Gradation equation is one way to describe the gradation of coarse-grained soil conveniently,exactly and quantitatively.With the gradation equation,the influence of gradation on the mechanical behaviors of coarse-grain...Gradation equation is one way to describe the gradation of coarse-grained soil conveniently,exactly and quantitatively.With the gradation equation,the influence of gradation on the mechanical behaviors of coarse-grained soil can be expressed quantitatively.A new gradation equation with a parameter is proposed.The basic properties and applicability of the new equation are studied.The results show that the proposed equation has the applicability to express coarse-grained soil gradation(CSG),and the range of the parameter β is found to be 0<β<1.The value ofbdetermines the gradation curve shape.If β>0.5,the gradation curve is sigmoidal,otherwise the gradation curve is hyperbolic.For well graded gradations,the parameter has the value of 0.13<β<1.Several CSGs used in domestic and foreign earth-rockfill dams are probed,and the value of the parameterbfalls in the range of 0.18 to 0.97.The investigation of the range of β is of value to guide the design for CSG of earth-rockfill dam.展开更多
Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the...Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the requirements for applications in emerging fields such as renewable energy and electric vehicles due to limitations including a disordered structure and uncontrolled defects.With an aim of realizing devisable structures,adjustable functions,and performance breakthroughs,superstructured carbons is proposed and represent a category of carbon-based materials,characterized by precisely-built pores,networks,and interfaces.Superstructured carbons can overcome the limitations of traditional carbon materials and improve the performance of energy storage and conversion devices.We review the structure-activity relationships of superstructured carbons and recent research advances from three aspects including a precisely customized pore structure,a dense carbon network framework,and a multi-component highly coupled interface between the different components.Finally,we provide an outlook on the future development of and practical challenges in energy storage and conversion devices.展开更多
Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity ar...Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.展开更多
Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIB...Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIBs,which are foldable and have high energy densities,are be-coming increasingly important as power sources for wear-able devices,flexible electronics,and mobile energy applica-tions.Carbon materials,especially carbon nanofibers,are pivotal in improving the performance of FLIBs by increas-ing electrical conductivity,chemical stability,and surface area,as well as reducing costs.These materials also play a significant role in establishing conducting networks and im-proving structural integrity,which are essential for extend-ing the cycle life and enhancing the safety of the batteries.This review considers the role of electrospinning in the fabrication of critical FLIB components,with a particular emphasis on the integration of carbon materials.It explores strategies to optimize FLIB performance by fine-tuning the electrospinning para-meters,such as electric field strength,spinning rate,solution concentration,and carbonization process.Precise control over fiber properties is crucial for enhancing battery reliability and stability during folding and bending.It also highlights the latest research findings in carbon-based electrode materials,high-performance electrolytes,and separator structures,discussing the practical challenges and opportunities these materials present.It underscores the significant impact of carbon materials on the evolution of FLIBs and their potential to shape future energy storage technologies.展开更多
