An analytical method for the determination of 26 impurity elements （such as Li, Be, Na, Mg, Al, Si, P, S, K, Ca, Sc, Ti, V, Cr, Co, Ni, Ga, Ge, Y, Nb, Mo, Ag, Cd, Sb, W and Pb） in MnZn ferrite powder by direct curre...An analytical method for the determination of 26 impurity elements （such as Li, Be, Na, Mg, Al, Si, P, S, K, Ca, Sc, Ti, V, Cr, Co, Ni, Ga, Ge, Y, Nb, Mo, Ag, Cd, Sb, W and Pb） in MnZn ferrite powder by direct current glow discharge mass spectrometry （GD-MS） was established. MnZn ferrite powder was mixed with copper powder, used as a conductor, and pressed. The effects of MnZn ferrite powder preparation conditions and glow discharge parameters for the sensitivity and stability of signal analysis were investigated. By determining the choice of isotope and the application of the mass resolutions of 4000 （MR, medium resolution） and 10000 （HR, high resolution）, mass spectral interference was eliminated. The contents of impurity elements in MnZn ferrite powder was calculated by subtraction after normalizing the total signal of Mn, Zn, Fe, O and Cu. The results showed that the detection limit of 26 kinds of impurity elements was between 0.002 and 0.57 μg/g, and the relative standard deviation （RSD） was between 3.33% and 32.35%. The accuracy of this method was verified by the ICP-MS. The method was simple and practical, which is applied to the determination of impurity elements in MnZn ferrite powder.展开更多
Pt and Ir coatings were produced by double glow plasma technology on the surface of Ti alloy substrates. The chemical compositions of the coatings were determined by X-ray diffraction and X-ray photoelectron spectrosc...Pt and Ir coatings were produced by double glow plasma technology on the surface of Ti alloy substrates. The chemical compositions of the coatings were determined by X-ray diffraction and X-ray photoelectron spectroscopy. The microstructure and morphology of the coatings were observed by scanning electron microscopy. The hardness and elastic modulus of the coatings were estimated by nanoindentation. The measurements of adhesive forces of the coatings were performed with scratch tester. The results indicated that the Pt and Ir coatings displayed the preferred (220) orientation due to the initial nuclei with preferred growth on the surface of the substrates. The interface between the Pt coating and substrate exhibited no evidence of delamination. The Ir coating was composed of irregular columnar grains with many nanovoids at the interface between the coating and substrate. The mean values of hardness for Pt and Ir coatings were 0.9 GPa and 9 GPa, respectively. The elastic modulus of Pt and Ir coatings were 178 GPa and 339 GPa, respectively. The adhesive forces of the Pt and Ir coatings were about 66.4 N and 55 N, respectively. The Pt and Ir coatings adhered well to the Ti alloy substrates.展开更多
To discuss the modes of dielectric barrier discharge(DBD) between needle-to-plane electrodes in air,DBD is generated and observed on a needle-to-plane device at atmospheric pressure air.Fast images of the DBD are take...To discuss the modes of dielectric barrier discharge(DBD) between needle-to-plane electrodes in air,DBD is generated and observed on a needle-to-plane device at atmospheric pressure air.Fast images of the DBD are taken by using a charge couple device(CCD) cinema with a macro lens,while the electrical and photo-electricity waveforms of the DBD are recorded.The current waveforms show that under an applied voltage of 3 kV,there are numerous short current pulses in both positive and negative half-periods of discharges.However,under 6 kV,there are still the numerous short current pulses in the positive half-periods,but only one wide current pulse in each negative half-period.This difference is also found in the photoelectric signals.The streamer,corona and glow discharges are observed from the images of the discharges at different applied voltages.The structure of glow discharge in the negative period is exactly the same as that of the low pressure glow discharge.However,in the positive period of discharge there is always a streamer.In the negative period of discharge,while the applied voltage increases,the transition from corona to glow discharge is observed.The progress of a transition between streamer and glow discharge at 6 kV during one period is analyzed.The glow discharge appearance is determined by two factors: the discharge current is limited to a certain extent by the dielectric layer; the charges deposited on the dielectric layer during the last half period enhance the intensity of the electric field.At an insufficient applied voltage,the cathode drop leads to no glow discharge,but Trichel pulses.展开更多
