Two-dimensional Ruddlesden-Popper(2DRP)perovskite exhibits excellent stability in perovskite solar cells(PSCs)due to introducing hydrophobic long-chain organic spacers.However,the poor charge transporting property of ...Two-dimensional Ruddlesden-Popper(2DRP)perovskite exhibits excellent stability in perovskite solar cells(PSCs)due to introducing hydrophobic long-chain organic spacers.However,the poor charge transporting property of bulky organic cation spacers limits the performance of 2DRP PSCs.Inspired by the Asite cation alloying strategy in 3D perovskites,2DRP perovskites with a binary spacer can promote charge transporting compared to the unary spacer counterparts.Herein,the superior MA-based 2DRP perovskite films with a binary spacer,including 3-guanidinopropanoic acid(GPA)and 4-fluorophenethylamine(FPEA)are realized.These films(GPA_(0.85)FPEA_(0.15))_(2)MA_(4)Pb_5I_(16)show good morphology,large grain size,decreased trap state density,and preferential orientation of the as-prepared film.Accordingly,the present 2DRP-based PSC with the binary spacer achieves a remarkable efficiency of 18.37%with a V_(OC)of1.15 V,a J_(SC)of 20.13 mA cm^(-2),and an FF of 79.23%.To our knowledge,the PCE value should be the highest for binary spacer MA-based 2DRP(n≤5)PSCs to date.Importantly,owing to the hydrophobic fluorine group of FPEA and the enhanced interlayer interaction by FPEA,the unencapsulated 2DRP PSCs based on binary spacers exhibit much excellent humidity stability and thermal stability than the unary spacer counterparts.展开更多
Based on detailed analysis of advantages and disadvantages of the existing connected-component labeling （CCL） algorithm,a new algorithm for binary connected components labeling based on run-length encoding （RLE） a...Based on detailed analysis of advantages and disadvantages of the existing connected-component labeling （CCL） algorithm,a new algorithm for binary connected components labeling based on run-length encoding （RLE） and union-find sets has been put forward.The new algorithm uses RLE as the basic processing unit,converts the label merging of connected RLE into sets grouping in accordance with equivalence relation,and uses the union-find sets which is the realization method of sets grouping to solve the label merging of connected RLE.And the label merging procedure has been optimized：the union operation has been modified by adding the ＂weighted rule＂ to avoid getting a degenerated-tree,and the ＂path compression＂ has been adopted when implementing the find operation,then the time complexity of label merging is O（nα（n））.The experiments show that the new algorithm can label the connected components of any shapes very quickly and exactly,save more memory,and facilitate the subsequent image analysis.展开更多
基金financially supported by the Natural Science Foundation of China(Grant Nos.52372226,52173263,62004167)the Natural Science Basic Research Plan in Shaanxi Province of China(Grant Nos.2022JM-315,2023-JC-QN-0643)+4 种基金the National Key R&D Program of China(Grant No.2022YFB3603703)the Qinchuangyuan High-level Talent Project of Shaanxi(Grant No.QCYRCXM-2022-219)the Ningbo Natural Science Foundation(Grant No.2022J061)the Key Research and Development Program of Shaanxi(Grant No.2023GXLH-091)the Shccig-Qinling Program and the Fundamental Research Funds for the Central Universities。
文摘Two-dimensional Ruddlesden-Popper(2DRP)perovskite exhibits excellent stability in perovskite solar cells(PSCs)due to introducing hydrophobic long-chain organic spacers.However,the poor charge transporting property of bulky organic cation spacers limits the performance of 2DRP PSCs.Inspired by the Asite cation alloying strategy in 3D perovskites,2DRP perovskites with a binary spacer can promote charge transporting compared to the unary spacer counterparts.Herein,the superior MA-based 2DRP perovskite films with a binary spacer,including 3-guanidinopropanoic acid(GPA)and 4-fluorophenethylamine(FPEA)are realized.These films(GPA_(0.85)FPEA_(0.15))_(2)MA_(4)Pb_5I_(16)show good morphology,large grain size,decreased trap state density,and preferential orientation of the as-prepared film.Accordingly,the present 2DRP-based PSC with the binary spacer achieves a remarkable efficiency of 18.37%with a V_(OC)of1.15 V,a J_(SC)of 20.13 mA cm^(-2),and an FF of 79.23%.To our knowledge,the PCE value should be the highest for binary spacer MA-based 2DRP(n≤5)PSCs to date.Importantly,owing to the hydrophobic fluorine group of FPEA and the enhanced interlayer interaction by FPEA,the unencapsulated 2DRP PSCs based on binary spacers exhibit much excellent humidity stability and thermal stability than the unary spacer counterparts.
文摘Based on detailed analysis of advantages and disadvantages of the existing connected-component labeling （CCL） algorithm,a new algorithm for binary connected components labeling based on run-length encoding （RLE） and union-find sets has been put forward.The new algorithm uses RLE as the basic processing unit,converts the label merging of connected RLE into sets grouping in accordance with equivalence relation,and uses the union-find sets which is the realization method of sets grouping to solve the label merging of connected RLE.And the label merging procedure has been optimized：the union operation has been modified by adding the ＂weighted rule＂ to avoid getting a degenerated-tree,and the ＂path compression＂ has been adopted when implementing the find operation,then the time complexity of label merging is O（nα（n））.The experiments show that the new algorithm can label the connected components of any shapes very quickly and exactly,save more memory,and facilitate the subsequent image analysis.
