Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as...Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.展开更多
An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the...An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.展开更多
In the paper,we report a highly robust and porous bimetallic Ti-MOF(designated Mg_(2)Ti-ABTC)by utiliz-ing a trinuclear[Mg_(2)TiO(COO)_(6)]cluster and a tetradentate H_(4)ABTC(3,3′,5,5′-azobenzene tetracarboxylic ac...In the paper,we report a highly robust and porous bimetallic Ti-MOF(designated Mg_(2)Ti-ABTC)by utiliz-ing a trinuclear[Mg_(2)TiO(COO)_(6)]cluster and a tetradentate H_(4)ABTC(3,3′,5,5′-azobenzene tetracarboxylic acid)ligand.Mg_(2)Ti-ABTC exhibited permanent porosity for N_(2),CO_(2),CH_(4),C_(2)H_(2),C_(2)H_(4),and C_(2)H_(6)gas adsorption.Further-more,Mg_(2)Ti-ABTC exhibited outstanding photocatalytic activity in the oxidation of aromatic sulfides to the corre-sponding sulfoxides under ambient air conditions.Mechanism studies reveal that photoinduced holes(h^(+)),the super-oxide radical(·O_(2)^(-)),and singlet oxygen(^(1)O_(2))are pivotal species involved in the photocatalytic oxidation reaction.展开更多
When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution...When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.展开更多
As battlefield scale enlarges,cross-platform collaborative combat provides an appealing paradigm for modern warfare.Complicated constraints and vast solution space pose great challenge for reasonable and efficient mis...As battlefield scale enlarges,cross-platform collaborative combat provides an appealing paradigm for modern warfare.Complicated constraints and vast solution space pose great challenge for reasonable and efficient mission planning,where path planning and target assignment are tightly coupled.In this paper,we focus on UAV mission planning under carrier delivery mode(e.g.,by aircraft carrier,ground vehicle,or transport aircraft) and design a three-layer hierarchical solution framework.In the first layer,we simultaneously determine delivery points and target set division by clustering.To address the safety concerns of radar risk and UAV endurance,an improved density peak clustering algorithm is developed by constraint fusio n.In the second layer,mission planning within each cluster is viewed as a coope rative multiple-task assignment problem.A hybrid heuristic algorithm that integrates a voting-based heuristic solution generation strategy(VHSG) and a stochastic variable neighborhood search(SVNS),called VHSG-SVNS,is proposed for rapid solution.Based on the results of the first two layers,the third layer transforms carrier path planning into a multiple-vehicle routing problem with time window.The cost between any two nodes is calculated by the A~* algorithm,and the genetic algorithm is then implemented to determine the global route.Finally,a practical mission scenario containing 200 targets is used to validate the effectiveness of the designed framework,where three layers cooperate well with each other to generate satisfactory combat scheduling.Comparisons are made in each layer to highlight optimum-seeking capability and efficiency of the proposed algorithms.Works done in this paper provide a simple but efficient solution framework for cross-platform cooperative mission planning problems,and can be potentially extended to other applications such as post-disaster search and rescue,forest surveillance and firefighting,logistics pick and delivery,etc.展开更多
As the core component of inertial navigation systems, fiber optic gyroscope (FOG), with technical advantages such as low power consumption, long lifespan, fast startup speed, and flexible structural design, are widely...As the core component of inertial navigation systems, fiber optic gyroscope (FOG), with technical advantages such as low power consumption, long lifespan, fast startup speed, and flexible structural design, are widely used in aerospace, unmanned driving, and other fields. However, due to the temper-ature sensitivity of optical devices, the influence of environmen-tal temperature causes errors in FOG, thereby greatly limiting their output