In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospher...In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospheric pressure are numerically studied.The results show that,a discharge without dielectric layers,i.e.a barrier free discharge,is extinguished only with the decrease of the applied voltage.Only one positive discharge event occurs at the slope of the pulsed voltage.A stable glow of barrier free discharge can be achieved only in short durations of the pulsed voltage.The barrier free discharge always starts with a subnormal glow discharge and then evolves into a normal glow discharge.Moreover,to control the discharge stabilization better,the effects of pulse repetition frequency,pulse duration,rising(front) and falling(slope) times on the discharge characteristics are investigated systematically.It is found that the discharge is comparatively more sensitive to the repetition frequency and the pulse duration,while little affected by the rising and falling times.展开更多
In this paper,the influence of ammonia admixture on argon discharge properties is investigated.Electrical measurements,as well as ten-nanoseconds-exposure photographs taken by an intensified charge-coupled device(ICCD...In this paper,the influence of ammonia admixture on argon discharge properties is investigated.Electrical measurements,as well as ten-nanoseconds-exposure photographs taken by an intensified charge-coupled device(ICCD)camera,are employed to confirm the existence of atmospheric pressure glow discharge(APGD)in Ar/NH3mixture.The breakdown voltage and transition voltage between APGD and filamentary discharge are studied at various ammonia concentrations.The results show that a small amount of NH3can lead to APGD due to the Penning ionization of NH3molecules by metastable argon,and the breakdown voltage increases with the growth in NH3concentrations owing to the electronegative feature of NH3.The optical emission spectrum of Ar/NH3APGD is analyzed.Besides,gas temperature is estimated at 327 K by the diagnoses of the OH(A-X)(0,0)band of the spectrum.展开更多
基金Project(21275162)supported by the National Natural Science Foundation of ChinaProject(KJZH14217)supported by the Achievement Transfer Program of Institutions of Higher Education in Chongqing,ChinaProject(KJ1601224)supported by the Scientific and Technological Research Program of Chongqing Municipal Education Commission,China
文摘An analytical method for the determination of 26 impurity elements （such as Li, Be, Na, Mg, Al, Si, P, S, K, Ca, Sc, Ti, V, Cr, Co, Ni, Ga, Ge, Y, Nb, Mo, Ag, Cd, Sb, W and Pb） in MnZn ferrite powder by direct current glow discharge mass spectrometry （GD-MS） was established. MnZn ferrite powder was mixed with copper powder, used as a conductor, and pressed. The effects of MnZn ferrite powder preparation conditions and glow discharge parameters for the sensitivity and stability of signal analysis were investigated. By determining the choice of isotope and the application of the mass resolutions of 4000 （MR, medium resolution） and 10000 （HR, high resolution）, mass spectral interference was eliminated. The contents of impurity elements in MnZn ferrite powder was calculated by subtraction after normalizing the total signal of Mn, Zn, Fe, O and Cu. The results showed that the detection limit of 26 kinds of impurity elements was between 0.002 and 0.57 μg/g, and the relative standard deviation （RSD） was between 3.33% and 32.35%. The accuracy of this method was verified by the ICP-MS. The method was simple and practical, which is applied to the determination of impurity elements in MnZn ferrite powder.
