料与活性炭(AC)组装为超级电容器CoAl-LDH//AC,得到的最大功率密度为1.58 kW/kg,最大能量密度达249.5 Wh/kg,同时循环5 000次后得到改性后的CoAl-LDH//AC的电流保持率为85.5%,比改性前的电流保持率(60.2%)有较大提升。 展开更多
关键词 超级电容器 层状双氢氧化物 coal-LDHs 绣球花状
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Dynamic characteristics of coal specimens with varying static preloading levels under low-frequency disturbance load 被引量:1
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作者 WEN Xiao-ze FENG Guo-rui +5 位作者 GUO Jun YU Lu-yang QIAN Rui-peng ZHANG Jie ZHANG Peng-fei FENG Wen-ming 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2644-2657,共14页
The mechanical properties of residual coal pillars under the influence of upward mining disturbances significantly affect the safety of residual mining activities on working faces.This study conducted low-frequency di... The mechanical properties of residual coal pillars under the influence of upward mining disturbances significantly affect the safety of residual mining activities on working faces.This study conducted low-frequency disturbance dynamic uniaxial compression tests on coal specimens using a self-developed dynamic-static load coupling electro-hydraulic servo system,and studied the strength evolutions,surface deformations,acoustic emission(AE)characteristic parameters,and the failure modes of coal specimens with different static preloading levels were studied.The disturbance damage is positively correlated with the coal specimen static preload level.Specifically,the cumulative AE count rates of the initial accelerated damage stage for the coal specimens with static preloading level of 60%and 70%of the uniaxial compressive strength(UCS)were 2.66 and 3.19 times that of the 50%UCS specimens,respectively.Macroscopically,this behaviour manifested as a decrease in the compressive strength,and the mean strengths of the disturbance-damaged coal specimens with 60%and 70%of UCS static preloading decreased by 8.53%and 9.32%,respectively,compared to those of the specimens under pure static loading.The crack sources,such as the primary fissures,strongly control the dynamic response of the coal specimen.The difference between the dynamic responses of the coal specimens and that of dense rocks is significant. 展开更多
关键词 low-frequency disturbance dynamic response coal specimens static preloading level
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Macroscopic and microscopic mechanical behavior and seepage characteristics of coal under hydro-mechanical coupling 被引量:1
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作者 GAO Ming-zhong GAO Zheng +6 位作者 YANG Ben-gao XIE Jing WANG Ming-yao HAO Hai-chun WU Yan ZHOU Lang WANG Jing-yu 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2765-2779,共15页
