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Phase Transfer Catalyzed Method to Prepare Symmetrical Azobenzenes from Anilines
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《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 1999年第S1期325-325,共1页
关键词 Phase Transfer Catalyzed Method to prepare Symmetrical Azobenzenes from Anilines
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Preparation and Modification of MXene Composites for Application in Electrochemical Energy Storage
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作者 Zhang-Hai You Ding-Ze Lu +5 位作者 Kiran Kumar Kondamareddy Wen-Ju Gu Peng-Fei Cheng Jing-Xuan Yang Rui Zheng Hong-Mei Wang 《电化学(中英文)》 北大核心 2025年第5期1-27,共27页
With the acceleration of advanced industrialization and urbanization,the environment is deteriorating rapidly,and non-renewable energy resources are depleted.The gradual advent of potential clean energy storage techno... With the acceleration of advanced industrialization and urbanization,the environment is deteriorating rapidly,and non-renewable energy resources are depleted.The gradual advent of potential clean energy storage technologies is particularly urgent.Electrochemical energy storage technologies have been widely used in multiple fields,especially supercapacitors and rechargeable batteries,as vital elements of storing renewable energy.In recent years,two-dimensional material MXene has shown great potential in energy and multiple application fields thanks to its excellent electrical properties,large specific surface area,and tunability.Based on the layered materials of MXene,researchers have successfully achieved the dual functions of energy storage and conversion by adjusting the surface terminals at the Fermi level.It is worth noting that compared with other two-dimensional materials,MXene has more active sites on the basal plane,showing excellent catalytic performance.In contrast,other two-dimensional materials have catalytic activity only at the edge sites.This article comprehensively overviews the synthesis process,structural characteristics,modification methods for MXene-based polymer materials,and their applications in electrochemical energy storage.It also briefly discusses the potential of MXene-polymer materials in electromagnetic shielding technology and sensors and looks forward to future research directions. 展开更多
关键词 MXene Preparation process Modification strategy Electrochemical energy storage
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A Retrospective Cohort Study on the Improvement of Prognosis of Hospitalized COVID-19 Patients Using Traditional Chinese Medicine Preparations
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作者 DOU Li WANG Wei +9 位作者 YU Manshu YUAN Sicheng HU Jingyi ZHUANG Yuwen QI Minghao WANG Yuanyuan YANG Fei MENG Jiale GUO Tao WANG Xiaoxiao 《南京中医药大学学报》 北大核心 2025年第11期1585-1595,共11页
OBJECTIVE The emergence of evolving variants of Coronavirus disease 2019(COVID-19)has fostered the need for change of newer and adaptive treatments for these infections.During the COVID-19 pandemic and persists,tradit... OBJECTIVE The emergence of evolving variants of Coronavirus disease 2019(COVID-19)has fostered the need for change of newer and adaptive treatments for these infections.During the COVID-19 pandemic and persists,traditional Chinese medicine(TCM)herbs exhibit significant bioactivity and therapeutic effect.This study is aimed to evaluate the efficacy of four TCM preparations on 28-day mortality risk of patients and changes of the laboratory indicators.METHODS The retrospective cohort study included patients with COVID-19 who were admitted to the Jiangsu Province Hospital of Chinese Medicine from December 15,2022 to January 15,2023,and those died within 48 hours of admission or cannot be tracked for outcomes were excluded.The primary outcome was survival status in 28 days(death or survival)starting from the day of admission.The second outcomes were laboratory indicators,including absolute lymphocyte count,lactate dehydrogenase,creatinine,and blood urea nitrogen.Binary logistic regressions were used to estimate the effect of TCM preparations on the primary and secondary outcomes in main analysis.Meanwhile,heterogeneity and robustness of results from main analysis were assessed by subgroup analyses and multiple sensitivity analyses.RESULTS 1816 eligible patients were included in analysis dataset,including 573 patients received standard care(control group)and 1243 patients received TCM preparations(hospital preparation group).The 28-day mortality rate of hospital preparation group was lower than that of control group(4.75%vs.14.83%),and the difference was statistically significant(χ^(2)=54.666,P<0.001).The risk of 28-day mortality was 0.535 times lower in the hospital