A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]py...A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazine scaffold was serendipitously prepared from the reaction of the pro-ligand of H_(2)L1(N,N'-bis(pyrazin-2-ylmethyl)pyrazine-2,3-dicarboxamide) with CuSO_(4)·5H_(2O) in aqueous solution at room temperature.Complex 1 was characterized by IR,single-crystal X-ray analysis,and magnetic susceptibility measurements.Single-crystal X-ray analysis reveals that the complex consists of three Cu(Ⅱ) ions,two in situ transformed L2~-ligands,two coordinated sulfates,seven coordinated water molecules,and eight uncoordinated water molecules.Magnetic susceptibility measurement indicates that there are obvious ferromagnetic coupling interactions between the adjacent Cu(Ⅱ) ions in 1.CCDC:1852713.展开更多
During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents ...During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents a method for evalu-ating the electrical performance of the radome when subjected to thermo-mechanical-electrical(TME)coupling.The method involves establishing a TME coupling model(TME-CM)based on the TME sharing mesh model(TME-SMM)generated by the tetrahedral mesh partitioning of the radome structure.The effects of dielectric temperature drift and structural deformation on the radome’s electrical performance are also considered.Firstly,the temperature field of the radome is obtained by tran-sient thermal analysis while the deformation field of the radome is obtained by static analysis.Subsequently,the dielectric varia-tion and structural deformation of the radome are accurately incorporated into the electrical simulation model based on the TME-SMM.The three-dimensional(3D)ray tracing method with the aperture integration technique is used to calculate the radome’s electrical performance.A representative example is provided to illustrate the superiority and necessity of the pro-posed method.This is achieved by calculating and analyzing the changes in the radome’s electrical performance over time dur-ing high-speed flight.展开更多
Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduce...Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduced a computational model for analyzing probabilistic dynamic responses of three-dimensional(3D)coupled train-ballasted track-subgrade system(TBTSS),where the coupling effects of uncertain rail irregularities,stiffness and damping properties of ballast and subgrade layers were simultaneously considered.The number theoretical method(NTM)was employed to design discrete points for the multi-dimensional stochastic parameters.The time-histories of stochastic dynamic vibrations of the TBSS with systematically uncertain structural parameters were calculated accurately and efficiently by employing the probability density evolution method(PDEM).The model-predicted results were consistent with those by the Monte Carlo simulation method.A sensitivity study was performed to assess the relative importance of those uncertain structural parameters,based on which a case study was presented to explore the stochastic probability evolution mechanism of such train-ballasted track-subgrade system.展开更多
The joint of clay core-wall and concrete cut-off wall is one of the weakest parts in high earth and rockftll dams.A kind of highly plastic clay is always fixed on the joint to fit the large shear deformation between c...The joint of clay core-wall and concrete cut-off wall is one of the weakest parts in high earth and rockftll dams.A kind of highly plastic clay is always fixed on the joint to fit the large shear deformation between clay core-wall and concrete cut-offwall,so the hydro-mechanical coupling mechanisms on the joint under high stress,high hydraulic gradient,and large shear deformation are of great importance for the evaluation of dam safety.The hydro-mechanical coupling characteristics of the joint of the highly plastic clay and the concrete cut-off wall in a high earth and rockfill dam in China were studied by using a newly designed soil-structure contact erosion apparatus.The experimental results indicate that：1） Shear failure on the joint is due to the hydro-mechanical coupling effect of stress and seepage failure.The seepage failure will induce the final shear failure when the ratio of deviatoric stress to confining pressure is within 1.0-1.2; 2） A