To determine the optimal or near optimal parameters of PID controller with incomplete derivation, a novel design method based on differential evolution （DE） algorithm is presented. The controller is called DE-PID co...To determine the optimal or near optimal parameters of PID controller with incomplete derivation, a novel design method based on differential evolution （DE） algorithm is presented. The controller is called DE-PID controller. To overcome the disadvantages of the integral performance criteria in the frequency domain such as IAE, ISE, and ITSE, a new performance criterion in the time domain is proposed. The optimization procedures employing the DE algorithm to search the optimal or near optimal PID controller parameters of a control system are demonstrated in detail. Three typical control systems are chosen to test and evaluate the adaptation and robustness of the proposed DE-PID controller. The simulation results show that the proposed approach has superior features of easy implementation, stable convergence characteristic, and good computational efficiency. Compared with the ZN, GA, and ASA, the proposed design method is indeed more efficient and robust in improving the step response of a control system.展开更多
An optimal PID controller with incomplete derivation is proposed based on fuzzy inference and the geneticalgorithm, which is called the fuzzy-GA PID controller with incomplete derivation. It consists of the off-line p...An optimal PID controller with incomplete derivation is proposed based on fuzzy inference and the geneticalgorithm, which is called the fuzzy-GA PID controller with incomplete derivation. It consists of the off-line part andthe on-line part. In the off-line part, by taking the overshoot, rise time, and settling time of system unit step re-sponse as the performance indexes and by using the genetic algorithm, a group of optimal PID parameters K*p , Ti* ,and Tj are obtained, which are used as the initial values for the on-line tuning of PID parameters. In the on-linepart, based on K; , Ti* , and T*d and according to the current system error e and its time derivative, a dedicatedprogram is written, which is used to optimize and adjust the PID parameters on line through a fuzzy inference mech-anism to ensure that the system response has optimal dynamic and steady-state performance. The controller has beenused to control the D. C. motor of the intelligent bionic artificial leg designed by the authors. The result of computersimulation shows that this kind of optimal PID controller has excellent control performance and robust performance.展开更多
Pitch produced by the lique-faction of coal was divided into two frac-tions:soluble in toluene(TS)and insol-uble in toluene but soluble in pyridine(TI-PS),and their differences in molecu-lar structure and oxidation ac...Pitch produced by the lique-faction of coal was divided into two frac-tions:soluble in toluene(TS)and insol-uble in toluene but soluble in pyridine(TI-PS),and their differences in molecu-lar structure and oxidation activity were studied.Several different carbon materi-als were produced from them by oxida-tion in air(350℃,300 mL/min)fol-lowed by carbonization(1000℃ in Ar),and the effect of the cross-linked structure on their structure and sodium storage properties was investigated.The results showed that the two pitch fractions were obviously different after the air oxidation.The TS fraction with a low degree of condensation and abundant side chains had a stronger oxidation activity and thus introduced more cross-linked oxygen-containing functional groups C(O)―O which prevented carbon layer rearrangement during the carbonization.As a result,a disordered hard carbon with more defects was formed,which improved the electrochemical performance.Therefore,the carbon materials derived from TS(O-TS-1000)had an obvious disordered structure and a larger layer spacing,giving them better sodium storage perform-ance than those derived from the TI-PS fraction(O-TI-PS-1000).The specific capacity of O-TS-1000 was about 250 mAh/g at 20 mA/g,which was 1.67 times higher than that of O-TI-PS-1000(150 mAh/g).展开更多
Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1....Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1.5)Cl_(3)]·5H_(2)O}n(2)are framework isomers,which both contain zigzag chains formed by DPA,Zn^(2+),and Cl-.The zigzag chains in 1 are further assembled by C—H…Cl interactions into layers,and these layers exhibit two different orientations,displaying a rare 2D to 3D interpenetration mode.The zigzag chains in 2 are parallelly arranged.{[Zn_(3)(DPA)_(3)Br_(6)]·2DMF·_(1.5)H_(2)O}n(3)is isostructural to 2.3 was obtained using ZnBr_(2)instead of ZnCl_(2).[M(DPA)(formate)_(2)(H_(2)O)_(2)]n[M=Co(4),Cu(5)]are isostructural,contain chain structures formed by DPA,Cu^(2+)/Co^(2+),and for-mate ions,which were formed in situ in the solvothermal reaction.{[Zn(DIP)_(2)Cl]ClO_(4)}n(6)contains a layer structure formed by DIP and Zn^(2+).Free DPA and DIP ligands exhibited high fluorescence at room temperature,and coordina-tion polymers 3 and 6 displayed enhanced fluorescent emissions.展开更多
We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),campho...We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),camphoric acid(H_(2)cpa)].In[Cd(dip)(cda)]·4H_(2)O}_(n)(1),the Cd^(2+)ions,acting as tetrahedral nodes,are linked by dipand cda^(2-)ligands with four Cd^(2+)ions into five-fold interpenetrating network array of topology of dia.In{[Cd(dip)(cpa)]·4H_(2)O}_(n)(2),the Cd^(2+)ions,acting as a 4-connector,are linked by cpa^(2-)and dip ligands into a 3D framework ofcds topology.In{[Ni(dia)_(2)Cl_(2)]·DMF}_(n)(3),the Ni^(2+)ion is linked by four dia ligands into a layer structure,and 1Dchannels of a cross-section of 1.35 nm×0.96 nm are formed.In{[Cd(dia)_(2)(H_(2)O)_(2)](NO_(3))_(2)·2DMSO}n(4),the dia ligandsconnected Cd^(2+)ions into a 2D layer,and 1D channels are formed between adjacent layers with a cross-section of0.87 nm×0.43 nm.In[Zn(dip)Cl_(2)]_(n)(5),the Zn^(2+)ion is linked by dip ligands into an infinite 1D chain.The infrared,thermal gravimetric,and fluorescent emission data were collected and analyzed for these coordination polymers.CCDC:2356055,1;2440075,2;2356057,3;2356057,4;2356059,5.展开更多
The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively red...The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively reduce C=C or C=O bonds while preserving other functional groups within the molecule.This approach serves as a critical strategy for the directional synthesis of high-value molecules.However,achieving such selectivity remains challenging due to the thermodynamic equilibrium and kinetic competition between C=O and C=C bonds inα,β-unsaturated systems.Consequently,constructing precisely targeted catalytic systems is essential to overcome these limitations,offering both fundamental scientific significance and industrial application potential.Metal-organic frameworks(MOFs)and their derivatives have emerged as innovative platforms for designing such systems,owing to their programmable topology,tunable pore microenvironments,spatially controllable active sites,and modifiable electronic structures.This review systematically summarizes the research progress of MOF-based catalysts for selec-tive hydrogenation ofα,β-unsaturated aldehydes/ketones in the last decade,with emphasis on the design strategy,conformational relationship,and catalytic mechanism,aiming to provide new ideas for the design of targeted catalyt-ic systems for the selective hydrogenation ofα,β-unsaturated aldehydes/ketones.展开更多