Understanding the physical,mechanical behavior,and seepage characteristics of coal under hydro-mechanical coupling holds significant importance for ensuring the stability of surrounding rock formations and preventing ... Understanding the physical,mechanical behavior,and seepage characteristics of coal under hydro-mechanical coupling holds significant importance for ensuring the stability of surrounding rock formations and preventing gas outbursts.Scanning electron microscopy,uniaxial tests,and triaxial tests were conducted to comprehensively analyze the macroscopic and microscopic physical and mechanical characteristics of coal under different soaking times.Moreover,by restoring the stress path and water injection conditions of the protective layer indoors,we explored the coal mining dynamic behavior and the evolution of permeability.The results show that water causes the micro-surface of coal to peel off and cracks to expand and develop.With the increase of soaking time,the uniaxial and triaxial strengths were gradually decreased with nonlinear trend,and decreased by 63.31%and 30.95%after soaking for 240 h,respectively.Under different water injection pressure conditions,coal permeability undergoes three stages during the mining loading process and ultimately increases to higher values.The peak stress of coal,the deviatoric stress and strain at the permeability surge point all decrease with increasing water injection pressure.The results of this research can help improve the understanding of the coal mechanical properties and seepage evolution law under hydro-mechanical coupling. 展开更多
关键词 coal water intrusion mechanical properties PERMEABILITY macro and micro features
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多功能CoAl-LDH/CdS光催化剂的制备及其性能研究 被引量:1
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作者 唐丹琪 阳敏 +3 位作者 朱子 张海燕 李铭 李佑稷 《功能材料》 CAS CSCD 北大核心 2024年第7期7166-7176,共11页
在能源危机和环境污染的双重挑战下,开发集能量转化和环境治理于一体的多功能光催化剂是促进太阳能-化学能转化的有效策略。采用正六边形的CoAl-LDH纳米薄片为载体,通过原位生长CdS纳米颗粒的方法,构建了CoAl-LDH/CdS的Ⅱ型异质结。利用... 在能源危机和环境污染的双重挑战下,开发集能量转化和环境治理于一体的多功能光催化剂是促进太阳能-化学能转化的有效策略。采用正六边形的CoAl-LDH纳米薄片为载体,通过原位生长CdS纳米颗粒的方法,构建了CoAl-LDH/CdS的Ⅱ型异质结。利用CoAl-LDH纳米薄片在可见光区域的宽普吸收性和良好载体的特性,结合CdS的高光量子产率,再通过异质结构的构建,获得了多功能CoAl-LDH/CdS光催化材料。并通过优化CdS的负载量,获得的CoAl-LDH/CdS-2光催剂降解罗丹明B的降解率最大(在光催化降解时间t=60 min时内,降解率=88.48%),分别是CdS和CoAl-LDH单体的1.18倍和8.62倍。其中CoAl-LDH/CdS-1的CO产量最高为39.02 mol/g,分别是纯CoAl-LDH和纯CdS的4.2倍和2.5倍,这主要归功于复合材料中CoAl-LDH纳米片和CdS纳米颗粒间紧密异质结构的构建,丰富的耦合界面大大降低了光生载流子的复合率,这为多功能光催化剂的开发提供了理论基础。 展开更多
关键词 coal-LDH CDS 异质结 光催化降解 CO 2还原
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Failure mechanisms and destruction characteristics of cemented coal gangue backfill under compression effect of non-uniform load 被引量:1
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作者 FENG Guo-rui GUO Wei +5 位作者 QI Ting-ye LI Zhu CUI Jia-qing WANG Hao-chen CUI Ye-kai MA Jing-kai 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2676-2693,共18页