negative exponential permeability empirical model for the joint denoted by a newly defined principal stress function,which considers the coupling effect of confining pressure and axial pressure on the permeability,is established based on hydro-mechanical coupling experiments.3） The variation of the settlement before and after seepage failure is very different.The settlement before seepage failure changes very slowly,while it increases significantly after the seepage failure.4） The stress-strain relationship is of a strain softening type.5） Flow along the joint still follows Darcian flow rule.The results will provide an important theoretical basis for the further evaluation on the safety of the high earth and rockfill dam.展开更多
It is shown that the 3d5(4X) 4s(5X)of 4s satellites ,except to the coupling between 3d54s(7,5S) and 3p→ 3d transition ,plays a key role on the magnitude of photoionization of 4s cross section .The coupled equation me...It is shown that the 3d5(4X) 4s(5X)of 4s satellites ,except to the coupling between 3d54s(7,5S) and 3p→ 3d transition ,plays a key role on the magnitude of photoionization of 4s cross section .The coupled equation methodis improvedto calculate this resonance by including these channels .The results of calculations are compared with the experimental data from 4 6eV to 5 6eV photon energies,which are in good agreement with the experiment.展开更多
Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interac...Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.展开更多
为明晰水肥耦合对炭基质栽培番茄产量品质的提升效应,将生物炭混掺到由酒糟、秸秆等农业废弃物拌制成的基质模块中,设置2个灌溉量(I_(1):100%ET_(c),I_(2):80%ET_(c),ET_(c)为作物蒸发蒸腾量),2个施肥量(N-P_(2)O_(5)-K_(2)O)(F_(1):240...为明晰水肥耦合对炭基质栽培番茄产量品质的提升效应,将生物炭混掺到由酒糟、秸秆等农业废弃物拌制成的基质模块中,设置2个灌溉量(I_(1):100%ET_(c),I_(2):80%ET_(c),ET_(c)为作物蒸发蒸腾量),2个施肥量(N-P_(2)O_(5)-K_(2)O)(F_(1):240-180-200 kg/hm^(2),F2:180-135-150 kg/hm^(2))及基质中4个生物炭添加量(B0:0,B1:1%,B3:3%,B5:5%),共16组处理,研究水肥耦合对炭基质栽培番茄叶面积指数(leaf area index,LAI)、叶绿素相对含量(soil and plant analyzer development,SPAD)、植株养分(全氮、全钾、有机碳)吸收量、化学计量特征(氮钾比、碳氮比)、产量及品质(可溶性固形物含量、维生素C含量、硝酸盐含量、可溶性糖含量、可滴定酸含量、糖酸比)的影响,揭示炭基质栽培番茄产量及品质的关键驱动因子,构建以番茄产量、品质及其关键驱动因子为目标的熵权-TOPSIS多目标综合评价模型,提出水肥与炭基质耦合的最优方案。结果表明:炭基质对番茄LAI、SPAD值、养分吸收量、产量及品质影响显著(P<0.05);在相同灌溉和施肥条件下,炭基质增加了番茄整株钾吸收量、整株碳同化量、产量及维生素C含量,降低了硝酸盐含量;基于结构方程模型,番茄整株碳同化量是产量的关键驱动因子,其增加有助于提高番茄产量,氮钾比是品质的关键驱动因子,其降低有助于改善番茄品质;采用熵权-TOPSIS多目标综合评价模型,筛选出I_(1)F_(2)B_(3)处理是水肥与炭基质耦合的最优方案。研究可为农业废弃物高效利用及高品质果蔬的水肥炭有效管理提供理论依据。展开更多
文摘A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazine scaffold was serendipitously prepared from the reaction of the pro-ligand of H_(2)L1(N,N'-bis(pyrazin-2-ylmethyl)pyrazine-2,3-dicarboxamide) with CuSO_(4)·5H_(2O) in aqueous solution at room temperature.Complex 1 was characterized by IR,single-crystal X-ray analysis,and magnetic susceptibility measurements.Single-crystal X-ray analysis reveals that the complex consists of three Cu(Ⅱ) ions,two in situ transformed L2~-ligands,two coordinated sulfates,seven coordinated water molecules,and eight uncoordinated water molecules.Magnetic susceptibility measurement indicates that there are obvious ferromagnetic coupling interactions between the adjacent Cu(Ⅱ) ions in 1.CCDC:1852713.
文摘During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents a method for evalu-ating the electrical performance of the radome when subjected to thermo-mechanical-electrical(TME)coupling.The method involves establishing a TME coupling model(TME-CM)based on the TME sharing mesh model(TME-SMM)generated by the tetrahedral mesh partitioning of the radome structure.The effects of dielectric temperature drift and structural deformation on the radome’s electrical performance are also considered.Firstly,the temperature field of the radome is obtained by tran-sient thermal analysis while the deformation field of the radome is obtained by static analysis.Subsequently,the dielectric varia-tion and structural deformation of the radome are accurately incorporated into the electrical simulation model based on the TME-SMM.The three-dimensional(3D)ray tracing method with the aperture integration technique is used to calculate the radome’s electrical performance.A representative example is provided to illustrate the superiority and necessity of the pro-posed method.This is achieved by calculating and analyzing the changes in the radome’s electrical performance over time dur-ing high-speed flight.
