采用D314树脂从钼精矿焙烧淋洗液中回收钼,探讨了D314树脂加入量、吸附温度、溶液pH值等因素对吸附过程的影响。结果表明,在pH=4时,吸附容量最佳;钼吸附为吸热过程,提高吸附温度,有利于钼的吸附;钼的动态吸附和动态解吸均采用20 m L/h流...采用D314树脂从钼精矿焙烧淋洗液中回收钼,探讨了D314树脂加入量、吸附温度、溶液pH值等因素对吸附过程的影响。结果表明,在pH=4时,吸附容量最佳;钼吸附为吸热过程,提高吸附温度,有利于钼的吸附;钼的动态吸附和动态解吸均采用20 m L/h流速,钼吸附率为96.63%,解吸率为98.81%。红外测试结果表明,10%的氨水溶液可以有效解吸负载树脂上的钼。展开更多
Cr(Ⅵ) was quantitatively adsorbed by D201×4 resin with pH=2.63～3.66 in the medium of HAc NaAc.The statically saturated sorption capacity is 156.8mg/g·resin.The sorption rate constant is k 298 =1.80×10...Cr(Ⅵ) was quantitatively adsorbed by D201×4 resin with pH=2.63～3.66 in the medium of HAc NaAc.The statically saturated sorption capacity is 156.8mg/g·resin.The sorption rate constant is k 298 =1.80×10 -4 s -1 .The apparent sorption activation energy of APAR for Cr(Ⅵ) is 7.21kJ·mol -1 .The themodynamic parameters of sorption:enthalpy change ΔH,free energy change ΔG and entropy change ΔS of sorption (D201×4) for Cr(Ⅵ) are 33.12kJ·mol -1 ,-28.36kJ·mol -1 ,206.3J·mol -1 ·K -1 ,respectively.Coordination molar ratio of the functional group of D201×4 to Cr(Ⅵ) is 1∶1.Cr(Ⅵ) adsorbed on D201×4 can be reductively eluated by 5% NH 4Cl-10% NH 3·H 2O.The sorption rate of D201×4 for Cr(Ⅵ) is fast.The equilibrium time of adsorption is five hours.展开更多
文摘采用D314树脂从钼精矿焙烧淋洗液中回收钼,探讨了D314树脂加入量、吸附温度、溶液pH值等因素对吸附过程的影响。结果表明,在pH=4时,吸附容量最佳;钼吸附为吸热过程,提高吸附温度,有利于钼的吸附;钼的动态吸附和动态解吸均采用20 m L/h流速,钼吸附率为96.63%,解吸率为98.81%。红外测试结果表明,10%的氨水溶液可以有效解吸负载树脂上的钼。
文摘Cr(Ⅵ) was quantitatively adsorbed by D201×4 resin with pH=2.63～3.66 in the medium of HAc NaAc.The statically saturated sorption capacity is 156.8mg/g·resin.The sorption rate constant is k 298 =1.80×10 -4 s -1 .The apparent sorption activation energy of APAR for Cr(Ⅵ) is 7.21kJ·mol -1 .The themodynamic parameters of sorption:enthalpy change ΔH,free energy change ΔG and entropy change ΔS of sorption (D201×4) for Cr(Ⅵ) are 33.12kJ·mol -1 ,-28.36kJ·mol -1 ,206.3J·mol -1 ·K -1 ,respectively.Coordination molar ratio of the functional group of D201×4 to Cr(Ⅵ) is 1∶1.Cr(Ⅵ) adsorbed on D201×4 can be reductively eluated by 5% NH 4Cl-10% NH 3·H 2O.The sorption rate of D201×4 for Cr(Ⅵ) is fast.The equilibrium time of adsorption is five hours.