Backfill mining is one of the most important technical means for controlling strata movement and reducing surface subsidence and environmental damage during exploitation of underground coal resources. Ensuring the sta... Backfill mining is one of the most important technical means for controlling strata movement and reducing surface subsidence and environmental damage during exploitation of underground coal resources. Ensuring the stability of the backfill bodies is the primary prerequisite for maintaining the safety of the backfilling working face, and the loading characteristics of backfill are closely related to the deformation and subsidence of the roof. Elastic thin plate model was used to explore the non-uniform subsidence law of the roof, and then the non-uniform distribution characteristics of backfill bodies’ load were revealed. Through a self-developed non-uniform loading device combined with acoustic emission (AE) and digital image correlation (DIC) monitoring technology, the synergistic dynamic evolution law of the bearing capacity, apparent crack, and internal fracture of cemented coal gangue backfills (CCGBs) under loads with different degrees of non-uniformity was deeply explored. The results showed that: 1) The uniaxial compressive strength (UCS) of CCGB increased and then decreased with an increase in the degree of non-uniformity of load (DNL). About 40% of DNL was the inflection point of DNL-UCS curve and when DNL exceeded 40%, the strength decreased in a cliff-like manner;2) A positive correlation was observed between the AE ringing count and UCS during the loading process of the specimen, which was manifested by a higher AE ringing count of the high-strength specimen. 3) Shear cracks gradually increased and failure mode of specimens gradually changed from “X” type dominated by tension cracks to inverted “Y” type dominated by shear cracks with an increase in DNL, and the crack opening displacement at the peak stress decreased and then increased. The crack opening displacement at 40% of the DNL was the smallest. This was consistent with the judgment of crack size based on the AE b-value, i. e., it showed the typical characteristics of “small b-value-large crack and large b-value-small crack”. The research results are of significance for preventing the instability and failure of backfill. 展开更多
关键词 cemented coal gangue backfill non-uniform load degree of non-uniformity of load failure mode crack opening displacement
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Mechanical heterogeneity characterization of coal materials based on nano-indentation experiments
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作者 ZHANG Qi LI Xiang-chun +3 位作者 LI Biao MENG Jun-qing NIE Bai-sheng LU Wei-dong 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第9期3142-3155,共14页