preparation group as compared with the control group(OR=0.46,95%CI:0.305-0.708,P<0.001)showed by multivariable binary logistic regressions.Subgroup analyses showed that taking TCM preparations reduced the 28-day mortality risk.Sensitivity analyses demonstrated that the results of the main analysis for primary outcomes were robust.For secondary outcomes,the risk of abnormal absolute lymphocyte counts at discharge in the hospital preparation group decreased by 0.284 times(OR=0.703,95%CI:0.515-0.961,P=0.027).CONCLUSION Compared with standard of care,taking four hospital preparations including Kanggan Heji,Feining Heji,Qishen Gubiao Keli,and Qianghuo Qushi Qingwen Heji decreased risk of 28-day mortality among hospitalized COVID-19 patients.TCM therapy achieves adequate therapeutic effects in COVID-19. 展开更多
关键词 traditional Chinese medicine preparations COVID-19 28-day mortality retrospective cohort study
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A review of petroleum asphalt-based carbon materials in electrochemical energy storage 被引量:3
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作者 DU Shao-xiong KONG Ling-yu +6 位作者 LIU Lu CAO Zi-yang WU Xi SUN Bo LI Zheng-xuan YANG Wang LI Yong-feng 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第6期1088-1107,共20页
Petroleum asphalt,an important by-product of the petrochemical industry,has diverse applications but often suffers from low industrial added value.Because of its low cost,high carbon content,and high polycyclic aromat... Petroleum asphalt,an important by-product of the petrochemical industry,has diverse applications but often suffers from low industrial added value.Because of its low cost,high carbon content,and high polycyclic aromatic hydrocarbon content,appropriate modification can increase its value and expand its energy storage applications.Current research progress on the common preparation methods of petroleum asphalt-based carbon materials,including template-assisted pyrolysis,molten salt treatment,activation,heteroatom doping,and pre-oxidation is reviewed,and its use in supercapacitors and alkali metal ion batteries,is also elaborated.Feasible solutions for the current problems with petroleum asphalt are proposed,with the aim of providing insights into its high value-added utilization. 展开更多
关键词 Petroleum asphalt Carbon materials PREPARATION ELECTROCHEMISTRY Energy storage
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Low-cost synthesis of high-purity Li_(2)S for sulfide solid state electrolytes enabled by polyvinyl alcohol 被引量:3
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作者 WU Zhuang-zhi HAN Cheng +3 位作者 WANG Jia-sen LI Xue-bao FEI Hao WANG De-zhi 《Journal of Central South University》 CSCD 2024年第12期4449-4459,共11页
Sulfide solid electrolytes(S-SEs)are widely preferred for their high ionic conductivity and processability.However,the further development of S-SEs is hindered by the excessive price of its critical raw materials of L... Sulfide solid electrolytes(S-SEs)are widely preferred for their high ionic conductivity and processability.However,the further development of S-SEs is hindered by the excessive price of its critical raw materials of Li_(2)S.Herein,a low-cost and environmentally friendly method is proposed to synthesize Li_(2)S by the carbothermal reduction reaction of Li_(2)SO_(4)in one step,and the effects of various factors are also discussed.As a result,a purity of 99.67%is obtained over the self-prepared Li_(2)S.More importantly,the cost of the self-prepared Li_(2)S is only about 50$/kg,which is significantly lower than that of the commercial counterpart(10000−15000 dollar/kg).Moreover,the ionic conductivity of Li_(5.5)PS_(4.5)Cl_(1.5)prepared using self-prepared Li_(2)S as raw materials is 4.19 mS/cm at room temperature,which is a little higher than that of Li_(5.5)PS_(4.5)Cl_(1.5)using commercial Li_(2)S(4.05 mS/cm).And the all-solid-state lithium batteries(ASSLBs)with the as-prepared electrolytes could maintain a discharge capacity of 109.9 mA·h/g with an average coulombic efficiency(CE)of 98%after 100 cycles at 0.2 C,which is equivalent to that using commercial Li_(2)S,demonstrating that the preparation strategy of Li_(2)S proposed in this work is feasible. 展开更多
关键词 lithium sulfide one-step preparation sulfide solid-state electrolytes all-solid-state lithium battery carbothermal reduction low-cost preparation
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Microfluidic preparation of surfactant-free ultrafine DAAF with tunable particle size for insensitive initiator explosives 被引量:1
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作者 Bo Yang Rui Li +9 位作者 Wei Cao Si-min He Jincan Zhu Qi Wu Heng Ding Jin Chen Weimiao Wang Zhiqiang Qiao Xiaodong Li Guangcheng Yang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期42-52,共11页