基金supported by the National Natural Science Foundation of China(50872055/E020703)Funding for Outstanding Doctoral Dissertation in NUAA(BCXJ1109)the Funding of Jiangsu Innovation Program for Graduate Education(CXLX11_0207)
文摘Pt and Ir coatings were produced by double glow plasma technology on the surface of Ti alloy substrates. The chemical compositions of the coatings were determined by X-ray diffraction and X-ray photoelectron spectroscopy. The microstructure and morphology of the coatings were observed by scanning electron microscopy. The hardness and elastic modulus of the coatings were estimated by nanoindentation. The measurements of adhesive forces of the coatings were performed with scratch tester. The results indicated that the Pt and Ir coatings displayed the preferred (220) orientation due to the initial nuclei with preferred growth on the surface of the substrates. The interface between the Pt coating and substrate exhibited no evidence of delamination. The Ir coating was composed of irregular columnar grains with many nanovoids at the interface between the coating and substrate. The mean values of hardness for Pt and Ir coatings were 0.9 GPa and 9 GPa, respectively. The elastic modulus of Pt and Ir coatings were 178 GPa and 339 GPa, respectively. The adhesive forces of the Pt and Ir coatings were about 66.4 N and 55 N, respectively. The Pt and Ir coatings adhered well to the Ti alloy substrates.
基金supported by National High-tech Research and Development Program of China(863 Program)(2012AA062609)National Twelfth-five Year Science and Technology Supporting Program of China(2013BAC06B02)+1 种基金Special Fund for Marine Scientific Research in the Public Interest(201305027-5)Fundamental Research Fund for the Central Universities(3132013316)
文摘To discuss the modes of dielectric barrier discharge(DBD) between needle-to-plane electrodes in air,DBD is generated and observed on a needle-to-plane device at atmospheric pressure air.Fast images of the DBD are taken by using a charge couple device(CCD) cinema with a macro lens,while the electrical and photo-electricity waveforms of the DBD are recorded.The current waveforms show that under an applied voltage of 3 kV,there are numerous short current pulses in both positive and negative half-periods of discharges.However,under 6 kV,there are still the numerous short current pulses in the positive half-periods,but only one wide current pulse in each negative half-period.This difference is also found in the photoelectric signals.The streamer,corona and glow discharges are observed from the images of the discharges at different applied voltages.The structure of glow discharge in the negative period is exactly the same as that of the low pressure glow discharge.However,in the positive period of discharge there is always a streamer.In the negative period of discharge,while the applied voltage increases,the transition from corona to glow discharge is observed.The progress of a transition between streamer and glow discharge at 6 kV during one period is analyzed.The glow discharge appearance is determined by two factors: the discharge current is limited to a certain extent by the dielectric layer; the charges deposited on the dielectric layer during the last half period enhance the intensity of the electric field.At an insufficient applied voltage,the cathode drop leads to no glow discharge,but Trichel pulses.
文摘In order to better understand the physical mechanism of sub-microsecond pulsed glow discharge with bare metal electrodes,using a one-dimensional self-consistent fluid model,the properties of the discharge at atmospheric pressure are numerically studied.The results show that,a discharge without dielectric layers,i.e.a barrier free discharge,is extinguished only with the decrease of the applied voltage.Only one positive discharge event occurs at the slope of the pulsed voltage.A stable glow of barrier free discharge can be achieved only in short durations of the pulsed voltage.The barrier free discharge always starts with a subnormal glow discharge and then evolves into a normal glow discharge.Moreover,to control the discharge stabilization better,the effects of pulse repetition frequency,pulse duration,rising(front) and falling(slope) times on the discharge characteristics are investigated systematically.It is found that the discharge is comparatively more sensitive to the repetition frequency and the pulse duration,while little affected by the rising and falling times.
基金Project supported by China National Fund for Distinguished Young Scientists(51125029)
文摘In this paper,the influence of ammonia admixture on argon discharge properties is investigated.Electrical measurements,as well as ten-nanoseconds-exposure photographs taken by an intensified charge-coupled device(ICCD)camera,are employed to confirm the existence of atmospheric pressure glow discharge(APGD)in Ar/NH3mixture.The breakdown voltage and transition voltage between APGD and filamentary discharge are studied at various ammonia concentrations.The results show that a small amount of NH3can lead to APGD due to the Penning ionization of NH3molecules by metastable argon,and the breakdown voltage increases with the growth in NH3concentrations owing to the electronegative feature of NH3.The optical emission spectrum of Ar/NH3APGD is analyzed.Besides,gas temperature is estimated at 327 K by the diagnoses of the OH(A-X)(0,0)band of the spectrum.