Two tetrasubstituted carbazole derivatives TBICz and TOXDCz have been designed and synthesized,which possess the twist skeletons and exhibit excellent thermal and morphological stabilities.Utilizing these novel compou...Two tetrasubstituted carbazole derivatives TBICz and TOXDCz have been designed and synthesized,which possess the twist skeletons and exhibit excellent thermal and morphological stabilities.Utilizing these novel compounds as host material,high efficiency solution-processed green phosphorescent organic light-emitting diodes(PhOLEDs)have been achieved.The high triplet energies of TBICz and TOXDCz ensure efficient energy transfer from the host to the phosphor and triplet exciton confinement on the phosphor.Solution-processable green phospho⁃rescent devices employing Ir(ppy)3 as guest and the two tetrasubstituted carbazole derivatives as hosts exhibit high ef⁃ficiencies.The best EL performance is achieved for the TBICz-based device,with a maximum current efficiency of 27.3 cd/A,a maximum power efficiency of 15.9 lm/W,and a maximum external quantum efficiency of 7.8%,which provides more host material options for solution-processed OLEDs.展开更多
To investigate the effect of rail pad viscoelasticity on vehicle-track-bridge coupled vibration,the fractional Voigt and Maxwell model in parallel(FVMP)was used to characterize the viscoelastic properties of the rail ...To investigate the effect of rail pad viscoelasticity on vehicle-track-bridge coupled vibration,the fractional Voigt and Maxwell model in parallel(FVMP)was used to characterize the viscoelastic properties of the rail pad based on dynamic performance test results.The FVMP model was then incorporated into the vehicle-track-bridge nonlinear coupled model,and its dynamic response was solved using a cross-iteration algorithm with a relaxation factor.Results indicate that the nonlinear coupled model achieves good convergence when the time step is less than 0.001 s,with the cross-iteration algorithm adjusting the wheel-rail force.In particular,the best convergence is achieved when the relaxation factor is within the range of 0.3-0.5.The FVMP model effectively characterizes the viscoelasticity of rail pads across a temperature range of±20℃and a frequency range of 1-1000 Hz.The viscoelasticity of rail pads significantly affects high-frequency vibrations in the coupled system,particularly around 50 Hz,corresponding to the wheel-rail coupled resonance range.Considering rail pad viscoelasticity is essential for accurately predicting track structure vibrations.展开更多
The mass spectrometric fragmentation of TMS derivatives of sterols was studied and analyzed based on the mass spectrometry of the TMS derivatives of standards.The double bond numbers and the degree of the methylize,al...The mass spectrometric fragmentation of TMS derivatives of sterols was studied and analyzed based on the mass spectrometry of the TMS derivatives of standards.The double bond numbers and the degree of the methylize,alkylize and the related position in the sterol nucleus and the side chains were confirmed by the characteristic ions.Total lipids were extracted using Bligh-Dyer method.Sterols were isolated by solvent partition with chloroform-hexane(1 ∶4,by volume),derivated by BSTFA,and analyzed by GC-MS.The regular pattern was used for identifying the sterols in a dinoflagellate from the Symbodinium sp.展开更多
汽车悬架控制系统是一个由较多非线性因素共同作用的复杂系统,针对传统PID控制效果不理想的问题,通过数值拟合的方式引入弹簧与阻尼等非线性影响因素,建立1/4汽车悬架非线性动力学模型,借鉴免疫反馈原理,结合积分控制的规律,提出一种模...汽车悬架控制系统是一个由较多非线性因素共同作用的复杂系统,针对传统PID控制效果不理想的问题,通过数值拟合的方式引入弹簧与阻尼等非线性影响因素,建立1/4汽车悬架非线性动力学模型,借鉴免疫反馈原理,结合积分控制的规律,提出一种模糊免疫PID(proportion integral derivative)控制方法,并利用免疫进化算法进行参数优化设计。仿真结果表明,该方法在汽车非线性悬架控制系统中可行且有效,其控制器性能也优于常规的PID控制器,具有更好的响应特性,同时也提高了汽车的操作稳定性和乘坐舒适性。展开更多
为提升船用汽轮发电机组大幅变工况时的控制精度和鲁棒性,以船用汽轮机调节系统各部件的模块化数学模型为基础,建立汽轮机组数字电液(digital electric hydraulic,DEH)闭环模糊比例、积分、微分(proportion integration derivative,PID...为提升船用汽轮发电机组大幅变工况时的控制精度和鲁棒性,以船用汽轮机调节系统各部件的模块化数学模型为基础,建立汽轮机组数字电液(digital electric hydraulic,DEH)闭环模糊比例、积分、微分(proportion integration derivative,PID)控制模型;融合遗传算法的选择、交叉、变异和自适应递减权重法,提出遗传粒子群智能优化算法,并结合标准测试函数验证提出算法具有较高的收敛速度和精度;基于遗传粒子群智能优化算法建立汽轮机变工况自适应智能模糊PID控制模型,实现模糊PID的量化因子与比例因子最优化设计,进而开展船用汽轮发电机组大幅变工况动态特性及扰动因素影响分析,结果表明本文建立的自适应智能模糊PID控制模型具有更好的控制稳态性能与鲁棒性,为船用汽轮机组大幅度变工况智能控制优化设计提供了有力的技术支撑。展开更多