accuracy. This work researches on machine-learn-ing based temperature error compensation techniques for FOG. Specifically, it focuses on compensating for the bias errors gen-erated in the fiber ring due to the Shupe effect. This work pro-poses a composite model based on k-means clustering, sup-port vector regression, and particle swarm optimization algo-rithms. And it significantly reduced redundancy within the sam-ples by adopting the interval sequence sample. Moreover, met-rics such as root mean square error (RMSE), mean absolute error (MAE), bias stability, and Allan variance, are selected to evaluate the model’s performance and compensation effective-ness. This work effectively enhances the consistency between data and models across different temperature ranges and tem-perature gradients, improving the bias stability of the FOG from 0.022 °/h to 0.006 °/h. Compared to the existing methods utiliz-ing a single machine learning model, the proposed method increases the bias stability of the compensated FOG from 57.11% to 71.98%, and enhances the suppression of rate ramp noise coefficient from 2.29% to 14.83%. This work improves the accuracy of FOG after compensation, providing theoretical guid-ance and technical references for sensors error compensation work in other fields.展开更多
Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication lin...Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication links.However,when UAV swarm perform tasks in narrow spaces,they often encounter various spatial obstacles,building shielding materials,and high-speed node movements,which result in intermittent network communication links and cannot support the smooth comple-tion of tasks.In this paper,a high mobility and dynamic topol-ogy of the UAV swarm is particularly considered and the high dynamic mobile topology-based clustering(HDMTC)algorithm is proposed.Simulation and real flight verification results verify that the proposed HDMTC algorithm achieves higher stability of net-work,longer link expiration time(LET),and longer node lifetime,all of which improve the communication performance for UAV swarm networks.展开更多
Genetic relationships between Ziziphus jujuba and Ziziphus spinosa populations were studied using RAPD data in population genetics. 275 loci were gained among which 249 loci were polymorphic by 22 primers. The polymor...Genetic relationships between Ziziphus jujuba and Ziziphus spinosa populations were studied using RAPD data in population genetics. 275 loci were gained among which 249 loci were polymorphic by 22 primers. The polymorphic loci percentage was 89% among Z.spinosa population while that of Z.jujuba population was 56%. 31 specific RAPD markers were detected on 3 Z.jujuba varieties and 15 Z.spinosa forms. Cluster analysis showed: when λ=12, the forms tested were divided into 2 groups. One included Z. jujuba cv. Zanhuangdazao, Yudichuangan, Yuanshichuangan, Xiaochuangan, Qiantai No.1, Luzhuangchuangan; the other included Z. jujuba cv. Zilingdan and 26 Z. spinosa forms. All above indicated that Z. jujuba and Z.spinosa should be regarded as two separate species.展开更多
为寻求模型不匹配问题的一种恰当的解决途径,提出了基于语料分布特性的CADIC(clustering algorithm based on the distributions of intrinsic clusters)聚类算法.CADIC以重标度的形式隐式地将语料特性融入算法框架,从而使算法模型具备...为寻求模型不匹配问题的一种恰当的解决途径,提出了基于语料分布特性的CADIC(clustering algorithm based on the distributions of intrinsic clusters)聚类算法.CADIC以重标度的形式隐式地将语料特性融入算法框架,从而使算法模型具备更灵活的适应能力.在聚类过程中,CADIC选择一组具有良好区分度的方向构建CADIC坐标系,在该坐标系下统计固有簇的分布特性,以构造各个坐标轴的重标度函数,并以重标度的形式对语料分布进行隐式的归一化,从而提高聚类决策的有效性.CADIC以迭代的方式收敛到最终解,其时间复杂度与K-means保持在同一量级.在国际知名评测语料上的实验结果表明,CADIC算法的基本框架是合理的,其聚类性能与当前领先水平的聚类算法相当.展开更多
GRAPES(global and regional assimilation and prediction system)是由中国气象科学研究院灾害天气国家重点实验室自主研究开发的中国新一代数值天气预报系统,其目标是科研/业务通用.为了实现这一目标,结合高性能计算机的体系结构设计...GRAPES(global and regional assimilation and prediction system)是由中国气象科学研究院灾害天气国家重点实验室自主研究开发的中国新一代数值天气预报系统,其目标是科研/业务通用.为了实现这一目标,结合高性能计算机的体系结构设计并实现模式的并行计算是必不可少的.作为核心开发技术之一,GRAPES系统设计并实现了模式的并行计算方案,包括中尺度有限区模式的并行计算和全球模式并行计算.GRAPES模式并行计算版本在IBM-Cluster1600上的测试表明,GRAPES模式的并行计算程序正确、稳定、有效,为其业务化之路奠定了基础,同时也为系统未来的可持续开发、优化创造了条件.展开更多
文摘Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.
