Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.Th...Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.This research,for the first time,conducted a comprehensive optimization design and comparative analysis of three compact LIBS system optical paths:the paraxial optical path(OP),the off-axis OP,and the reflective OP.The differences in spectral intensity and stability among these paths were revealed,providing a scientific basis for selecting the optimal OP for LIBS systems.The research found that the paraxial OP excels in spectral performance and quantitative analysis accuracy,making it the preferred choice for compact LIBS systems.Specifically,the paraxial OP significantly enhances spectral intensity,achieving a 6 times improvement over the off-axis OP and an even more remarkable 150 times increase compared to the reflective OP,greatly enhancing detection sensitivity.Additionally,the relative standard deviation,spectral stability index,maintains a consistently low level,ranging from 10.9%to 13.4%,significantly outperforming the other two OPs and ensuring the reliability of analytical results.In the field of quantitative analysis,the paraxial OP also demonstrates higher accuracy,precision,and sensitivity,comparing to other OPs.The quantitative analysis models for Si,Cu,and Ti elements exhibit excellent fitting,providing users with high-quality quantitative analysis results that are of great significance for applications in material science,environmental monitoring,industrial inspection,and other fields.In summary,this study not only confirms the enormous application potential of the paraxial OP in compact LIBS systems but also provides valuable practical experience and theoretical support for the miniaturization and integration of LIBS systems.Looking ahead,with continuous technological advancements,the design of the paraxial OP is expected to further propel the widespread adoption of LIBS technology in portable,on-site detection applications.展开更多
Pulse echo accumulation is commonly employed in coherent Doppler wind LiDAR(light detection and ranging)under the assumption of steady wind.Here,the measured spectral data are analyzed in the time dimension and freque...Pulse echo accumulation is commonly employed in coherent Doppler wind LiDAR(light detection and ranging)under the assumption of steady wind.Here,the measured spectral data are analyzed in the time dimension and frequency dimension to cope with the temporal wind shear and achieve the optimal accumulation time.A hardware-efficient algorithm combining the interpolation and cross-correlation is used to enhance the wind retrieval accuracy by reducing the frequency sampling interval and then reduce the spectral width calculation error.Moreover,the temporal broadening effect and spatial broadening effect are decoupled according to the strategy we developed.展开更多
Fatigue failure has long been an important issue for ships and offshore structures. Among the numerous methods for predicting fatigue life, the spectral method is accepted as the most reliable. Although the theory beh...Fatigue failure has long been an important issue for ships and offshore structures. Among the numerous methods for predicting fatigue life, the spectral method is accepted as the most reliable. Although the theory behind spectral analysis is straight-forward, the analysis itself is complicated and time-consuming because it is closely related to critical technical details such as the application of fatigue loading (wave pressures and the inertial forces due to cargoes), the extraction of the stress, and the calculation of stress RAO. Here, four key technical details-loading application, displacement boundary condition, the calculation of stress RAO, and the extraction of the fatigue stress-are discussed thoroughly. For each aspect, a resolution is presented based on the finite element pre-and post-processing software MSC/PATRAN or FE solver MSC/NASTRAN. The resolutions are effective and efficient, which can help engineers perform spectral fatigue analysis accurately and faster.展开更多
The application of ti me-series modeling and forecasting method to the spectral analysis for lubricat ing oil of mechanical equipment is discussed. The AR model is used to perform a time-series modeling and forecasti...The application of ti me-series modeling and forecasting method to the spectral analysis for lubricat ing oil of mechanical equipment is discussed. The AR model is used to perform a time-series modeling and forecasting analysis for the spectral analysis data co llected from aero-engines. In the oil condition monitoring field of mechanical equipment, the use of the method of time-series analysis has rarely been report ed. As indicated in the satisfactory example, a practical method for condition m onitoring and fault forecasting of mechanical equipment has been achieved.展开更多
In order to obtain the elemental compositions of the projectile and target materials during 2A12 aluminum projectile shot on a natural dolomite plate, three kinds of experiments have been conducted using a spectral ac...In order to obtain the elemental compositions of the projectile and target materials during 2A12 aluminum projectile shot on a natural dolomite plate, three kinds of experiments have been conducted using a spectral acquirement system established on a two-stage light gas gun for impact velocities ranging from 2.20 km/s to 4.20 km/s, at the same projectile incidence angle of 30°. Experimental results show that the elemental compositions of the projectile and target materials in the strong shock experiments have a good agreement with the original elemental compositions of the projectile and target. In addition, the relations between spectral radiant intensity and elemental compositions of the projectile and target materials have been obtained for different impact velocities, in which the spectral radiant intensity of the main elements in the material increases with increasing impact velocity, and more elements appear with increasing impact velocity since more energy would result from a higher velocity impact.展开更多
