The complexes of zinc chloride and zinc nitrate with 2 amino 4,6 dimethyl pyrimidine (ADMP) were prepared through reflux in alcohol. The compositions of the complexes Zn(ADMP)2Cl2 (b) and Zn(ADMP)2(NO3)2·4H2O (c)...The complexes of zinc chloride and zinc nitrate with 2 amino 4,6 dimethyl pyrimidine (ADMP) were prepared through reflux in alcohol. The compositions of the complexes Zn(ADMP)2Cl2 (b) and Zn(ADMP)2(NO3)2·4H2O (c) were determined by chemical and elemental analyses. The complexes were characterized by IR, XPS, 1H NMR and TG DTG techniques. The constant volume combustion energies of ADMP and the complexes, ΔcE, were determined by a precise rotating bomb calorimeter at 298.15K. They were (-3664.53±1.18)kJ·mol-1, (-7130.94±3.69)kJ·mol-1, and (-7637.87±5.71)kJ·mol-1. Their standard enthalpies of combustion,, and standard enthalpies of formation, , were calculated. They were (-3666.39±1.18)kJ·mol-1, (-7129.70±3.69)kJ·mol-1, (-7632.91 ±5.71)kJ·mol-1 and (19.09±1.43)kJ·mol-1, (-411.96±4.03)kJ·mol-1, (-1153.28±6.02)kJ·mol-1.展开更多
The title compound 3 was synthesized from diethylguanidine nitrate（2） obtained from diethylamine, CaCN2 and HNO3. The mixture consisted of 0.5 mol 2, 0.55 mol acetonyl propionate, 3 g benzyltriethylammonium chloride...The title compound 3 was synthesized from diethylguanidine nitrate（2） obtained from diethylamine, CaCN2 and HNO3. The mixture consisted of 0.5 mol 2, 0.55 mol acetonyl propionate, 3 g benzyltriethylammonium chloride, and 44 g NaOH was refluxed for 4 hours to give 85 g 3, in yield 94.6%.展开更多
Synthesis steps of 4,5 diamino 6 hydroxy 2 mercaptopyrimidine were improved on cyclocondensation of ethyl cyanoacetate with thiourea,nitrosation and reduction to obtain the product in 89% yield with high purity on ind...Synthesis steps of 4,5 diamino 6 hydroxy 2 mercaptopyrimidine were improved on cyclocondensation of ethyl cyanoacetate with thiourea,nitrosation and reduction to obtain the product in 89% yield with high purity on industrial scale.展开更多
文摘The complexes of zinc chloride and zinc nitrate with 2 amino 4,6 dimethyl pyrimidine (ADMP) were prepared through reflux in alcohol. The compositions of the complexes Zn(ADMP)2Cl2 (b) and Zn(ADMP)2(NO3)2·4H2O (c) were determined by chemical and elemental analyses. The complexes were characterized by IR, XPS, 1H NMR and TG DTG techniques. The constant volume combustion energies of ADMP and the complexes, ΔcE, were determined by a precise rotating bomb calorimeter at 298.15K. They were (-3664.53±1.18)kJ·mol-1, (-7130.94±3.69)kJ·mol-1, and (-7637.87±5.71)kJ·mol-1. Their standard enthalpies of combustion,, and standard enthalpies of formation, , were calculated. They were (-3666.39±1.18)kJ·mol-1, (-7129.70±3.69)kJ·mol-1, (-7632.91 ±5.71)kJ·mol-1 and (19.09±1.43)kJ·mol-1, (-411.96±4.03)kJ·mol-1, (-1153.28±6.02)kJ·mol-1.
文摘The title compound 3 was synthesized from diethylguanidine nitrate（2） obtained from diethylamine, CaCN2 and HNO3. The mixture consisted of 0.5 mol 2, 0.55 mol acetonyl propionate, 3 g benzyltriethylammonium chloride, and 44 g NaOH was refluxed for 4 hours to give 85 g 3, in yield 94.6%.
文摘Synthesis steps of 4,5 diamino 6 hydroxy 2 mercaptopyrimidine were improved on cyclocondensation of ethyl cyanoacetate with thiourea,nitrosation and reduction to obtain the product in 89% yield with high purity on industrial scale.
基金2013年国家级大学生创新创业训练计划项目(201313256001)湖北师范学院硕士研究生创新科研基金项目(1051320130216)+1 种基金National Undergraduate Training Programs for Innovation and Entrepreneurship(201313256001)Postgraduate Innovation Scientific Research Foundation of Hubei Normal University(1051320130216)