To overcome the defects that the traditional ap-proach for multi-objective programming under uncertain ran-dom environment(URMOP)neglects the randomness and uncer-tainty of the problem and the volatility of the result...To overcome the defects that the traditional ap-proach for multi-objective programming under uncertain ran-dom environment(URMOP)neglects the randomness and uncer-tainty of the problem and the volatility of the results,a new ap-proach is proposed based on expected value-standard devi-ation value criterion(C_(ESD) criterion).Firstly,the effective solution to the URMOP problem is defined;then,by applying sequence relationship between the uncertain random variables,the UR-MOP problem is transformed into a single-objective program-ming(SOP)under uncertain random environment(URSOP),which are transformed into a deterministic counterpart based on the C_(ESD) criterion.Then the validity of the new approach is proved that the optimal solution to the SOP problem is also effi-cient for the URMOP problem;finally,a numerical example and a case application are presented to show the effectiveness of the new approach.展开更多
Two pairs of structural isomers isolated from Aconitum nagarum var.lasiandrum have been differentiated by ESI MS using hydroxylamine hydrochloride(NH2OH·HCl) derivative method.
To evaluate the performance of real time kinematic (RTK) network algorithms without applying actual measurements, a new method called geometric precision evaluation methodology (GPEM) based on covariance analysis was ...To evaluate the performance of real time kinematic (RTK) network algorithms without applying actual measurements, a new method called geometric precision evaluation methodology (GPEM) based on covariance analysis was presented. Three types of multiple reference station interpolation algorithms, including partial derivation algorithm (PDA), linear interpolation algorithms (LIA) and least squares condition (LSC) were discussed and analyzed. The geometric dilution of precision (GDOP) was defined to describe the influence of the network geometry on the interpolation precision, and the different GDOP expressions of above-mentioned algorithms were deduced. In order to compare geometric precision characteristics among different multiple reference station network algorithms, a simulation was conducted, and the GDOP contours of these algorithms were enumerated. Finally, to confirm the validation of GPEM, an experiment was conducted using data from Unite State Continuously Operating Reference Stations (US-CORS), and the precision performances were calculated according to the real test data and GPEM, respectively. The results show that GPEM generates very accurate estimation of the performance compared to the real data test.展开更多
基金the National Natural Science Foundation of China (60375001)the Scientific Research Foundation of Hunan Provincial Education Department (05B016).
文摘To determine the optimal or near optimal parameters of PID controller with incomplete derivation, a novel design method based on differential evolution （DE） algorithm is presented. The controller is called DE-PID controller. To overcome the disadvantages of the integral performance criteria in the frequency domain such as IAE, ISE, and ITSE, a new performance criterion in the time domain is proposed. The optimization procedures employing the DE algorithm to search the optimal or near optimal PID controller parameters of a control system are demonstrated in detail. Three typical control systems are chosen to test and evaluate the adaptation and robustness of the proposed DE-PID controller. The simulation results show that the proposed approach has superior features of easy implementation, stable convergence characteristic, and good computational efficiency. Compared with the ZN, GA, and ASA, the proposed design method is indeed more efficient and robust in improving the step response of a control system.
