In this paper,a conventional soliton(CS)mode-locked erbium-doped fiber(EDF)laser was de-veloped using MAX phase material(MAX-PM)Nb_(4)AlC_(3)as a saturable absorber(SA).First,the liquid phase exfoliation(LPE)method wa...In this paper,a conventional soliton(CS)mode-locked erbium-doped fiber(EDF)laser was de-veloped using MAX phase material(MAX-PM)Nb_(4)AlC_(3)as a saturable absorber(SA).First,the liquid phase exfoliation(LPE)method was utilized to prepare Nb_(4)AlC_(3)nanosheets,and then a piece of tapered fiber was adopted to fabricate Nb_(4)AlC_(3)-SA.It was found that the saturation intensity and modulation depth of the Nb_(4)AlC_(3)-SA are 2.02 MW/cm^(2)and 1.88%.Based on the Nb_(4)AlC_(3)-SA,a conventional soliton(CS)mode-locked EDF laser was achieved.The central wavelength,pulse duration,and pulse repetition rate were found to be 1565.65 nm,615.37 fs,and 24.63 MHz,respectively.The performance is competitive and particularly superior in terms of pulse duration.This study fully confirms that Nb_(4)AlC_(3)possesses marvellous nonlinear saturable absorption properties and opens new possibilities for further research on air-stable ultrafast photon-ic devices.展开更多
以 Na Cl薄液层模拟 LC4CS铝合金的大气腐蚀环境 ,并在实验室空气中、3 .5 % Na Cl溶液中和 Na Cl薄液层作用下研究 LC4CS铝合金的疲劳性能。结果显示 ,在 ΔK小于 40 0 N/mm3/2时 ,薄液层下铝合金的腐蚀疲劳裂纹扩展速率大于 Na Cl溶...以 Na Cl薄液层模拟 LC4CS铝合金的大气腐蚀环境 ,并在实验室空气中、3 .5 % Na Cl溶液中和 Na Cl薄液层作用下研究 LC4CS铝合金的疲劳性能。结果显示 ,在 ΔK小于 40 0 N/mm3/2时 ,薄液层下铝合金的腐蚀疲劳裂纹扩展速率大于 Na Cl溶液中的数值 ,也大于实验室空气中的数值。在ΔK较小时 ,薄液层下腐蚀疲劳裂纹断口的特征与 Na Cl溶液中的较为接近 。展开更多
The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized ...The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized and measured by ultra violet absorption spectrometry and fluorescence spectrum. The results show that upconversion spectrum exhibit at 590nm and 610nm exited at 790nm, and the upconversion intensity increases with the EuCl3 ratio increasing in CsCl.展开更多
The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid ph...The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .展开更多
The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(...The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(6)? 3, Z=4. The Pd? ion has an square planar geometry, and is coordinated by four S atom donors from four thiourea molecules. The two Cl- anions found in the apical position balance the charge. In the solid state, the title compound forms three dimensional network structures through hydrogen bonds. The intermolecular hydrogen bonds connect the {Pd4}2+ and chloride ion to contribute to the stability of the structure. CCDC: 193379.展开更多
文摘In this paper,a conventional soliton(CS)mode-locked erbium-doped fiber(EDF)laser was de-veloped using MAX phase material(MAX-PM)Nb_(4)AlC_(3)as a saturable absorber(SA).First,the liquid phase exfoliation(LPE)method was utilized to prepare Nb_(4)AlC_(3)nanosheets,and then a piece of tapered fiber was adopted to fabricate Nb_(4)AlC_(3)-SA.It was found that the saturation intensity and modulation depth of the Nb_(4)AlC_(3)-SA are 2.02 MW/cm^(2)and 1.88%.Based on the Nb_(4)AlC_(3)-SA,a conventional soliton(CS)mode-locked EDF laser was achieved.The central wavelength,pulse duration,and pulse repetition rate were found to be 1565.65 nm,615.37 fs,and 24.63 MHz,respectively.The performance is competitive and particularly superior in terms of pulse duration.This study fully confirms that Nb_(4)AlC_(3)possesses marvellous nonlinear saturable absorption properties and opens new possibilities for further research on air-stable ultrafast photon-ic devices.
文摘以 Na Cl薄液层模拟 LC4CS铝合金的大气腐蚀环境 ,并在实验室空气中、3 .5 % Na Cl溶液中和 Na Cl薄液层作用下研究 LC4CS铝合金的疲劳性能。结果显示 ,在 ΔK小于 40 0 N/mm3/2时 ,薄液层下铝合金的腐蚀疲劳裂纹扩展速率大于 Na Cl溶液中的数值 ,也大于实验室空气中的数值。在ΔK较小时 ,薄液层下腐蚀疲劳裂纹断口的特征与 Na Cl溶液中的较为接近 。
文摘The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized and measured by ultra violet absorption spectrometry and fluorescence spectrum. The results show that upconversion spectrum exhibit at 590nm and 610nm exited at 790nm, and the upconversion intensity increases with the EuCl3 ratio increasing in CsCl.
文摘The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .
文摘The title compound, Pd4Cl2, has been synthesized and structurally characterized. It crystallizes in orthorhombic, Pna2(1) space group , with Mr=481.79(C4H16Cl2N8PdS4), a=12.943(3), b=8.283(2), c=15.148(3)? , V=1623.9(6)? 3, Z=4. The Pd? ion has an square planar geometry, and is coordinated by four S atom donors from four thiourea molecules. The two Cl- anions found in the apical position balance the charge. In the solid state, the title compound forms three dimensional network structures through hydrogen bonds. The intermolecular hydrogen bonds connect the {Pd4}2+ and chloride ion to contribute to the stability of the structure. CCDC: 193379.