Background Zonal application maps are designed to represent field variability using key variables that can be translated into tailored management practices.For cotton,zonal maps for crop growth regulator(CGR)applicati...Background Zonal application maps are designed to represent field variability using key variables that can be translated into tailored management practices.For cotton,zonal maps for crop growth regulator(CGR)applications under variable-rate(VR)strategies are commonly based exclusively on vegetation indices(VIs)variability.However,VIs often saturate in dense crop vegetation areas,limiting their effectiveness in distinguishing variability in crop growth.This study aimed to compare unsupervised framework(UF)and supervised framework(SUF)approaches for generat-ing zonal application maps for CGR under VR conditions.During 2022-2023 agricultural seasons,an UF was employed to generate zonal maps based on locally collected field data on plant height of cotton,satellite imagery,soil texture,and phenology data.Subsequently,a SUF(based on historical data between 2020-2021 to 2022-2023 agricultural seasons)was developed to predict plant height using remote sensing and phenology data,aiming to replicate same zonal maps but without relying on direct field measurements of plant height.Both approaches were tested in three fields and on two different dates per field.Results The predictive model for plant height of SUF performed well,as indicated by the model metrics.However,when comparing zonal application maps for specific field-date combinations,the predicted plant height exhibited lower variability compared with field measurements.This led to variable compatibility between SUF maps,which utilized the model predictions,and the UF maps,which were based on the real field data.Fields characterized by much pronounced soil texture variability yielded the highest compatibility between the zonal application maps produced by both SUF and UF approaches.This was predominantly due to the greater consistency in estimating plant development patterns within these heterogeneous field environments.While VR application approach can facilitate product savings during the application operation,other key factors must be considered.These include the availability of specialized machinery required for this type of applications,as well as the inherent operational costs associated with applying a single CGR product which differs from the typical uniform rate applications that often integrate multi-ple inputs.Conclusion Predictive modeling shows promise for assisting in the creation of zonal application maps for VR of CGR applications.However,the degree of agreement with the actual variability in crop growth found in the field should be evaluated on a field-by-field basis.The SUF approach,which is based on plant heigh prediction,demonstrated potential for supporting the development of zonal application maps for VR of CGR applications.However,the degree to which this approach aligns itself with the actual variability in crop growth observed in the field may vary,necessi-tating field-by-field evaluation.展开更多
Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam suppor...Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam support system with high strength is developed.The high-strength bearing characteristics and coupling yielding support mechanism of this support system are studied by the mechanical tests of composite members and the combined support system.The test results show that under the coupling effect of support members,the peak stress of the box-shaped support beam in the anchor box beam is reduced by 21.9%,and the average deformation is increased by 135.0%.The ultimate bending bearing capacity of the box-shaped support beam is 3.5 times that of traditional channel beam.The effective compressive stress zone applied by the high prestressed cable is expanded by 26.4%.On this basis,the field support comparison test by the anchor channel beam,the anchor I-shaped beam and the anchor box beam are carried out.Compared with those of the previous two,the surrounding rock convergence of the latter is decreased by 41.2%and 22.2%,respectively.The field test verifies the effectiveness of the anchor box beam support system.展开更多
This study investigates the potential of metal additives in acrylonitrile butadiene styrene(ABS)polymer fuel to enhance hybrid rocket motor(HRM)performance through computational analysis,Chemical Equilibrium with Appl...This study investigates the potential of metal additives in acrylonitrile butadiene styrene(ABS)polymer fuel to enhance hybrid rocket motor(HRM)performance through computational analysis,Chemical Equilibrium with Applications(CEA),software.ABS was selected as the base fuel due to its thermoplastic nature,which allows for the creation of complex fuel geometries through 3D printing,offering significant flexibility in fuel design.Hybrid rockets,which combine a solid fuel with a liquid oxidiser,offer advantages in terms of operational simplicity and safety.However,conventional polymer fuels often exhibit low regression rates and suboptimal combustion efficiencies.In this research,we evaluated a range of metal