High purity and ultrafine DAAF(u-DAAF)is an emerging insensitive charge in initiators.Although there are many ways to obtain u-DAAF,developing a preparation method with stable operation,accurate control,good quality c... High purity and ultrafine DAAF(u-DAAF)is an emerging insensitive charge in initiators.Although there are many ways to obtain u-DAAF,developing a preparation method with stable operation,accurate control,good quality consistency,equipment miniaturization,and minimum manpower is an inevitable requirement to adapt to the current social technology development trend.Here reported is the microfluidic preparation of u-DAAF with tunable particle size by a passive swirling microreactor.Under the guidance of recrystallization growth kinetics and mixing behavior of fluids in the swirling microreactor,the key parameters(liquid flow rate,explosive concentration and crystallization temperature)were screened and optimized through screening experiments.Under the condition that no surfactant is added and only experimental parameters are controlled,the particle size of recrystallized DAAF can be adjusted from 98 nm to 785 nm,and the corresponding specific surface area is 8.45 m^(2)·g^(-1)to 1.33 m^(2)·g^(-1).In addition,the preparation method has good batch stability,high yield(90.8%-92.6%)and high purity(99.0%-99.4%),indicating a high practical application potential.Electric explosion derived flyer initiation tests demonstrate that the u-DAAF shows an initiation sensitivity much lower than that of the raw DAAF,and comparable to that of the refined DAAF by conventional spraying crystallization method.This study provides an efficient method to fabricate u-DAAF with narrow particle size distribution and high reproducibility as well as a theoretical reference for fabrication of other ultrafine explosives. 展开更多
关键词 Microfluidic preparation Screening crystallization conditions Narrow particle size distribution Low initiation sensitivity Ultrafine DAAF
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The preparation and properties of N-doped carbon materials and their use for sodium storage
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作者 YUAN Ren-lu HOU Ruo-yang +4 位作者 SHANG Lei LIU Xue-wei LI Ang CHEN Xiao-hong SONG Huai-he 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第5期770-795,共26页
Defect engineering by heteroatom doping gives carbon materials some new characteristics such as a different electronic structure and a high electrochemical activity,making them suitable for high-performance applicatio... Defect engineering by heteroatom doping gives carbon materials some new characteristics such as a different electronic structure and a high electrochemical activity,making them suitable for high-performance applications.N-doping has been widely investigated because of its similar atom radius to carbon,high electronegativity as well as many different configurations.We summarize the preparation methods and properties of N-doped carbon materials,and discuss their possible use in sodium ion storage.The relationships between N content/configuration and crystallinity,electronic conductivity,wettability,chemical reactivity as well as sodium ion storage performance are discussed. 展开更多
关键词 N-doped carbon material N configuration Preparation method Performance Sodium storage
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On-site preparation of one-dimensional C_(60) polymer crystals
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作者 Xia Wang Fei Pan Yanwu Zhu 《中国科学技术大学学报》 CAS CSCD 北大核心 2024年第9期2-6,32,68,共7页
The preparation of large crystals is highly important for the characterization and application of a newly found structure but remains a challenge for one-dimensional(1D)C_(60) polymers.In this work,we successfully fab... The preparation of large crystals is highly important for the characterization and application of a newly found structure but remains a challenge for one-dimensional(1D)C_(60) polymers.In this work,we successfully fabricated a 1D C_(60) polymer crystal via on-site annealing of a millimeter-sized C_(60) molecular crystal withα-Li_(3)N at 500°C and ambient pres�sure.Characterizations show that the C_(60) cages in the crystal have been efficiently connected,forming 1D chains along the<110>direction in an orthorhombic 3D structure.At the same time,the crystal maintains a morphology similar to that of the pristine C_(60)crystal,providing opportunities for characterization of all the facets of the crystal via Raman spectroscopy and thus suggesting the formation mechanism of such crystals. 展开更多
关键词 fullerene C_(60) molecular crystal on-site preparation 1D C_(60) polymer crystal covalent connection
