The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressur...The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressure range of 26.6-266 Pa.The results showed that adsorption was found to be the rate-controlling process for the thiophene/NiY zeolite system,and there were two different adsorption processes.Two kinds of adsorption models have been proposed,namely:the S-M interaction(low frequency adsorption) and the π-complexation(high frequency adsorption).High frequency adsorption obeyed the Langmuir model.By combining the FR method and Langmuir model,the adsorption site of high frequency adsorption process at 302 K and 335 K was 3.172 mmol/g and 2.974 mmol/g,respectively,and on the combined adsorption isotherms,the adsorption site of the low frequency adsorption process at 302 K and 335 K was 0.308 mmol/gand 0.436 mmol/g,respectively.The low frequency adsorption process(S-M interaction) was the main adsorption process.The diffusion process was the rate-controlling process for the benzene-NiY zeolite system.展开更多
In this paper,we establish the Hàjek-Rèniy type inequality for Banach space valued martingales generalizing the recent results of Tómcs and L'ibor [1].Then p-uniformly smoothable Banach space is c...In this paper,we establish the Hàjek-Rèniy type inequality for Banach space valued martingales generalizing the recent results of Tómcs and L'ibor [1].Then p-uniformly smoothable Banach space is characterized in terms of the Hàjek-Rèniy type inequality for Banach space valued martingales.Those results generalize the recent results of Gan Shixin [2].展开更多
Based on NII spectra, some transition probabilities for 2p4f-2p3d and 2s2p23d-2s2p23p are obtained by a semi- classical method. The results are in good agreement with other measurements and the data reported by the Na...Based on NII spectra, some transition probabilities for 2p4f-2p3d and 2s2p23d-2s2p23p are obtained by a semi- classical method. The results are in good agreement with other measurements and the data reported by the National Institute of Standards and Technology. The transition probability for a line of 424.18nm is reported for the first time. Meanwhile, a feasible method of calculating transition parameters related to special excited configurations or highly excited states is provided.展开更多
基金the National Natural Science Foundation of China(NSFC.Contract No.20546003 and No.20776064)
文摘The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressure range of 26.6-266 Pa.The results showed that adsorption was found to be the rate-controlling process for the thiophene/NiY zeolite system,and there were two different adsorption processes.Two kinds of adsorption models have been proposed,namely:the S-M interaction(low frequency adsorption) and the π-complexation(high frequency adsorption).High frequency adsorption obeyed the Langmuir model.By combining the FR method and Langmuir model,the adsorption site of high frequency adsorption process at 302 K and 335 K was 3.172 mmol/g and 2.974 mmol/g,respectively,and on the combined adsorption isotherms,the adsorption site of the low frequency adsorption process at 302 K and 335 K was 0.308 mmol/gand 0.436 mmol/g,respectively.The low frequency adsorption process(S-M interaction) was the main adsorption process.The diffusion process was the rate-controlling process for the benzene-NiY zeolite system.
基金Supported by the Youth Foundation of the Department of Education of Sichuan Province（07ZB042） Supported by Natural Science Foundation of the Department of Education of Sichuan Province（09ZC071）
文摘In this paper,we establish the Hàjek-Rèniy type inequality for Banach space valued martingales generalizing the recent results of Tómcs and L'ibor [1].Then p-uniformly smoothable Banach space is characterized in terms of the Hàjek-Rèniy type inequality for Banach space valued martingales.Those results generalize the recent results of Gan Shixin [2].
基金Project supported by the National Natural Science Foundation of China （Grant No 40475007）.
文摘Based on NII spectra, some transition probabilities for 2p4f-2p3d and 2s2p23d-2s2p23p are obtained by a semi- classical method. The results are in good agreement with other measurements and the data reported by the National Institute of Standards and Technology. The transition probability for a line of 424.18nm is reported for the first time. Meanwhile, a feasible method of calculating transition parameters related to special excited configurations or highly excited states is provided.
