针对在室温环境下探测瓦斯浓度,提出一种基于钯掺杂单壁碳纳米管(Pd-SWCNTs)的超宽带射频识别(UWB-RFID)传感器。传感器为薄型标签,由传感探头和电磁界面组成,其中传感探头为一PdSWCNTs加载的交叉指型电极(IDE);电磁界面由天线、微带线...针对在室温环境下探测瓦斯浓度,提出一种基于钯掺杂单壁碳纳米管(Pd-SWCNTs)的超宽带射频识别(UWB-RFID)传感器。传感器为薄型标签,由传感探头和电磁界面组成,其中传感探头为一PdSWCNTs加载的交叉指型电极(IDE);电磁界面由天线、微带线和终端负载组成。Pd-SWCNTs感知瓦斯浓度,引起IDE电流的变化,形成带隙幅度调制和带隙频率调制两种识别模式。当瓦斯浓度从0×10-6增加到100×10-6,基于带隙调幅调制的识别灵敏度为-9.32 d B;而基于带隙调频调制的识别灵敏度为-11.30 d B。展开更多
Over 400 researchers from 31 countries attended Carbon 2004, an international Carbon conference, held in Providence, Rhode Island, USA, from July 11-16, 2004. About 494 presentations (287 oral, 207 posters) at this co...Over 400 researchers from 31 countries attended Carbon 2004, an international Carbon conference, held in Providence, Rhode Island, USA, from July 11-16, 2004. About 494 presentations (287 oral, 207 posters) at this conference covered the following 13 areas: Adsorption and gas storage, Biological and medical application, Carbon nanomaterials, Chars/cokes and industrial applications, Electronic/Electrochemical properties and applications, Flame formed carbons, Materials characterization/techniques, Membranes/pyrocarbons and diamond films, Novel forms and chemically modified carbons, Porous carbons/activations, Precursor chemistry/carbonization and graphitization, Reactivity/catalysis and surface science, Structural carbons/fibers and composites. Carbon nanomaterials and nanostructure were highlighted at this conference, 12 of all 48 oral sessions and 112 of all 494 papers being on this topic. A pre-(conference) workshop, A Colloquium on Carbon Nanoforms, and three of the four plenary lectures reported the latest (development) and showed us the current trends in research on Carbon nanomaterials. At this conference, the idea was emphasized that the "nano" concept now not only represents some kinds of materials and structure, but also, much more important, brings us a new insight to carbon materials, novel or conventional. Carbon scientists firmly believe that they are trying to create the "golden age" of Carbon materials.Blood coagulation resistance of nonwoven single-walled carbon nanotubes and its implications for implantable prosthesesMENG Jie^1,SONG Li^2,KONG Hua^1,WANG Chao-ying^2,GUO Xiao-tian^1,XU Hai-yan^1,XIE Si-shen^2(1. Institute of Basic Medicine, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing100005, China;2. Institute of Physics, Chinese Academy of Science, Beijing100080, China)Abstract:The anticoagulation property of a SWNT membrane is investigated in blood-contacting environments. The adsorption behaviors of fibrinogen, albumin and fresh plasma on SWNT membrane were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray analysis. The platelet adhesion and activation induced by the SWNT membrane were evaluated through SEM observations and fluorescent labeled flow cytometric analysis. Results indicated that the SWNT membrane showed a clear adsorption preference of fibrinogen over albumin. However, there was no appreciable platelet adhesion and activation occurred consequently on a SWNT membrane surface pre-absorbed with fresh plasma, and the percentage of activated platelets caused by a SWNT membrane in a platelet-rich-plasma was about 5?%. The conclusion is that the SWNT membrane has unique platelet inertness in blood environments and this anticoagulant effect permits potential use in artificial organs, prostheses and tissue engineering in the cardiac-vascular systems.展开更多
Single wall carbon nanotube (SWNT) was prepared by d.c. arc discharge method and purified by filtration method. After refluxed in HNO 3, the ends of SWNT were opened and oxidized into carboxylate group, which may reac...Single wall carbon nanotube (SWNT) was prepared by d.c. arc discharge method and purified by filtration method. After refluxed in HNO 3, the ends of SWNT were opened and oxidized into carboxylate group, which may react with other reagents. For chemical modification of SWNT, the carboxyl terminated SWNT reacted with CH 3(CH 2) 15 NH 2 with the aid of the condensation agent DCC to obtain the derivatives of SWNT with the amido alkyl chain which enhanced the solubility of SWNT in organic solvent. The results of micro IR prove the formation of amido group in SWNT sample(\{ (CO)=\}1 647 cm -1 ). The FT Raman results show that SWNT sample preserve its structure after the condensation reaction( ω r=181 cm -1 ). [WT5HZ]展开更多
The electrochemical behavior of the film of single wall carbon nanotube(SWNT) functionalized with carboxylic acid group was studied extensively at the glassy carbon(GC) electrode. One stable couple of waves correspond...The electrochemical behavior of the film of single wall carbon nanotube(SWNT) functionalized with carboxylic acid group was studied extensively at the glassy carbon(GC) electrode. One stable couple of waves corresponding to the redox of the carboxylic acid group, which was supported by the IR experiments, was observed. The electrode process involved four electrons, while the rate determining step was a one-electron reduction. The SWNT film modified electrode showed nice electrocatalytic behaviors toward the oxidations of some biomolecules such as dopamine, epinephrine and ascorbic acid.展开更多