文摘An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.
文摘In the paper,we report a highly robust and porous bimetallic Ti-MOF(designated Mg_(2)Ti-ABTC)by utiliz-ing a trinuclear[Mg_(2)TiO(COO)_(6)]cluster and a tetradentate H_(4)ABTC(3,3′,5,5′-azobenzene tetracarboxylic acid)ligand.Mg_(2)Ti-ABTC exhibited permanent porosity for N_(2),CO_(2),CH_(4),C_(2)H_(2),C_(2)H_(4),and C_(2)H_(6)gas adsorption.Further-more,Mg_(2)Ti-ABTC exhibited outstanding photocatalytic activity in the oxidation of aromatic sulfides to the corre-sponding sulfoxides under ambient air conditions.Mechanism studies reveal that photoinduced holes(h^(+)),the super-oxide radical(·O_(2)^(-)),and singlet oxygen(^(1)O_(2))are pivotal species involved in the photocatalytic oxidation reaction.
基金supported by the National Natural Science Foundation of China(72471240).
文摘When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.
文摘As battlefield scale enlarges,cross-platform collaborative combat provides an appealing paradigm for modern warfare.Complicated constraints and vast solution space pose great challenge for reasonable and efficient mission planning,where path planning and target assignment are tightly coupled.In this paper,we focus on UAV mission planning under carrier delivery mode(e.g.,by aircraft carrier,ground vehicle,or transport aircraft) and design a three-layer hierarchical solution framework.In the first layer,we simultaneously determine delivery points and target set division by clustering.To address the safety concerns of radar risk and UAV endurance,an improved density peak clustering algorithm is developed by constraint fusio n.In the second layer,mission planning within each cluster is viewed as a coope rative multiple-task assignment problem.A hybrid heuristic algorithm that integrates a voting-based heuristic solution generation strategy(VHSG) and a stochastic variable neighborhood search(SVNS),called VHSG-SVNS,is proposed for rapid solution.Based on the results of the first two layers,the third layer transforms carrier path planning into a multiple-vehicle routing problem with time window.The cost between any two nodes is calculated by the A~* algorithm,and the genetic algorithm is then implemented to determine the global route.Finally,a practical mission scenario containing 200 targets is used to validate the effectiveness of the designed framework,where three layers cooperate well with each other to generate satisfactory combat scheduling.Comparisons are made in each layer to highlight optimum-seeking capability and efficiency of the proposed algorithms.Works done in this paper provide a simple but efficient solution framework for cross-platform cooperative mission planning problems,and can be potentially extended to other applications such as post-disaster search and rescue,forest surveillance and firefighting,logistics pick and delivery,etc.
基金supported by the National Natural Science Foundation of China(62375013).