To investigate the complex macro-mechanical properties of coal from a micro-mechanical perspective,we have conducted a series of micro-mechanical experiments on coal using a nano-indentation instrument.These experimen... To investigate the complex macro-mechanical properties of coal from a micro-mechanical perspective,we have conducted a series of micro-mechanical experiments on coal using a nano-indentation instrument.These experiments were conducted under both dynamic and static loading conditions,allowing us to gather the micro-mechanical parameters of coal for further analysis of its micro-mechanical heterogeneity using the box counting statistical method and the Weibull model.The research findings indicate that the load–displacement curves of the coal mass under the two different loading modes exhibit noticeable discreteness.This can be attributed to the stress concentration phenomenon caused by variations in the mechanical properties of the micro-units during the loading process of the coal mass.Consequently,there are significant fluctuations in the micro-mechanical parameters of the coal mass.Moreover,the mechanical heterogeneity of the coal at the nanoscale was confirmed based on the calculation results of the standard deviation coefficient and Weibull modulus of the coal body’s micromechanical parameters.These results reveal the influence of microstructural defects and minerals on the uniformity of the stress field distribution within the loaded coal body,as well as on the ductility characteristics of the micro-defect structure.Furthermore,there is a pronounced heterogeneity in the micromechanical parameters.Furthermore,we have established a relationship between the macro and micro elastic modulus of coal by applying the Mori-Tanaka homogenization method.This relationship holds great significance for revealing the micro-mechanical failure mechanism of coal. 展开更多
关键词 nano-indentation experiment MICROMECHANICS heterogeneity characterization coal
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Effect of hybrid type of fibers on the mechanical properties of stabilized sand with coal waste and cement
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作者 AFRAKOTI Mobina Taslimi Paein CHOOBBASTI Asskar Janalizadeh +1 位作者 KUTANAEI Saman Soleimani VAFAEI Ali 《Journal of Central South University》 CSCD 2024年第11期4276-4292,共17页
Coal waste(CW)could be used for soil stabilization due to the pozzolanic elements it contains.There hasn’t been much investigation into how different fibers affect the mechanical qualities of stabilized sand,although... Coal waste(CW)could be used for soil stabilization due to the pozzolanic elements it contains.There hasn’t been much investigation into how different fibers affect the mechanical qualities of stabilized sand,although adding fibers of any kind to soils may improve the soil because of fiber characteristics like rigidity.For this reason,several tests were carried out on sand that contained 6%cement(by dry weight of used sand),5 wt%CW,0 wt%,0.25 wt%,and 0.50 wt%fiber,as well as the unconfined compressive strength(UCS)test,indirect tensile strength(ITS)test,unconsolidated undrained(UU)triaxial test,scanning