文摘针对在室温环境下探测瓦斯浓度,提出一种基于钯掺杂单壁碳纳米管(Pd-SWCNTs)的超宽带射频识别(UWB-RFID)传感器。传感器为薄型标签,由传感探头和电磁界面组成,其中传感探头为一PdSWCNTs加载的交叉指型电极(IDE);电磁界面由天线、微带线和终端负载组成。Pd-SWCNTs感知瓦斯浓度,引起IDE电流的变化,形成带隙幅度调制和带隙频率调制两种识别模式。当瓦斯浓度从0×10-6增加到100×10-6,基于带隙调幅调制的识别灵敏度为-9.32 d B;而基于带隙调频调制的识别灵敏度为-11.30 d B。
文摘Over 400 researchers from 31 countries attended Carbon 2004, an international Carbon conference, held in Providence, Rhode Island, USA, from July 11-16, 2004. About 494 presentations (287 oral, 207 posters) at this conference covered the following 13 areas: Adsorption and gas storage, Biological and medical application, Carbon nanomaterials, Chars/cokes and industrial applications, Electronic/Electrochemical properties and applications, Flame formed carbons, Materials characterization/techniques, Membranes/pyrocarbons and diamond films, Novel forms and chemically modified carbons, Porous carbons/activations, Precursor chemistry/carbonization and graphitization, Reactivity/catalysis and surface science, Structural carbons/fibers and composites. Carbon nanomaterials and nanostructure were highlighted at this conference, 12 of all 48 oral sessions and 112 of all 494 papers being on this topic. A pre-(conference) workshop, A Colloquium on Carbon Nanoforms, and three of the four plenary lectures reported the latest (development) and showed us the current trends in research on Carbon nanomaterials. At this conference, the idea was emphasized that the "nano" concept now not only represents some kinds of materials and structure, but also, much more important, brings us a new insight to carbon materials, novel or conventional. Carbon scientists firmly believe that they are trying to create the "golden age" of Carbon materials.Blood coagulation resistance of nonwoven single-walled carbon nanotubes and its implications for implantable prosthesesMENG Jie^1,SONG Li^2,KONG Hua^1,WANG Chao-ying^2,GUO Xiao-tian^1,XU Hai-yan^1,XIE Si-shen^2(1. Institute of Basic Medicine, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing100005, China;2. Institute of Physics, Chinese Academy of Science, Beijing100080, China)Abstract:The anticoagulation property of a SWNT membrane is investigated in blood-contacting environments. The adsorption behaviors of fibrinogen, albumin and fresh plasma on SWNT membrane were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray analysis. The platelet adhesion and activation induced by the SWNT membrane were evaluated through SEM observations and fluorescent labeled flow cytometric analysis. Results indicated that the SWNT membrane showed a clear adsorption preference of fibrinogen over albumin. However, there was no appreciable platelet adhesion and activation occurred consequently on a SWNT membrane surface pre-absorbed with fresh plasma, and the percentage of activated platelets caused by a SWNT membrane in a platelet-rich-plasma was about 5?%. The conclusion is that the SWNT membrane has unique platelet inertness in blood environments and this anticoagulant effect permits potential use in artificial organs, prostheses and tissue engineering in the cardiac-vascular systems.
文摘Single wall carbon nanotube (SWNT) was prepared by d.c. arc discharge method and purified by filtration method. After refluxed in HNO 3, the ends of SWNT were opened and oxidized into carboxylate group, which may react with other reagents. For chemical modification of SWNT, the carboxyl terminated SWNT reacted with CH 3(CH 2) 15 NH 2 with the aid of the condensation agent DCC to obtain the derivatives of SWNT with the amido alkyl chain which enhanced the solubility of SWNT in organic solvent. The results of micro IR prove the formation of amido group in SWNT sample(\{ (CO)=\}1 647 cm -1 ). The FT Raman results show that SWNT sample preserve its structure after the condensation reaction( ω r=181 cm -1 ). [WT5HZ]
文摘The electrochemical behavior of the film of single wall carbon nanotube(SWNT) functionalized with carboxylic acid group was studied extensively at the glassy carbon(GC) electrode. One stable couple of waves corresponding to the redox of the carboxylic acid group, which was supported by the IR experiments, was observed. The electrode process involved four electrons, while the rate determining step was a one-electron reduction. The SWNT film modified electrode showed nice electrocatalytic behaviors toward the oxidations of some biomolecules such as dopamine, epinephrine and ascorbic acid.