additives-aluminium(Al),boron(B),nickel(Ni),copper(Cu),and iron(Fe)-at chamber pressures ranging from 1 to 30 bar and oxidiser-to-fuel(O/F)ratios between 1.1 and 12,resulting in 1800 unique test conditions.The main performance parameters used to assess each formulation were characteristic velocity(C^(*))and adiabatic flame temperature.The results revealed that each test produced a different optimum O/F ratio,with most ratios falling between 4 and 6.The highest performance was achieved at a chamber pressure of 30 bar across all formulations.Among the additives,Al and B demonstrated significant potential for improved combustion performance with increasing metal loadings.In contrast,Fe,Cu,and Ni reached optimal performance at a minimum loading of 1%.Future work includes investigating B-Al metal composites as additives into the ABS base polymer fuel,and doing experimental validation tests where the metallised ABS polymer fuel is 3D printed.展开更多
为了解决判别聚落群过于依赖考古专家人工划分的问题,以郑洛地区新石器时代聚落遗址为例,采用基于密度的DBSCAN(density-based spatial clustering of applications with noise)算法对聚落遗址进行空间聚类研究。通过对郑洛地区四个文...为了解决判别聚落群过于依赖考古专家人工划分的问题,以郑洛地区新石器时代聚落遗址为例,采用基于密度的DBSCAN(density-based spatial clustering of applications with noise)算法对聚落遗址进行空间聚类研究。通过对郑洛地区四个文化时期聚落遗址的分布分析,发现郑洛地区的主体聚落群从研究区东部的嵩山以南地区,转移到郑洛地区中部的伊洛河流域,并且在伊洛河流域长期定居下来,不断发展扩大;大型聚落遗址主要分布在主体聚落群里,除了裴李岗文化时期部分大型聚落较孤立;从仰韶文化后期到龙山文化时期,聚落遗址分布呈主从式环状分布格局;大多数聚落群的走向都和河流分布一致。研究表明,利用DBSCAN算法进行聚落遗址聚类是可行的,通过聚类得到郑洛地区新石器时代四个文化时期聚落遗址的分布特征。展开更多
Manuel C.Molles Jr.所著的Ecology:Concepts and Applications(《生态学:概念与应用》)在教材与网络资源的建设方面进行了有益的尝试,其主教材及辅助教学资源的设计理念值得借鉴。主教材从1999年到2008年出版了4版,主教材内容及版本更...Manuel C.Molles Jr.所著的Ecology:Concepts and Applications(《生态学:概念与应用》)在教材与网络资源的建设方面进行了有益的尝试,其主教材及辅助教学资源的设计理念值得借鉴。主教材从1999年到2008年出版了4版,主教材内容及版本更新快,力求及时反映学科前沿水平的新技术、新知识;正文内容和版式编排设计以读者为本,注重为学生服务;网上辅助教学资源围绕主教材的系列产品进行整体设计,体现利教利学的建设理念,既为教师教学提供帮助和指导,也重视给予学生自我发挥的空间,网站展示条理清晰,内容布局规范,内容介绍注重以读者为中心,满足不同客户的需求。展开更多
基金Project(2018YFC1508505)supported by the National Key Research and Development Program of ChinaProject(U1865104)supported by Yalong River Joint Fund of Natural Science Foundation of China-Yalong River Basin Hydropower Development Co.,Ltd.,China+1 种基金Project(51479052)supported by National Natural Science of ChinaProject(2019T120443)supported by China Postdoctoral Science Foundation。
文摘Gradation equation is one way to describe the gradation of coarse-grained soil conveniently,exactly and quantitatively.With the gradation equation,the influence of gradation on the mechanical behaviors of coarse-grained soil can be expressed quantitatively.A new gradation equation with a parameter is proposed.The basic properties and applicability of the new equation are studied.The results show that the proposed equation has the applicability to express coarse-grained soil gradation(CSG),and the range of the parameter β is found to be 0<β<1.The value ofbdetermines the gradation curve shape.If β>0.5,the gradation curve is sigmoidal,otherwise the gradation curve is hyperbolic.For well graded gradations,the parameter has the value of 0.13<β<1.Several CSGs used in domestic and foreign earth-rockfill dams are probed,and the value of the parameterbfalls in the range of 0.18 to 0.97.The investigation of the range of β is of value to guide the design for CSG of earth-rockfill dam.
文摘Carbon materials are a key component in energy storage and conversion devices and their microstructure plays a crucial role in determining device performance.However,traditional carbon materials are unable to meet the requirements for applications in emerging fields such as renewable energy and electric vehicles due to limitations including a disordered structure and uncontrolled defects.With an aim of realizing devisable structures,adjustable functions,and performance breakthroughs,superstructured carbons is proposed and represent a category of carbon-based materials,characterized by precisely-built pores,networks,and interfaces.Superstructured carbons can overcome the limitations of traditional carbon materials and improve the performance of energy storage and conversion devices.We review the structure-activity relationships of superstructured carbons and recent research advances from three aspects including a precisely customized pore structure,a dense carbon network framework,and a multi-component highly coupled interface between the different components.Finally,we provide an outlook on the future development of and practical challenges in energy storage and conversion devices.
基金西南大学中央高校基本科研业务费项目(SWU-KT22030)重庆市教育委员会科学技术研究项目(KJQN202300205)Deutsche Forschungsgemeinschaft(DFG,German Research Foundation,457444676).