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Effects of Silicon Preparation on Root Physiological Activity of Rice Under Cadmium Stress
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作者 Ren Hongyu Wu Jianan +4 位作者 Wang Wenbo Li Shuai Wen Yahuan Lin Zixin Zhang Xingwen 《Journal of Northeast Agricultural University(English Edition)》 CAS 2024年第4期54-65,共12页
The rice Dongfu 159 was used for the potting experiment to simulate soil cadmium(Cd)stress,and four silicon preparations,Si-50-G and Si-60-G at a concentration of 0.20%and Si-T-G and Si-E-G at a concentration of 0.50%... The rice Dongfu 159 was used for the potting experiment to simulate soil cadmium(Cd)stress,and four silicon preparations,Si-50-G and Si-60-G at a concentration of 0.20%and Si-T-G and Si-E-G at a concentration of 0.50%,were applied at the tillering stage and booting stage of rice,respectively.The cadmium content,root vitality,root malondialdehyde(MDA)content,and antioxidant enzyme activity of each part of rice plants were determined,in order to provide a theoretical reference for exploring the mechanism of silicon fertilizer on the mitigation of Cd-stressed plants.The results showed that under the condition of cadmium stress,silicon application could significantly increase the root vitality and antioxidant enzyme activity,reduce the content of MDA,and reduce the accumulation of cadmium in various parts of rice.The treatment of Si-T-G applied at the tillering stage was the most effective in increasing the root vitality of rice,which was significantly increased by 63.00%compared with the CK.The treatment of Si-50-G applied at the stage of booting was the most effective in reducing MDA content of rice roots,which was significantly reduced by 30.16%compared with the CK.The treatment of Si-60-G applied at the stage of booting was the most effective in increasing the root superoxide dismutase(SOD)activity,which was significantly increased by 39.36%compared with the CK.The treatment of Si-60-G applied at the tillering stage was the most effective in increasing the root peroxidase(POD)and catalase(CAT)activities,which were significantly increased by 64.66%and 51.52%,respectively,compared with the CK.The treatment of Si-T-G applied at the tillering stage was the most effective in reducing Cd content of rice roots,stems and grains,which were significantly reduced by 39.53%,61.19%and 43.41%,respectively,compared with the CK,and the treatment of Si-60-G was the most effective in reducing Cd content of leaves,which was significantly reduced by 53.40%compared with the CK. 展开更多
关键词 cadmium stress RICE silicon preparation root physiological activity
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具有模糊校正的GPC在NCS中的应用
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作者 胡丹 《科学技术与工程》 2009年第11期3124-3126,共3页
针对网络的引进而产生的时延及系统的不确定性问题,在GPC控制算法的基础上通过加入模糊校正的方法更好的解决了网络控制系统中系统模型失配和噪声干扰等对系统控制效果的影响,仿真结果验证了控制器设计方法的有效性。
关键词 网络控制系统 广义预测控制(General prepareD Control GPC) 模糊校正
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氧化银沉淀-离子色谱法测定海水中的痕量亚硝酸根和硝酸根 被引量:18
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作者 傅厚暾 赵俐敏 +2 位作者 李贝 罗曼 王家家 《色谱》 CAS CSCD 北大核心 2007年第1期120-120,共1页
关键词 离子色谱(IC) 海水(seawater) 亚硝酸根(NO2^-) 硝酸根(NO3^-) 样品前处理(sample preparation)
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固相微萃取-气相色谱法测定醒脑静注射剂中的麝香酮 被引量:12
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作者 魏宁漪 马长华 段天璇 《色谱》 CAS CSCD 北大核心 2005年第5期565-565,共1页
关键词 固相微萃取(solid phase microextraction) 气相色谱法(gas chromatography) 麝香酮(muscone) 中药制剂(Chinese herba preparation)
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从当代美、日两国体育院系发展看我国体育专业教育改革 被引量:12
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作者 张建华 周之华 《体育学刊》 CAS 1999年第3期57-63,共7页
Similaritics and differences of current reforms of Professional Preperaration Of Physical Education in the U. S. A and Japan are pointed out through a comprehensive analysis and comparative study on current situation ... Similaritics and differences of current reforms of Professional Preperaration Of Physical Education in the U. S. A and Japan are pointed out through a comprehensive analysis and comparative study on current situation of the reforms and their backgrounds in this paper. Also, constructive suggests are Put forward here for the reform of professional preparation in physical education taking place in China. 展开更多
关键词 Professional Preparation of PHYSICAL EDUCATION school(or department) of PHYSICAL EDUCATION and SPORT major REFORM
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GC-MS测定中的小体积样品浓缩技术 被引量:1
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作者 王立 齐刚 +3 位作者 王尚军 刘鸿雁 张玉玲 刘晓华 《分析测试学报》 CAS CSCD 北大核心 2007年第z1期138-139,共2页
New preparation methods for the GC-MS analytical sample are reviewed in this paper.There are MT,SH-MT,PMT,ME-MT,MCT,and so on mainly.