electron microscope(SEM)test and ultrasonic pulse velocity(UPV)test.The results showed that in comparison to other fiber reinforced mix designs,the specimen reinforced with 0.5%fibers and the mix design of 0.25 wt%glass and 0.25 wt%polypropylene(PP)fibers exhibited the maximum strength.Examining the impact of fiber type found that glass fibers influence PP strength more favorably than other fiber types.The use of PP fibers is an excellent solution for the problem of large strains in design processes,while adding glass fibers is considered a suitable treatment for issues related to small strains. 展开更多
关键词 coal waste CEMENT unconfined compressive strength ultrasonic pulse velocity
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中国煤岩气突破及意义 被引量:3
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作者 邹才能 赵群 +15 位作者 刘翰林 孙粉锦 陈艳鹏 邓泽 于荣泽 李士祥 杨智 吴松涛 马锋 高金亮 沈振 周国晓 尹帅 宋昱 郭秋雷 李勇 《天然气工业》 北大核心 2025年第4期1-18,共18页
近年来,中国煤岩气革命是非常规天然气的一匹“黑马”,中国石油建成了世界首个年产200×10^(4) t油气当量煤岩气田,实现煤岩气科技、管理与战略3个创新,对全球非常规油气发展具有重大意义。煤岩气突破体现出坚持以“源岩油气”为导... 近年来,中国煤岩气革命是非常规天然气的一匹“黑马”,中国石油建成了世界首个年产200×10^(4) t油气当量煤岩气田,实现煤岩气科技、管理与战略3个创新,对全球非常规油气发展具有重大意义。煤岩气突破体现出坚持以“源岩油气”为导向的勘探战略及“立足常规、突破非常规”理论体系的科学性,或可能是中国继页岩油气革命之后的一场“新革命”。为了进一步促进煤岩气规模化勘探开发进程,在阐述煤岩气概念、内涵、类型及发育特征的基础上,系统论述了煤岩气革命的科学意义,总结了当前煤岩气核心勘探开发技术,指出了煤岩气面临的挑战和未来的发展方向。研究结果表明:①中国非常规油气发展历经油砂稠油、致密砂岩油气、页岩油气和煤岩油气4个阶段,煤岩气革命历经了“煤成气”理论、“煤层气”理论、“煤岩气”理论3个阶段与3次突破。②煤岩气指煤岩地层内形成的天然气,煤岩气富集具有“原生原储、原位原聚”特点。③煤岩气革命的科学内涵包括将资源视野从浅层煤岩气扩展到深层煤岩气的科技革命、注重降本增效的管理革命和新增中国天然气新气源的战略革命。④煤岩气两种类型包括地下原位先天地温形成的“煤岩气”、地下原位人工加热形成的“煤岩气”,前者富集的3个关键特征是进入中高成熟度、自封闭顶底板和较高占比游离气;随着原位加热改造技术的发展,地下原位人工加热形成的“煤岩气”资源,有望在天然气工业中发挥出更大的战略性潜力。⑤目前中国煤岩气5个核心勘探开发技术进展包括煤岩气甜点区/段分类标准的制定、高精度地震/地质一体化导向的实现、聚能经济压裂技术的探索、控压排采开发模式的创建、煤岩气数智化平台的开发。⑥煤岩气革命发展仍面临4个关键挑战包括“甜点区/段”分布规律认识不清、低成本少水—无水压裂工艺研发滞后、智能化井工厂建设不能满足需求、煤岩气产量峰值维持难度大。结论认为,中国煤岩气革命将对天然气工业产生重大影响,具体体现在将不断丰富非常规油气地质学理论、地下煤炭气化有望成为一场“真正革命”、人工智能驱动煤岩气创新发展、加速构建天然气经济效益评价完整体系。 展开更多
关键词 煤岩气概念 煤岩气地质理论 煤岩气类型 煤岩气技术 煤岩气革命 非常规天然气
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Tar formation characteristic of integrated process of coal pyrolysis with dry reforming of low carbon alkane over Ni/La_(2)O_(3)-ZrO_(2)
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作者 LÜJiannan LI Yang +1 位作者 JIN Lijun HU Haoquan 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第12期1823-1833,I0001-I0006,共17页
Coal pyrolysis integrated with dry reforming of low-carbon alkane(CP-DRA)is an effective way to improve tar yield.Ni/La_(2)O_(3)-ZrO_(2) with a La/Zr ratio of 4 was a good catalyst for DRA to inhibit carbon deposition... Coal pyrolysis integrated with dry reforming of low-carbon alkane(CP-DRA)is an effective way to improve tar yield.Ni/La_(2)O_(3)-ZrO_(2) with a La/Zr ratio of 4 was a good catalyst for DRA to inhibit carbon deposition and obtain high tar yield in CP-DRA.In this study,the fraction distribution and component of tars from CP-DRA and coal pyrolysis in N_(2) atmosphere(CP-N_(2))were