基金Project (50275150) supported by the National Natural Science Foundation of ChinaProject (RL200002) supported by the Foundation of the Robotics Laboratory, Chinese Academy of Sciences
文摘An optimal PID controller with incomplete derivation is proposed based on fuzzy inference and the geneticalgorithm, which is called the fuzzy-GA PID controller with incomplete derivation. It consists of the off-line part andthe on-line part. In the off-line part, by taking the overshoot, rise time, and settling time of system unit step re-sponse as the performance indexes and by using the genetic algorithm, a group of optimal PID parameters K*p , Ti* ,and Tj are obtained, which are used as the initial values for the on-line tuning of PID parameters. In the on-linepart, based on K; , Ti* , and T*d and according to the current system error e and its time derivative, a dedicatedprogram is written, which is used to optimize and adjust the PID parameters on line through a fuzzy inference mech-anism to ensure that the system response has optimal dynamic and steady-state performance. The controller has beenused to control the D. C. motor of the intelligent bionic artificial leg designed by the authors. The result of computersimulation shows that this kind of optimal PID controller has excellent control performance and robust performance.
文摘Pitch produced by the lique-faction of coal was divided into two frac-tions:soluble in toluene(TS)and insol-uble in toluene but soluble in pyridine(TI-PS),and their differences in molecu-lar structure and oxidation activity were studied.Several different carbon materi-als were produced from them by oxida-tion in air(350℃,300 mL/min)fol-lowed by carbonization(1000℃ in Ar),and the effect of the cross-linked structure on their structure and sodium storage properties was investigated.The results showed that the two pitch fractions were obviously different after the air oxidation.The TS fraction with a low degree of condensation and abundant side chains had a stronger oxidation activity and thus introduced more cross-linked oxygen-containing functional groups C(O)―O which prevented carbon layer rearrangement during the carbonization.As a result,a disordered hard carbon with more defects was formed,which improved the electrochemical performance.Therefore,the carbon materials derived from TS(O-TS-1000)had an obvious disordered structure and a larger layer spacing,giving them better sodium storage perform-ance than those derived from the TI-PS fraction(O-TI-PS-1000).The specific capacity of O-TS-1000 was about 250 mAh/g at 20 mA/g,which was 1.67 times higher than that of O-TI-PS-1000(150 mAh/g).
文摘Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1.5)Cl_(3)]·5H_(2)O}n(2)are framework isomers,which both contain zigzag chains formed by DPA,Zn^(2+),and Cl-.The zigzag chains in 1 are further assembled by C—H…Cl interactions into layers,and these layers exhibit two different orientations,displaying a rare 2D to 3D interpenetration mode.The zigzag chains in 2 are parallelly arranged.{[Zn_(3)(DPA)_(3)Br_(6)]·2DMF·_(1.5)H_(2)O}n(3)is isostructural to 2.3 was obtained using ZnBr_(2)instead of ZnCl_(2).[M(DPA)(formate)_(2)(H_(2)O)_(2)]n[M=Co(4),Cu(5)]are isostructural,contain chain structures formed by DPA,Cu^(2+)/Co^(2+),and for-mate ions,which were formed in situ in the solvothermal reaction.{[Zn(DIP)_(2)Cl]ClO_(4)}n(6)contains a layer structure formed by DIP and Zn^(2+).Free DPA and DIP ligands exhibited high fluorescence at room temperature,and coordina-tion polymers 3 and 6 displayed enhanced fluorescent emissions.
文摘We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),camphoric acid(H_(2)cpa)].In[Cd(dip)(cda)]·4H_(2)O}_(n)(1),the Cd^(2+)ions,acting as tetrahedral nodes,are linked by dipand cda^(2-)ligands with four Cd^(2+)ions into five-fold interpenetrating network array of topology of dia.In{[Cd(dip)(cpa)]·4H_(2)O}_(n)(2),the Cd^(2+)ions,acting as a 4-connector,are linked by cpa^(2-)and dip ligands into a 3D framework ofcds topology.In{[Ni(dia)_(2)Cl_(2)]·DMF}_(n)(3),the Ni^(2+)ion is linked by four dia ligands into a layer structure,and 1Dchannels of a cross-section of 1.35 nm×0.96 nm are formed.In{[Cd(dia)_(2)(H_(2)O)_(2)](NO_(3))_(2)·2DMSO}n(4),the dia ligandsconnected Cd^(2+)ions into a 2D layer,and 1D channels are formed between adjacent layers with a cross-section of0.87 nm×0.43 nm.In[Zn(dip)Cl_(2)]_(n)(5),the Zn^(2+)ion is linked by dip ligands into an infinite 1D chain.The infrared,thermal gravimetric,and fluorescent emission data were collected and analyzed for these coordination polymers.CCDC:2356055,1;2440075,2;2356057,3;2356057,4;2356059,5.