关键词 REVIEW GC-MS Sample preparation MicroTrap
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气相色谱-质谱分析气体样品的制备方法和技术 被引量:4
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作者 王立 齐刚 焦海一 《分析测试学报》 CAS CSCD 北大核心 2004年第z1期146-147,共2页
  现代GC-MS仪器虽然具有较高的分辨能力和较高的灵敏度,但是对欲分析样品的要求也比较严格.诸如:进样量大小、组成组分的浓度范围、样品的物理状况、样品中的基体干扰等问题都是必须在进样之前调查清楚,才能选择正确的样品处理方法...   现代GC-MS仪器虽然具有较高的分辨能力和较高的灵敏度,但是对欲分析样品的要求也比较严格.诸如:进样量大小、组成组分的浓度范围、样品的物理状况、样品中的基体干扰等问题都是必须在进样之前调查清楚,才能选择正确的样品处理方法和技术并处理成GC-MS仪器能够直接进样测定的样品形式,获得正确的GC-MS分析测定结果.…… 展开更多
关键词 GC - MS Sample preparation Gas and vapor
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香蕉粉制备新工艺研究 被引量:2
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作者 付调坤 周瑶敏 +2 位作者 唐永富 方蕾 李积华 《江西农业学报》 CAS 2010年第12期110-112,116,共4页
介绍了一种高品质香蕉粉制备新工艺.将成熟香蕉清洗后于-1~2 ℃下冷藏至果肉温度不高于2 ℃,快速去皮后放入果肉重量1.0倍的有少量冰渣的冰冻水中,快速打浆,并将冷浆料泵入压力为0.1 MPa、进风温度为175 ℃的喷雾干燥塔中干燥,即可得... 介绍了一种高品质香蕉粉制备新工艺.将成熟香蕉清洗后于-1~2 ℃下冷藏至果肉温度不高于2 ℃,快速去皮后放入果肉重量1.0倍的有少量冰渣的冰冻水中,快速打浆,并将冷浆料泵入压力为0.1 MPa、进风温度为175 ℃的喷雾干燥塔中干燥,即可得到纯全香蕉粉.该工艺制备的香蕉粉保留了果肉原有色泽和风味,且可实现连续化生产,生产效率高. 展开更多
关键词 香蕉粉 制备新工艺 新工艺研究 Preparation Process New 果肉 喷雾干燥塔 连续化生产 进风温度 生产效率 工艺制备 冷浆料 高品质 重量 压力 色泽 去皮 清洗 冷藏 风味
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谈谈与examination搭配的词语
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作者 程红梅 《中小学英语教学与研究》 北大核心 2022年第5期76-78,共3页
本文结合相关辞书,概述与examination相关的表达。1.用prepare/revise/studyfor等表示“为考试而准备”“复习迎考”“温习备考”。例如:We are preparing for the examination next week.我们正在为下周的考试做准备。I do not have mu... 本文结合相关辞书,概述与examination相关的表达。1.用prepare/revise/studyfor等表示“为考试而准备”“复习迎考”“温习备考”。例如:We are preparing for the examination next week.我们正在为下周的考试做准备。I do not have much time to revise for examinations.我没有很多时间复习迎考。Ineed time to study for tomorrow's exami nation.我需要时间学习,准备明天的考试。 展开更多
关键词 PREPARING EXAMINATION 复习迎考
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Preparation and mechanical properties of polypropylene fiber reinforced calcined kaolin-fly ash based geopolymer 被引量:10
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作者 张祖华 姚晓 +2 位作者 诸华军 华苏东 陈悦 《Journal of Central South University》 SCIE EI CAS 2009年第1期49-52,共4页
To improve the environmental benefits and solve the problems of large shrinkage and high brittleness, the partial replacement of calcined kaolin by fly ash as a raw material for geopolymer synthesis and the influences... To improve the environmental benefits and solve the problems of large shrinkage and high brittleness, the partial replacement of calcined kaolin by fly ash as a raw material for geopolymer synthesis and the influences of polypropylene (PP) fiber on the mechanical properties and volume stability were investigated. The results show that compressive strength of the geopolymer containing 33.3%(mass fraction) fly ash by steam curing at 80 ℃ for 6 d is improved by 35.5%. The 3-day compressive strength, flexural strength and impacting energy of geopolymers containing 0.05%PP fiber increase by 67.8%, 36.1% and 6.25%, while the shrinkage and modulus of compressibility decrease by 38.6% and 31.3%, respectively. The results of scanning electron microscopy (SEM) and the appearances of crack growths confirm that PP fiber can offer a bridging effect over the harmful pores and defects and change the expanding ways of cracks, resulting in a great improvement of strength and toughness. 展开更多