characterized by using several methods to understand the effect of DRA on coal pyrolysis.The isotope trace method was also used to discuss the role of low-carbon alkane in CP-DRA.The results showed that the tar from CP-N_(2)is mainly composed of aliphatic compounds with more C_(al),H_(al) and CH+CH_(2),and the tar from CP-DRA contains more Car,Har,and CH_(3),and has lower weight-average molecular weight and more light tar content than CP-N_(2).A small amount of C_(2)H_(6) addition in CP-DRA will raise the ratio of H_(β) and CH+CH_(2).Electron paramagnetic resonance(EPR)analysis shows that the tar from CP-DRA has a higher radical concentration while the corresponding char has a lower radical concentration.The isotope trace experiment showed that alkanes provide·H,·CH_(3),etc.to stabilize the radicals from coal pyrolysis and result in more alkyl aromatic compounds during CP-DRA. 展开更多
关键词 coal pyrolysis dry reforming low carbon alkane Ni/La_(2)O_(3)-ZrO_(2) TAR
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大倾角极近距离煤层群重复采动巷道围岩破坏规律与控制方法 被引量:3
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作者 贾后省 张志明 +4 位作者 刘少伟 彭博 于辉 邵帅钦 王艺博 《煤炭科学技术》 北大核心 2025年第2期68-80,共13页
大倾角极近距离煤层群开采过程中,巷道受多重采动影响,支护维护困难。针对此类问题,以代池坝煤矿大倾角极近距离煤层群重复采动巷道31233运输巷为工程背景,主要采用数值模拟和现场试验研究方法,研究了巷道围岩应力环境演化特征及其作用... 大倾角极近距离煤层群开采过程中,巷道受多重采动影响,支护维护困难。针对此类问题,以代池坝煤矿大倾角极近距离煤层群重复采动巷道31233运输巷为工程背景,主要采用数值模拟和现场试验研究方法,研究了巷道围岩应力环境演化特征及其作用下巷道围岩破坏规律,设计了有利于围岩塑性破坏分布收敛的非对称屋顶断面,提出了基于巷道围岩塑性区分布规律的非均匀锚杆(索)支护设计方法。研究结果表明:大倾角极近距离煤层群重复采动影响条件下,巷道周边双向主应力差值较大且方向偏转,导致巷道围岩周边破坏呈现非均匀、局部湮灭、最大破坏深度偏转等蝶形特征,巷道内错位置和断面形状决定了巷道破坏形态和范围,内错距直接影响了其围岩塑性区分布与扩展的程度,而坚硬岩层的存在造成塑性区局部湮灭。当巷道内错距离大于17 m时,巷道周边应力趋于稳定,其围岩塑性区大小与形态无明显变化,内错位置大于该距离时,对巷道的围岩稳定性最有利。巷道断面的单边跨度尺寸决定了其所在侧的塑性破坏深度,当巷道断面为非对称屋顶断面时,围岩塑性分布收敛程度显著。巷道断面设计时,巷道最长边应位于坚硬岩层侧且尽量避开最大破坏深度方向,以便充分利用坚硬岩层塑性区湮灭特性,避免巷道围岩塑性区蝶叶过度扩展。因此,可充分利用大倾角非对称屋顶形巷道断面的几何特征,基于巷道围岩塑性区分布规律与合理锚固层位分布特征,进行非均匀锚杆(索)支护设计,有效保障锚杆(索)支护力的发挥的同时,保障巷道围岩的整体稳定。同时,在31233运输巷进行了试验,布设了巷道顶板深部位移与锚索支护力监测站,监测期间顶板变形量在100 mm以内,锚索支护力发挥稳定,围岩整体控制效果较好。 展开更多
关键词 大倾角 极近距离煤层群 重复采动 回采巷道 支护
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特厚煤层采放协调智能群组放煤工艺模型及关键技术研究 被引量:1
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作者 李东印 王祖洸 +5 位作者 王伸 李化敏 彭维平 李红斌 张国澎 张旭和 《河南理工大学学报(自然科学版)》 北大核心 2025年第3期22-33,共12页
目的综放开采是特厚煤层安全高效的开采方法,放煤环境复杂多变、采放协调难度大、放煤工艺及参数受控因素多,导致智能化综放开采尤其是智能放煤控制技术发展较为缓慢。针对特厚煤层综放面群组放煤下的智能化放煤控制难题,方法采用理论... 目的综放开采是特厚煤层安全高效的开采方法,放煤环境复杂多变、采放协调难度大、放煤工艺及参数受控因素多,导致智能化综放开采尤其是智能放煤控制技术发展较为缓慢。针对特厚煤层综放面群组放煤下的智能化放煤控制难题,方法采用理论分析、实验室仿真试验、计算机控制软件研发、现场试验与示范等方法,以“智能群组放煤机理-采放协调控制理论及方法-放煤工艺决策模型-放煤软件现场应用”为主线展开深入研究。结果结果表明:提出多放煤口群组协同放煤方法,以连续群组放煤为例,揭示了多放煤口群组协同放煤下的顶煤放出体和煤岩分界面的空间关系;深入剖析综放工作面的采放协调关系及群组放煤逻辑,提出特厚煤层综放面采放协调智能放煤控制理论,构建了综放面采放时间、空间和运能协调控制模型和基于强化学习及隐马尔科夫随机场模型的群组放煤协同控制决策方法,为智能化放煤决策与精准控制提供可靠理论基础;深度融合地质信息与采放工艺参数,建立了综放面多源信息数据库,为智能决策及数字孪生提供数据基础。结论基于群组放煤条件下的采放协调特征,构建了智能放煤决策模型,自主研发智能放煤决策系统(软件),实现了智能放煤工作面年产1500万t。 展开更多
关键词 特厚煤层 综放开采 智能放煤 采放协调 群组放煤