文摘The selective hydrogenation ofα,β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively reduce C=C or C=O bonds while preserving other functional groups within the molecule.This approach serves as a critical strategy for the directional synthesis of high-value molecules.However,achieving such selectivity remains challenging due to the thermodynamic equilibrium and kinetic competition between C=O and C=C bonds inα,β-unsaturated systems.Consequently,constructing precisely targeted catalytic systems is essential to overcome these limitations,offering both fundamental scientific significance and industrial application potential.Metal-organic frameworks(MOFs)and their derivatives have emerged as innovative platforms for designing such systems,owing to their programmable topology,tunable pore microenvironments,spatially controllable active sites,and modifiable electronic structures.This review systematically summarizes the research progress of MOF-based catalysts for selec-tive hydrogenation ofα,β-unsaturated aldehydes/ketones in the last decade,with emphasis on the design strategy,conformational relationship,and catalytic mechanism,aiming to provide new ideas for the design of targeted catalyt-ic systems for the selective hydrogenation ofα,β-unsaturated aldehydes/ketones.
文摘Two tetrasubstituted carbazole derivatives TBICz and TOXDCz have been designed and synthesized,which possess the twist skeletons and exhibit excellent thermal and morphological stabilities.Utilizing these novel compounds as host material,high efficiency solution-processed green phosphorescent organic light-emitting diodes(PhOLEDs)have been achieved.The high triplet energies of TBICz and TOXDCz ensure efficient energy transfer from the host to the phosphor and triplet exciton confinement on the phosphor.Solution-processable green phospho⁃rescent devices employing Ir(ppy)3 as guest and the two tetrasubstituted carbazole derivatives as hosts exhibit high ef⁃ficiencies.The best EL performance is achieved for the TBICz-based device,with a maximum current efficiency of 27.3 cd/A,a maximum power efficiency of 15.9 lm/W,and a maximum external quantum efficiency of 7.8%,which provides more host material options for solution-processed OLEDs.
基金Project(2023ZDZX0008)supported by the Sichuan Major Science and Technology Project,ChinaProject(52308468)supported by the National Natural Science Foundation of ChinaProject(2022JBQY009)supported by the Fundamental Research Funds for the Central Universities(Science and Technology Leading Talent Team Project),China。
文摘To investigate the effect of rail pad viscoelasticity on vehicle-track-bridge coupled vibration,the fractional Voigt and Maxwell model in parallel(FVMP)was used to characterize the viscoelastic properties of the rail pad based on dynamic performance test results.The FVMP model was then incorporated into the vehicle-track-bridge nonlinear coupled model,and its dynamic response was solved using a cross-iteration algorithm with a relaxation factor.Results indicate that the nonlinear coupled model achieves good convergence when the time step is less than 0.001 s,with the cross-iteration algorithm adjusting the wheel-rail force.In particular,the best convergence is achieved when the relaxation factor is within the range of 0.3-0.5.The FVMP model effectively characterizes the viscoelasticity of rail pads across a temperature range of±20℃and a frequency range of 1-1000 Hz.The viscoelasticity of rail pads significantly affects high-frequency vibrations in the coupled system,particularly around 50 Hz,corresponding to the wheel-rail coupled resonance range.Considering rail pad viscoelasticity is essential for accurately predicting track structure vibrations.
文摘The mass spectrometric fragmentation of TMS derivatives of sterols was studied and analyzed based on the mass spectrometry of the TMS derivatives of standards.The double bond numbers and the degree of the methylize,alkylize and the related position in the sterol nucleus and the side chains were confirmed by the characteristic ions.Total lipids were extracted using Bligh-Dyer method.Sterols were isolated by solvent partition with chloroform-hexane(1 ∶4,by volume),derivated by BSTFA,and analyzed by GC-MS.The regular pattern was used for identifying the sterols in a dinoflagellate from the Symbodinium sp.