关键词 polypropylene fiber calcined kaolin fly ash GEOPOLYMER PREPARATION mechanical properties
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Gold Characterization by MLA and Technological Tests-Discussion of Sample Preparation and Results 被引量:5
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作者 Carina Ulsen Henrique Kahn +2 位作者 Guilherme Nery Daniel Uliana Juliana L.Antoniassi 《矿物学报》 CAS CSCD 北大核心 2013年第S1期10-10,共1页
Gold has been present throughout the history of mankind and used to make jewelry and coins, and recently, acquired several industrial uses. The price of gold in international market had a significant increasing, surpa... Gold has been present throughout the history of mankind and used to make jewelry and coins, and recently, acquired several industrial uses. The price of gold in international market had a significant increasing, surpassing 100% in the last five years. Thereby, deposits with low levels of gold content, gold with complex associations or in a very fine particle size became exploitable again, allowing new projects and expansion of existing ones. However, for maximum process efficiency is indispensable a deep knowledge of the characteristics of these minerals and their behavior in face of beneficiation processes. Consequently, an accurate routine for mineralogical and technological characterization is essential. 展开更多
关键词 GOLD CHARACTERIZATION IMAGE analysis SAMPLE preparation
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Effect of heat treatment of Mn-Cu precursors on morphology of dealloyed nanoporous copper 被引量:3
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作者 TAN Xiu-lan LI Kai +6 位作者 NIU Gao YI zao LUO Jiang-shan LIU Ying HAN shan-jun WU Wei-dong TANG Yong-jian 《Journal of Central South University》 SCIE EI CAS 2012年第1期17-21,共5页
Nanoporous copper with nano-scale pore size was synthesized by dealloying Mn-Cu precursor alloy using a free corrosion method. The effects of heat treatment of Mn-Cu precursors on alloy phase, morphology and compositi... Nanoporous copper with nano-scale pore size was synthesized by dealloying Mn-Cu precursor alloy using a free corrosion method. The effects of heat treatment of Mn-Cu precursors on alloy phase, morphology and composition of the resultant nanoporous copper were investigated. It is revealed that the compositions distribute homogeneously in the bulk Mn-Cu precursors, which consequently results in a more fully dealloying for forming nanoporous copper. The alloy phase changes from Cuo.a9Mno.51 and Cuo.21Mno.79 of non-thermally treated precursor to Cuo.33Mn0.67 of heat treated alloy. The residual Mn content in nanoporous copper is decreased from 12.97% to 2.04% (molar fraction) made from the precursor without and with 95 h heat treatment. The typical pore shape of nanoporous copper prepared by dealloying the precursor without the heat treatment is divided into two different zones: the uniform bi-continuous structure zone and the blurry or no pore structure zone. Nanoporous copper is of a uniform sponge-like morphology made from the heat-treated precursor, and the average ligament diameter is 40 nm, far smaller than that from the non-thermally treated precursor, in which the average ligament diameter is estimated to be about 70 nm. 展开更多
关键词 nanoporous copper PREPARATION DEALLOYING heat treatment MORPHOLOGY
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