Thermogravimetric study of rubber compositions (operating glove and catheter) in medical waste was carried out using the thermogravimetric analyser (TGA),at the heating rate of 20 ℃/min in a stream of N2.The resu...Thermogravimetric study of rubber compositions (operating glove and catheter) in medical waste was carried out using the thermogravimetric analyser (TGA),at the heating rate of 20 ℃/min in a stream of N2.The results indicate that the decomposition process of operating glove appears an obvious mass loss stage at 250-485 ℃,while catheter has two obvious stages at 240-510 ℃ and 655-800 ℃,respectively; both samples present endothermic pyrolysis reaction; the decomposition of operating glove and the first mass loss stage of catheter are in agreement with natural rubber pyrolysis; the second mass loss stage of catheter corresponds to CaCO3 decomposition.Based on the experimental results,a novel two-step four-reaction model was established to simulate the whole continuous processes,which could more satisfactorily describe and predict the pyrolysis processes of rubber compositions,being more mechanistic and conveniently serving for the engineering.展开更多
This article concentrates on the properties of three-dimensional magneto-hydrodynamic flow of a viscous fluid saturated with Darcy porous medium deformed by a nonlinear variable thickened surface.Analysis of flow is d...This article concentrates on the properties of three-dimensional magneto-hydrodynamic flow of a viscous fluid saturated with Darcy porous medium deformed by a nonlinear variable thickened surface.Analysis of flow is disclosed in the neighborhood of stagnation point.Features of heat transport are characterized with Newtonian heating and variable thermal conductivity.Mass transport is carried out with first order chemical reaction and variable mass diffusivity.Resulting governing equations are transformed by implementation of appropriate transformations.Analytical convergent series solutions are computed via homotopic technique.Physical aspects of numerous parameters are discussed through graphical data.Drag force coefficient,Sherwood and Nusselt numbers are illustrated through graphs corresponding to various pertinent parameters.Graphical discussion reveals that conjugate and constructive chemical reaction parameters enhance the temperature and concentration distributions,respectively.展开更多
In this study,Al-65V alloy has been produced by electrode heating for 3−15 min.The impurities content,microstructure and the vanadium content of the alloy in the slag are investigated.The results indicate that differe...In this study,Al-65V alloy has been produced by electrode heating for 3−15 min.The impurities content,microstructure and the vanadium content of the alloy in the slag are investigated.The results indicate that different heating time shows obviously impacts not only on the impurities and microstructure of AlV alloy,but also on the vanadium recovery rate of slag.The impurities contents of C,O and N are 0.085%,0.022%and 0.036%,respectively,which meet the commercial standard when the electric heating time is controlled to 10 min,and the content of vanadium in slag is 0.18%.展开更多
基金Project(50378062)supported by the National Natural Science Foundation of ChinaProject(09JCYBJC08100)supported by the Natural Science Foundation of Tianjin Municipality,ChinaProject supported by Key Laboratory Program of the Ministry of Education,China
文摘Thermogravimetric study of rubber compositions (operating glove and catheter) in medical waste was carried out using the thermogravimetric analyser (TGA),at the heating rate of 20 ℃/min in a stream of N2.The results indicate that the decomposition process of operating glove appears an obvious mass loss stage at 250-485 ℃,while catheter has two obvious stages at 240-510 ℃ and 655-800 ℃,respectively; both samples present endothermic pyrolysis reaction; the decomposition of operating glove and the first mass loss stage of catheter are in agreement with natural rubber pyrolysis; the second mass loss stage of catheter corresponds to CaCO3 decomposition.Based on the experimental results,a novel two-step four-reaction model was established to simulate the whole continuous processes,which could more satisfactorily describe and predict the pyrolysis processes of rubber compositions,being more mechanistic and conveniently serving for the engineering.
文摘This article concentrates on the properties of three-dimensional magneto-hydrodynamic flow of a viscous fluid saturated with Darcy porous medium deformed by a nonlinear variable thickened surface.Analysis of flow is disclosed in the neighborhood of stagnation point.Features of heat transport are characterized with Newtonian heating and variable thermal conductivity.Mass transport is carried out with first order chemical reaction and variable mass diffusivity.Resulting governing equations are transformed by implementation of appropriate transformations.Analytical convergent series solutions are computed via homotopic technique.Physical aspects of numerous parameters are discussed through graphical data.Drag force coefficient,Sherwood and Nusselt numbers are illustrated through graphs corresponding to various pertinent parameters.Graphical discussion reveals that conjugate and constructive chemical reaction parameters enhance the temperature and concentration distributions,respectively.
基金Project(51734006)supported by the National Natural Science Foundation of ChinaProject(2014HA003)supported by the Cultivating Plan Program for the Leader in Science and Technology of Yunnan Province of China+1 种基金Project(2017HB009)supported by the Science and Technological Talent Cultivation Plan of Yunnan Province,ChinaProject(2017HA006)supported by the Program for the Academician Free Exploration Fund of Yunnan Province,China
文摘In this study,Al-65V alloy has been produced by electrode heating for 3−15 min.The impurities content,microstructure and the vanadium content of the alloy in the slag are investigated.The results indicate that different heating time shows obviously impacts not only on the impurities and microstructure of AlV alloy,but also on the vanadium recovery rate of slag.The impurities contents of C,O and N are 0.085%,0.022%and 0.036%,respectively,which meet the commercial standard when the electric heating time is controlled to 10 min,and the content of vanadium in slag is 0.18%.