文摘Diamond combines many unique properties,including high stability,strong optical dispersion,excellent mechanical strength,and outstanding thermal conductivity.Its structure,surface groups,and electrical conductivity are also tunable,increasing its functional versatility.These make diamond and its related materials,such as its composites,highly promising for various applications in energy fields.This review summarizes recent advances and key achievements in energy storage and conversion,covering electrochemical energy storage(e.g.,batteries and supercapacitors),electrocatalytic energy conversion(e.g.,CO_(2)and nitrogen reduction reactions),and solar energy conversion(e.g.,photo-(electro)chemical CO_(2)and nitrogen reduction reactions,and solar cells).Current challenges and prospects related to the synthesis of diamond materials and the technologies for their energy applications are outlined and discussed.
文摘Electrospinning technology has emerged as a promising method for fabricating flexible lithium-ion batter-ies(FLIBs)due to its ability to create materials with desir-able properties for energy storage applications.FLIBs,which are foldable and have high energy densities,are be-coming increasingly important as power sources for wear-able devices,flexible electronics,and mobile energy applica-tions.Carbon materials,especially carbon nanofibers,are pivotal in improving the performance of FLIBs by increas-ing electrical conductivity,chemical stability,and surface area,as well as reducing costs.These materials also play a significant role in establishing conducting networks and im-proving structural integrity,which are essential for extend-ing the cycle life and enhancing the safety of the batteries.This review considers the role of electrospinning in the fabrication of critical FLIB components,with a particular emphasis on the integration of carbon materials.It explores strategies to optimize FLIB performance by fine-tuning the electrospinning para-meters,such as electric field strength,spinning rate,solution concentration,and carbonization process.Precise control over fiber properties is crucial for enhancing battery reliability and stability during folding and bending.It also highlights the latest research findings in carbon-based electrode materials,high-performance electrolytes,and separator structures,discussing the practical challenges and opportunities these materials present.It underscores the significant impact of carbon materials on the evolution of FLIBs and their potential to shape future energy storage technologies.
文摘Background Zonal application maps are designed to represent field variability using key variables that can be translated into tailored management practices.For cotton,zonal maps for crop growth regulator(CGR)applications under variable-rate(VR)strategies are commonly based exclusively on vegetation indices(VIs)variability.However,VIs often saturate in dense crop vegetation areas,limiting their effectiveness in distinguishing variability in crop growth.This study aimed to compare unsupervised framework(UF)and supervised framework(SUF)approaches for generat-ing zonal application maps for CGR under VR conditions.During 2022-2023 agricultural seasons,an UF was employed to generate zonal maps based on locally collected field data on plant height of cotton,satellite imagery,soil texture,and phenology data.Subsequently,a SUF(based on historical data between 2020-2021 to 2022-2023 agricultural seasons)was developed to predict plant height using remote sensing and phenology data,aiming to replicate same zonal maps but without relying on direct field measurements of plant height.Both approaches were tested in three fields and on two different dates per field.Results The predictive model for plant height of SUF performed well,as indicated by the model metrics.However,when comparing zonal application maps for specific field-date combinations,the predicted plant height exhibited lower variability compared with field measurements.This led to variable compatibility between SUF maps,which utilized the model predictions,and the UF maps,which were based on the real field data.Fields characterized by much pronounced soil texture variability yielded the highest compatibility between the zonal application maps produced by both SUF and UF approaches.This was predominantly due to the greater consistency in estimating plant development patterns within these heterogeneous field environments.While VR application approach can facilitate product savings during the application operation,other key factors must be considered.These include the availability of specialized machinery required for this type of applications,as well as the inherent operational costs associated with applying a single CGR product which differs from the typical uniform rate applications that often integrate multi-ple inputs.Conclusion Predictive modeling shows promise for assisting in the creation of zonal application maps for VR of CGR applications.However,the degree of agreement with the actual variability in crop growth found in the field should be evaluated on a field-by-field basis.The SUF approach,which is based on plant heigh prediction,demonstrated potential for supporting the development of zonal application maps for VR of CGR applications.However,the degree to which this approach aligns itself with the actual variability in crop growth observed in the field may vary,necessi-tating field-by-field evaluation.