文摘汽车悬架控制系统是一个由较多非线性因素共同作用的复杂系统,针对传统PID控制效果不理想的问题,通过数值拟合的方式引入弹簧与阻尼等非线性影响因素,建立1/4汽车悬架非线性动力学模型,借鉴免疫反馈原理,结合积分控制的规律,提出一种模糊免疫PID(proportion integral derivative)控制方法,并利用免疫进化算法进行参数优化设计。仿真结果表明,该方法在汽车非线性悬架控制系统中可行且有效,其控制器性能也优于常规的PID控制器,具有更好的响应特性,同时也提高了汽车的操作稳定性和乘坐舒适性。
文摘为提升船用汽轮发电机组大幅变工况时的控制精度和鲁棒性,以船用汽轮机调节系统各部件的模块化数学模型为基础,建立汽轮机组数字电液(digital electric hydraulic,DEH)闭环模糊比例、积分、微分(proportion integration derivative,PID)控制模型;融合遗传算法的选择、交叉、变异和自适应递减权重法,提出遗传粒子群智能优化算法,并结合标准测试函数验证提出算法具有较高的收敛速度和精度;基于遗传粒子群智能优化算法建立汽轮机变工况自适应智能模糊PID控制模型,实现模糊PID的量化因子与比例因子最优化设计,进而开展船用汽轮发电机组大幅变工况动态特性及扰动因素影响分析,结果表明本文建立的自适应智能模糊PID控制模型具有更好的控制稳态性能与鲁棒性,为船用汽轮机组大幅度变工况智能控制优化设计提供了有力的技术支撑。
基金supported by the National Natural Science Foundation of China(72001213)the basic research program of Natural Science of Shaanxi Province,China(2021JQ-369).
文摘To overcome the defects that the traditional ap-proach for multi-objective programming under uncertain ran-dom environment(URMOP)neglects the randomness and uncer-tainty of the problem and the volatility of the results,a new ap-proach is proposed based on expected value-standard devi-ation value criterion(C_(ESD) criterion).Firstly,the effective solution to the URMOP problem is defined;then,by applying sequence relationship between the uncertain random variables,the UR-MOP problem is transformed into a single-objective program-ming(SOP)under uncertain random environment(URSOP),which are transformed into a deterministic counterpart based on the C_(ESD) criterion.Then the validity of the new approach is proved that the optimal solution to the SOP problem is also effi-cient for the URMOP problem;finally,a numerical example and a case application are presented to show the effectiveness of the new approach.
文摘Two pairs of structural isomers isolated from Aconitum nagarum var.lasiandrum have been differentiated by ESI MS using hydroxylamine hydrochloride(NH2OH·HCl) derivative method.
基金Project(61273055) supported by the National Natural Science Foundation of ChinaProject(CX2010B012) supported by Hunan Provincial Innovation Foundation for Postgraduate Students, ChinaProject(B100302) supported by Innovation Foundation for Postgraduate Students of National University of Defense Technology, China
文摘To evaluate the performance of real time kinematic (RTK) network algorithms without applying actual measurements, a new method called geometric precision evaluation methodology (GPEM) based on covariance analysis was presented. Three types of multiple reference station interpolation algorithms, including partial derivation algorithm (PDA), linear interpolation algorithms (LIA) and least squares condition (LSC) were discussed and analyzed. The geometric dilution of precision (GDOP) was defined to describe the influence of the network geometry on the interpolation precision, and the different GDOP expressions of above-mentioned algorithms were deduced. In order to compare geometric precision characteristics among different multiple reference station network algorithms, a simulation was conducted, and the GDOP contours of these algorithms were enumerated. Finally, to confirm the validation of GPEM, an experiment was conducted using data from Unite State Continuously Operating Reference Stations (US-CORS), and the precision performances were calculated according to the real test data and GPEM, respectively. The results show that GPEM generates very accurate estimation of the performance compared to the real data test.