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深部开采煤矿典型动力灾害孕灾主控因素与机制研究进展 被引量:3
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作者 杨科 郭鹏慧 +4 位作者 袁亮 曹安业 张永将 马衍坤 李家卓 《煤炭学报》 北大核心 2025年第7期3466-3487,共22页
煤炭资源的开采逐渐进入深部开采阶段,煤岩的非线性行为、大范围高能级灾害、多物理场耦合等现象加剧,冲击地压和煤与瓦斯突出二者相互诱导、相互激励,煤矿典型动力灾害危险性和危害性渐趋严重,已成为制约我国深部煤炭资源安全高效生产... 煤炭资源的开采逐渐进入深部开采阶段,煤岩的非线性行为、大范围高能级灾害、多物理场耦合等现象加剧,冲击地压和煤与瓦斯突出二者相互诱导、相互激励,煤矿典型动力灾害危险性和危害性渐趋严重,已成为制约我国深部煤炭资源安全高效生产的绊脚石,防治煤矿典型动力灾害的前提和基础是深入研究其发生机理。因此,需要掌握我国煤矿冲击地压、煤与瓦斯突出和煤岩瓦斯复合动力灾害机理研究领域的整体进展以及孕灾主控因素与机制。文中总结了前人及研究团队已有研究成果,利用CiteSpace软件梳理文献,并通过关键词共现和突现知识图谱分析,阐述了煤矿典型动力灾害领域发展历程中每个阶段的研究热点以及未来的发展态势;厘清了不同孕灾条件对煤与瓦斯突出和冲击地压影响的差异性;探讨了煤矿典型动力灾害孕育的“五效应”机制。分析认为,围绕煤矿典型动力灾害领域的研究均以其发生机理及孕灾因素为基点,其中孕灾因素以天然地质条件为主、开采技术条件为辅,不同的孕灾环境形成的典型动力灾害表现形式不同,典型动力灾害孕育机制包括物质内在效应、应力超载效应、能量驱动效应、结构异变效应和煤岩体时变效应,五者相互作用、相互影响。根据当前深部开采面临的问题和亟需攻克的关键难题提出了研究展望,亟待深入研究煤矿典型动力灾害全生命周期孕育特征、演化特征、致灾机理,深部强扰动作用下煤矿典型动力灾害前兆信息智能辨识、预警指标融合,以及多灾种链生灾害联防联控体系,从而有效保障深部煤炭资源安全高效开采。 展开更多
关键词 深部开采 煤与瓦斯突出 冲击地压 煤岩瓦斯复合动力灾害 孕灾机制
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强突煤层地面丛式井造穴卸压辅助石门揭煤技术 被引量:2
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作者 刘厅 翟成 +4 位作者 童校长 徐鹤翔 邹全乐 林柏泉 徐吉钊 《煤炭科学技术》 北大核心 2025年第5期144-157,共14页
针对深部强突煤层石门揭煤危险性高,打钻过程易喷孔、效率低的难题,基于数值模拟和现场试验研究了强突煤层地面丛式井全覆盖造穴辅助石门揭煤降突机理及关键技术参数优化方法。首先开发了地面丛式井多级造穴技术及配套系统;其次揭示了... 针对深部强突煤层石门揭煤危险性高,打钻过程易喷孔、效率低的难题,基于数值模拟和现场试验研究了强突煤层地面丛式井全覆盖造穴辅助石门揭煤降突机理及关键技术参数优化方法。首先开发了地面丛式井多级造穴技术及配套系统;其次揭示了丛式井造穴卸压煤体物理场演化规律,提出了造穴关键技术参数优化方法;最后成功开展了石门揭煤控制区地面丛式井全覆盖造穴辅助消突工程试验,验证了技术的有效性。结果表明:提出了多场协同调控防突方法,揭示了地面丛式井区域全覆盖造穴强化卸压增透,辅助石门揭煤消突机理,开发了“机械扩孔-水力喷射-排水释压”多级造穴技术,并配套研发了“造穴-排渣-水渣分离”一体化系统。煤体塑性区体积与等效直径平方呈线性关系,研究条件下的比值为81.90;洞穴附近低渗透区瓦斯压力随着洞穴直径的增大先降低后升高,对应的最优洞穴直径为2.0 m;揭煤巷道沿着垂直于最大主应力方向布置时,造穴后巷道两侧煤体更容易消突。成功开展了石门揭煤控制区地面丛式井全覆盖造穴辅助消突工程试验,技术实施后,煤层透气性系数提高约10倍,残余瓦斯压力和残余瓦斯含量显著降低,试验地点井下揭煤措施孔数量减少了24%、钻孔工程量降低了21%。开发的技术可进一步拓展形成“地面井煤气共采”方法,有望实现难采-难抽煤层煤与瓦斯的协同高效共采。 展开更多
关键词 强突煤层 石门揭煤 地面井造穴 应力-渗流耦合 煤气共采
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暗环境适应性的基于SLAM的煤矿井下机器人定位方法 被引量:1
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作者 江松 崔智翔 +3 位作者 代碧波 饶彬舰 何润丰 王浩宇 《煤炭科学技术》 北大核心 2025年第5期349-361,共13页
在智慧矿山建设的背景下,智能化设备的应用日益成为矿山智慧化改造的主要内容,用于巡检、危险区域勘测等任务的煤矿井下智能机器人运行依赖于数字地图构建和机器人自身定位,但大多数传统的定位方法在煤矿井下出现了低效甚至失效的情况,... 在智慧矿山建设的背景下,智能化设备的应用日益成为矿山智慧化改造的主要内容,用于巡检、危险区域勘测等任务的煤矿井下智能机器人运行依赖于数字地图构建和机器人自身定位,但大多数传统的定位方法在煤矿井下出现了低效甚至失效的情况,同步定位与建图技术(Simultaneous Localization and Mapping,SLAM)成为了煤矿井下智能机器人定位方法的较优选择。然而,受制于激光雷达的高成本,以及相机在井下的低光照环境性能不佳,需要设计一种兼顾低成本和具有井下低光照环境适应性的SLAM定位方法,故提出了一种具有井下暗光照适应性煤矿井下机器人定位方法。首先,采集了陕西省宝鸡市凤县某煤矿井下的实景图像和SLAM所需的相机与IMU数据,根据图像制作了非匹配的暗光与正常光数据集,经过数据扩增达到3560张图像。设计了结合自注意力模块的EnlightenGAN图像增强网络,在不依赖配对数据集的情况下兼顾图像不同区域的依赖关系应对图像光照不均区域。在ORB-SLAM3框架的基础上,引入全局部图像检测对输入图像进行筛分,引入基于解析解的IMU初始化改进策略提高初始化速度,并引入了改进的图像增强网络对低光照以及光照不均的图像进行增强处理。在EuRoC数据集上的试验表明,基于图像增强的煤矿井下智能机器人定位方法能够在低光照环境下降低13.7%的ERMS和15.24%的ESD。在2个实际煤矿巷道场景中,系统能够识别低光照环境、增加SLAM系统提取的特征点数量,减少定位轨迹的漂移现象,最终改善系统在巷道低光照区域的定位效果。 展开更多
关键词 同步建图与定位 井下煤矿 煤矿机器人 图像增强
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