基金Project(2023YFC2907600)supported by the National Key Research and Development Program of ChinaProjects(42277174,42477166)supported by the National Natural Science Foundation of China+1 种基金Project(2024JCCXSB01)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(KFJJ24-01M)supported by the State Key Laboratory of Explosion Science and Safety Protection,Beijing Institute of Technology,China。
文摘Considering the characteristics of deep thick top coal roadway,in which the high ground stress,coal seam with low strength,and a large range of surrounding rock fragmentation,the pressure relief anchor box beam support system with high strength is developed.The high-strength bearing characteristics and coupling yielding support mechanism of this support system are studied by the mechanical tests of composite members and the combined support system.The test results show that under the coupling effect of support members,the peak stress of the box-shaped support beam in the anchor box beam is reduced by 21.9%,and the average deformation is increased by 135.0%.The ultimate bending bearing capacity of the box-shaped support beam is 3.5 times that of traditional channel beam.The effective compressive stress zone applied by the high prestressed cable is expanded by 26.4%.On this basis,the field support comparison test by the anchor channel beam,the anchor I-shaped beam and the anchor box beam are carried out.Compared with those of the previous two,the surrounding rock convergence of the latter is decreased by 41.2%and 22.2%,respectively.The field test verifies the effectiveness of the anchor box beam support system.
文摘This study investigates the potential of metal additives in acrylonitrile butadiene styrene(ABS)polymer fuel to enhance hybrid rocket motor(HRM)performance through computational analysis,Chemical Equilibrium with Applications(CEA),software.ABS was selected as the base fuel due to its thermoplastic nature,which allows for the creation of complex fuel geometries through 3D printing,offering significant flexibility in fuel design.Hybrid rockets,which combine a solid fuel with a liquid oxidiser,offer advantages in terms of operational simplicity and safety.However,conventional polymer fuels often exhibit low regression rates and suboptimal combustion efficiencies.In this research,we evaluated a range of metal additives-aluminium(Al),boron(B),nickel(Ni),copper(Cu),and iron(Fe)-at chamber pressures ranging from 1 to 30 bar and oxidiser-to-fuel(O/F)ratios between 1.1 and 12,resulting in 1800 unique test conditions.The main performance parameters used to assess each formulation were characteristic velocity(C^(*))and adiabatic flame temperature.The results revealed that each test produced a different optimum O/F ratio,with most ratios falling between 4 and 6.The highest performance was achieved at a chamber pressure of 30 bar across all formulations.Among the additives,Al and B demonstrated significant potential for improved combustion performance with increasing metal loadings.In contrast,Fe,Cu,and Ni reached optimal performance at a minimum loading of 1%.Future work includes investigating B-Al metal composites as additives into the ABS base polymer fuel,and doing experimental validation tests where the metallised ABS polymer fuel is 3D printed.
文摘为了解决判别聚落群过于依赖考古专家人工划分的问题,以郑洛地区新石器时代聚落遗址为例,采用基于密度的DBSCAN(density-based spatial clustering of applications with noise)算法对聚落遗址进行空间聚类研究。通过对郑洛地区四个文化时期聚落遗址的分布分析,发现郑洛地区的主体聚落群从研究区东部的嵩山以南地区,转移到郑洛地区中部的伊洛河流域,并且在伊洛河流域长期定居下来,不断发展扩大;大型聚落遗址主要分布在主体聚落群里,除了裴李岗文化时期部分大型聚落较孤立;从仰韶文化后期到龙山文化时期,聚落遗址分布呈主从式环状分布格局;大多数聚落群的走向都和河流分布一致。研究表明,利用DBSCAN算法进行聚落遗址聚类是可行的,通过聚类得到郑洛地区新石器时代四个文化时期聚落遗址的分布特征。
文摘Manuel C.Molles Jr.所著的Ecology:Concepts and Applications(《生态学:概念与应用》)在教材与网络资源的建设方面进行了有益的尝试,其主教材及辅助教学资源的设计理念值得借鉴。主教材从1999年到2008年出版了4版,主教材内容及版本更新快,力求及时反映学科前沿水平的新技术、新知识;正文内容和版式编排设计以读者为本,注重为学生服务;网上辅助教学资源围绕主教材的系列产品进行整体设计,体现利教利学的建设理念,既为教师教学提供帮助和指导,也重视给予学生自我发挥的空间,网站展示条理清晰,内容布局规范,内容介绍注重以读者为中心,满足不同客户的需求。
