Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic...Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.展开更多
Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influenc...Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influence of BCDOM on soil organisms has not been clearly explained.Hence,this review aims to discuss the factors affecting BCDOM and its interaction with soil substances including organic pollutants,heavy metals,and microorganisms.Results displayed that the quantity of BCDOM ranges from 0.17 to 37.03 mg/g,which was influenced by feedstock,preparation methods of biochar,and extraction methods.With the decrease in lignin content of feedstocks,carbonization temperature,and acidity of extraction solution,the content of BCDOM increased.Through complexation and adsorption,protein-like components in BCDOM interact with heavy metals,promoting the adsorption and immobilization of heavy metals onto biochar.Furthermore,BCDOM enhances the adsorption of organic pollutants by biochar throughπ−πinteractions,hydrogen bonding,and redox processes.More importantly,BCDOM promotes plant growth by enhancing microbial activities,providing nutrients,and improving soil properties.However,the transport and fate of BCDOM in soil have not been well studied,and more researches are needed to explore the interaction mechanisms between BCDOM and soil organisms.展开更多
Tin phosphide(Sn_(x)P_(y))is an anode for sodium-ion batteries resulting from its exceptionally high theoretical capacity in future.Nevertheless,its application will be hindered by significant volume expansion during ...Tin phosphide(Sn_(x)P_(y))is an anode for sodium-ion batteries resulting from its exceptionally high theoretical capacity in future.Nevertheless,its application will be hindered by significant volume expansion during charge discharge cycles and poor electrical conductivity.This study employs a Sn-based metal-organic framework(Sn-MOF)as a precursor for synthesizing tin phosphide nanoparticles.Then Solidago Canadensis L.,commonly known as Canadian Goldenrod,is utilized as a biomass carbon carrier to form a composite with tin phosphide nanoparticles.The biomass derived porous carbon provides additional sodium ion storage sites and serves as a structural scaffold that constrains the volumetric expansion of tin phosphide,thereby enhancing the material’s stability.The fabricated composite exhibits superior electrode electrochemical performance for sodium-ion batteries.It retains a high capacity(489.5 mA·h/g)after 100 cycles at 0.2 A/g.Even after 500 cycles at a high current density of 2 A/g,it still maintains a stable reversible capacity.This study offers a comprehensive exploration of innovative design strategies essential for the development of novel anode materials,paving the way for more sustainable and efficient sodium-ion-based energy storage systems.展开更多
Following the fundamental characteristics of the porosity windbreak,this study suggests a new numerical investigation method for the wind field of the windbreak based on the porous medium physical model.This method ca...Following the fundamental characteristics of the porosity windbreak,this study suggests a new numerical investigation method for the wind field of the windbreak based on the porous medium physical model.This method can transform the reasonable matching problem of the porosity and windproof performance of the windbreak into a study of the relationship between the resistance coefficient of the porous medium and the aerodynamic load of the train.This study examines the influence of the hole type on the wind field behind the porosity windbreak.Then,the relationship between the resistance coefficient of the porous medium,the porosity of the windbreak,and the aerodynamic loads of the train is investigated.The results show that the porous media physical model can be used instead of the windbreak geometry to study the windbreak-train aerodynamic performance,and the process of using this method is suggested.展开更多
文摘Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.
基金Project(2020YFC1908802)supported by the National Key Research and Development Project of China。
文摘Biochar-derived dissolved organic matter(BCDOM),an essential component of biochar,plays a vital role in regulating the physicochemical and biological properties of soils during biochar application.However,the influence of BCDOM on soil organisms has not been clearly explained.Hence,this review aims to discuss the factors affecting BCDOM and its interaction with soil substances including organic pollutants,heavy metals,and microorganisms.Results displayed that the quantity of BCDOM ranges from 0.17 to 37.03 mg/g,which was influenced by feedstock,preparation methods of biochar,and extraction methods.With the decrease in lignin content of feedstocks,carbonization temperature,and acidity of extraction solution,the content of BCDOM increased.Through complexation and adsorption,protein-like components in BCDOM interact with heavy metals,promoting the adsorption and immobilization of heavy metals onto biochar.Furthermore,BCDOM enhances the adsorption of organic pollutants by biochar throughπ−πinteractions,hydrogen bonding,and redox processes.More importantly,BCDOM promotes plant growth by enhancing microbial activities,providing nutrients,and improving soil properties.However,the transport and fate of BCDOM in soil have not been well studied,and more researches are needed to explore the interaction mechanisms between BCDOM and soil organisms.
文摘Tin phosphide(Sn_(x)P_(y))is an anode for sodium-ion batteries resulting from its exceptionally high theoretical capacity in future.Nevertheless,its application will be hindered by significant volume expansion during charge discharge cycles and poor electrical conductivity.This study employs a Sn-based metal-organic framework(Sn-MOF)as a precursor for synthesizing tin phosphide nanoparticles.Then Solidago Canadensis L.,commonly known as Canadian Goldenrod,is utilized as a biomass carbon carrier to form a composite with tin phosphide nanoparticles.The biomass derived porous carbon provides additional sodium ion storage sites and serves as a structural scaffold that constrains the volumetric expansion of tin phosphide,thereby enhancing the material’s stability.The fabricated composite exhibits superior electrode electrochemical performance for sodium-ion batteries.It retains a high capacity(489.5 mA·h/g)after 100 cycles at 0.2 A/g.Even after 500 cycles at a high current density of 2 A/g,it still maintains a stable reversible capacity.This study offers a comprehensive exploration of innovative design strategies essential for the development of novel anode materials,paving the way for more sustainable and efficient sodium-ion-based energy storage systems.
基金Projects(52302447,52388102,52372369)supported by the National Natural Science Foundation of China。
文摘Following the fundamental characteristics of the porosity windbreak,this study suggests a new numerical investigation method for the wind field of the windbreak based on the porous medium physical model.This method can transform the reasonable matching problem of the porosity and windproof performance of the windbreak into a study of the relationship between the resistance coefficient of the porous medium and the aerodynamic load of the train.This study examines the influence of the hole type on the wind field behind the porosity windbreak.Then,the relationship between the resistance coefficient of the porous medium,the porosity of the windbreak,and the aerodynamic loads of the train is investigated.The results show that the porous media physical model can be used instead of the windbreak geometry to study the windbreak-train aerodynamic performance,and the process of using this method is suggested.