文摘As the core component of inertial navigation systems, fiber optic gyroscope (FOG), with technical advantages such as low power consumption, long lifespan, fast startup speed, and flexible structural design, are widely used in aerospace, unmanned driving, and other fields. However, due to the temper-ature sensitivity of optical devices, the influence of environmen-tal temperature causes errors in FOG, thereby greatly limiting their output accuracy. This work researches on machine-learn-ing based temperature error compensation techniques for FOG. Specifically, it focuses on compensating for the bias errors gen-erated in the fiber ring due to the Shupe effect. This work pro-poses a composite model based on k-means clustering, sup-port vector regression, and particle swarm optimization algo-rithms. And it significantly reduced redundancy within the sam-ples by adopting the interval sequence sample. Moreover, met-rics such as root mean square error (RMSE), mean absolute error (MAE), bias stability, and Allan variance, are selected to evaluate the model’s performance and compensation effective-ness. This work effectively enhances the consistency between data and models across different temperature ranges and tem-perature gradients, improving the bias stability of the FOG from 0.022 °/h to 0.006 °/h. Compared to the existing methods utiliz-ing a single machine learning model, the proposed method increases the bias stability of the compensated FOG from 57.11% to 71.98%, and enhances the suppression of rate ramp noise coefficient from 2.29% to 14.83%. This work improves the accuracy of FOG after compensation, providing theoretical guid-ance and technical references for sensors error compensation work in other fields.
基金supported by the National Key Research and Development Program of China(2024YFB4504500)Shanghai Collaborative Innovation Project(24xtcx00500).
文摘Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication links.However,when UAV swarm perform tasks in narrow spaces,they often encounter various spatial obstacles,building shielding materials,and high-speed node movements,which result in intermittent network communication links and cannot support the smooth comple-tion of tasks.In this paper,a high mobility and dynamic topol-ogy of the UAV swarm is particularly considered and the high dynamic mobile topology-based clustering(HDMTC)algorithm is proposed.Simulation and real flight verification results verify that the proposed HDMTC algorithm achieves higher stability of net-work,longer link expiration time(LET),and longer node lifetime,all of which improve the communication performance for UAV swarm networks.
文摘Genetic relationships between Ziziphus jujuba and Ziziphus spinosa populations were studied using RAPD data in population genetics. 275 loci were gained among which 249 loci were polymorphic by 22 primers. The polymorphic loci percentage was 89% among Z.spinosa population while that of Z.jujuba population was 56%. 31 specific RAPD markers were detected on 3 Z.jujuba varieties and 15 Z.spinosa forms. Cluster analysis showed: when λ=12, the forms tested were divided into 2 groups. One included Z. jujuba cv. Zanhuangdazao, Yudichuangan, Yuanshichuangan, Xiaochuangan, Qiantai No.1, Luzhuangchuangan; the other included Z. jujuba cv. Zilingdan and 26 Z. spinosa forms. All above indicated that Z. jujuba and Z.spinosa should be regarded as two separate species.
文摘为寻求模型不匹配问题的一种恰当的解决途径,提出了基于语料分布特性的CADIC(clustering algorithm based on the distributions of intrinsic clusters)聚类算法.CADIC以重标度的形式隐式地将语料特性融入算法框架,从而使算法模型具备更灵活的适应能力.在聚类过程中,CADIC选择一组具有良好区分度的方向构建CADIC坐标系,在该坐标系下统计固有簇的分布特性,以构造各个坐标轴的重标度函数,并以重标度的形式对语料分布进行隐式的归一化,从而提高聚类决策的有效性.CADIC以迭代的方式收敛到最终解,其时间复杂度与K-means保持在同一量级.在国际知名评测语料上的实验结果表明,CADIC算法的基本框架是合理的,其聚类性能与当前领先水平的聚类算法相当.
文摘GRAPES(global and regional assimilation and prediction system)是由中国气象科学研究院灾害天气国家重点实验室自主研究开发的中国新一代数值天气预报系统,其目标是科研/业务通用.为了实现这一目标,结合高性能计算机的体系结构设计并实现模式的并行计算是必不可少的.作为核心开发技术之一,GRAPES系统设计并实现了模式的并行计算方案,包括中尺度有限区模式的并行计算和全球模式并行计算.GRAPES模式并行计算版本在IBM-Cluster1600上的测试表明,GRAPES模式的并行计算程序正确、稳定、有效,为其业务化之路奠定了基础,同时也为系统未来的可持续开发、优化创造了条件.