基金Projects(51708558,51878673,U1734208,52078485,U1934217,U1934209)supported by the National Natural Science Foundation of ChinaProject(2020JJ5740)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(KF2020-03)supported by the Key Open Fund of State Key Laboratory of Mechanical Behavior and System Safety of Traffic Engineering Structures,ChinaProject(2020-Special-02)supported by the Science and Technology Research and Development Program of China Railway Group Limited。
文摘Random dynamic responses caused by the uncertainty of structural parameters of the coupled train-ballasted track-subgrade system under train loading can pose safety concerns to the train operation.This paper introduced a computational model for analyzing probabilistic dynamic responses of three-dimensional(3D)coupled train-ballasted track-subgrade system(TBTSS),where the coupling effects of uncertain rail irregularities,stiffness and damping properties of ballast and subgrade layers were simultaneously considered.The number theoretical method(NTM)was employed to design discrete points for the multi-dimensional stochastic parameters.The time-histories of stochastic dynamic vibrations of the TBSS with systematically uncertain structural parameters were calculated accurately and efficiently by employing the probability density evolution method(PDEM).The model-predicted results were consistent with those by the Monte Carlo simulation method.A sensitivity study was performed to assess the relative importance of those uncertain structural parameters,based on which a case study was presented to explore the stochastic probability evolution mechanism of such train-ballasted track-subgrade system.
基金Projects(51009053,51079039)supported by the National Natural Science Foundation of ChinaProject(20100094120004)supported by the Doctoral Program of Higher Education of China
文摘The joint of clay core-wall and concrete cut-off wall is one of the weakest parts in high earth and rockftll dams.A kind of highly plastic clay is always fixed on the joint to fit the large shear deformation between clay core-wall and concrete cut-offwall,so the hydro-mechanical coupling mechanisms on the joint under high stress,high hydraulic gradient,and large shear deformation are of great importance for the evaluation of dam safety.The hydro-mechanical coupling characteristics of the joint of the highly plastic clay and the concrete cut-off wall in a high earth and rockfill dam in China were studied by using a newly designed soil-structure contact erosion apparatus.The experimental results indicate that：1） Shear failure on the joint is due to the hydro-mechanical coupling effect of stress and seepage failure.The seepage failure will induce the final shear failure when the ratio of deviatoric stress to confining pressure is within 1.0-1.2; 2） A negative exponential permeability empirical model for the joint denoted by a newly defined principal stress function,which considers the coupling effect of confining pressure and axial pressure on the permeability,is established based on hydro-mechanical coupling experiments.3） The variation of the settlement before and after seepage failure is very different.The settlement before seepage failure changes very slowly,while it increases significantly after the seepage failure.4） The stress-strain relationship is of a strain softening type.5） Flow along the joint still follows Darcian flow rule.The results will provide an important theoretical basis for the further evaluation on the safety of the high earth and rockfill dam.
文摘It is shown that the 3d5(4X) 4s(5X)of 4s satellites ,except to the coupling between 3d54s(7,5S) and 3p→ 3d transition ,plays a key role on the magnitude of photoionization of 4s cross section .The coupled equation methodis improvedto calculate this resonance by including these channels .The results of calculations are compared with the experimental data from 4 6eV to 5 6eV photon energies,which are in good agreement with the experiment.
基金Project(50678059) supported by the National Natural Science Foundation of China
文摘Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.
文摘为明晰水肥耦合对炭基质栽培番茄产量品质的提升效应,将生物炭混掺到由酒糟、秸秆等农业废弃物拌制成的基质模块中,设置2个灌溉量(I_(1):100%ET_(c),I_(2):80%ET_(c),ET_(c)为作物蒸发蒸腾量),2个施肥量(N-P_(2)O_(5)-K_(2)O)(F_(1):240-180-200 kg/hm^(2),F2:180-135-150 kg/hm^(2))及基质中4个生物炭添加量(B0:0,B1:1%,B3:3%,B5:5%),共16组处理,研究水肥耦合对炭基质栽培番茄叶面积指数(leaf area index,LAI)、叶绿素相对含量(soil and plant analyzer development,SPAD)、植株养分(全氮、全钾、有机碳)吸收量、化学计量特征(氮钾比、碳氮比)、产量及品质(可溶性固形物含量、维生素C含量、硝酸盐含量、可溶性糖含量、可滴定酸含量、糖酸比)的影响,揭示炭基质栽培番茄产量及品质的关键驱动因子,构建以番茄产量、品质及其关键驱动因子为目标的熵权-TOPSIS多目标综合评价模型,提出水肥与炭基质耦合的最优方案。结果表明:炭基质对番茄LAI、SPAD值、养分吸收量、产量及品质影响显著(P<0.05);在相同灌溉和施肥条件下,炭基质增加了番茄整株钾吸收量、整株碳同化量、产量及维生素C含量,降低了硝酸盐含量;基于结构方程模型,番茄整株碳同化量是产量的关键驱动因子,其增加有助于提高番茄产量,氮钾比是品质的关键驱动因子,其降低有助于改善番茄品质;采用熵权-TOPSIS多目标综合评价模型,筛选出I_(1)F_(2)B_(3)处理是水肥与炭基质耦合的最优方案。研究可为农业废弃物高效利用及高品质果蔬的水肥炭有效管理提供理论依据。