We used a weather research and forecasting model to simulate a torrential rainstorm that occurred in Xinjiang,China during June 16–17,2016.The model successfully simulated the rainfall area,precipitation intensity,an...We used a weather research and forecasting model to simulate a torrential rainstorm that occurred in Xinjiang,China during June 16–17,2016.The model successfully simulated the rainfall area,precipitation intensity,and changes in precipitation.We identified a clear wave signal using the two-dimensional fast Fourier transform method;the waves propagated westwards,with wavelengths of 45–20 km,periods of 50–120 min,and phase velocities mainly concentrated in the-25 m/s to-10 m/s range.The results of wavelet cross-spectral analysis further confirmed that the waves were gravity waves,peaking at 11:00 UTC,June 17,2016.The gravity wave signal was identified along 79.17–79.93°E,81.35–81.45°E and 81.5–81.83°E.The gravity waves detected along 81.5–81.83°E corresponded well with precipitation that accumulated in 1 h,indicating that gravity waves could be considered a rainstorm precursor in future precipitation forecasts.展开更多
Although laser-induced breakdown spectroscopy(LIBS),as a fast on-line analysis technology,has great potential and competitiveness in the analysis of chemical composition and proximate analysis results of coal in therm...Although laser-induced breakdown spectroscopy(LIBS),as a fast on-line analysis technology,has great potential and competitiveness in the analysis of chemical composition and proximate analysis results of coal in thermal power plants,the measurement repeatability of LIBS needs to be further improved due to the difficulty in controlling the stability of the generated plasmas at present.In this paper,we propose a novel x-ray fluorescence(XRF) assisted LIBS method for high repeatability analysis of coal quality,which not only inherits the ability of LIBS to directly analyze organic elements such as C and H in coal,but also uses XRF to make up for the lack of stability of LIBS in determining other inorganic ash-forming elements.With the combination of elemental lines in LIBS and XRF spectra,the principal component analysis and the partial least squares are used to establish the prediction model and perform multi-elemental and proximate analysis of coal.Quantitative analysis results show that the relative standard deviation(RSD) of C is 0.15%,the RSDs of other elements are less than 4%,and the standard deviations of calorific value,ash content,sulfur content and volatile matter are 0.11 MJ kg,0.17%,0.79% and 0.41%respectively,indicating that the method has good repeatability in determination of coal quality.This work is helpful to accelerate the development of LIBS in the field of rapid measurement of coal entering the power plant and on-line monitoring of coal entering the furnace.展开更多
Spatio-temporal assessment of the above ground biomass （AGB） is a cumbersome task due to the difficulties associated with the measurement of different tree parameters such as girth at breast height and height of tre...Spatio-temporal assessment of the above ground biomass （AGB） is a cumbersome task due to the difficulties associated with the measurement of different tree parameters such as girth at breast height and height of trees. The present research was conducted in the campus of Birla Institute of Technology, Mesra, Ranchi, India, which is predomi- nantly covered by Sal （Shorea robusta C. F. Gaertn）. Two methods of regression analysis was employed to determine the potential of remote sensing parameters with the AGB measured in the field such as linear regression analysis between the AGB and the individual bands, principal components （PCs） of the bands, vegetation indices （VI）, and the PCs of the VIs respectively and multiple linear regression （MLR） analysis be- tween the AGB and all the variables in each category of data. From the linear regression analysis, it was found that only the NDVI exhibited regression coefficient value above 0.80 with the remaining parameters showing very low values. On the other hand, the MLR based analysis revealed significantly improved results as evidenced by the occurrence of very high correlation coefficient values of greater than 0.90 determined between the computed AGB from the MLR equations and field-estimated AGB thereby ascertaining their superiority in providing reliable estimates of AGB. The highest correlation coefficient of 0.99 is found with the MLR involving PCs of VIs.展开更多
Energy resolution calibration is crucial for gamma-ray spectral analysis,as measured using a scintillation detector.A locally constrained regularization method was proposed to determine the resolution calibration para...Energy resolution calibration is crucial for gamma-ray spectral analysis,as measured using a scintillation detector.A locally constrained regularization method was proposed to determine the resolution calibration parameters.First,a Monte Carlo simulation model consistent with an actual measurement system was constructed to obtain the energy deposition distribution in the scintillation crystal.Subsequently,the regularization objective function is established based on weighted least squares and additional constraints.Additional constraints were designed using a special weighting scheme based on the incident gamma-ray energies.Subsequently,an intelligent algorithm was introduced to search for the optimal resolution calibration parameters by minimizing the objective function.The most appropriate regularization parameter was determined through mathematical experiments.When the regularization parameter was 30,the calibrated results exhibited the minimum RMSE.Simulations and test pit experiments were conducted to verify the performance of the proposed method.The simulation results demonstrate that the proposed algorithm can determine resolution calibration parameters more accurately than the traditional weighted least squares,and the test pit experimental results show that the R-squares between the calibrated and measured spectra are larger than 0.99.The accurate resolution calibration parameters determined by the proposed method lay the foundation for gamma-ray spectral processing and simulation benchmarking.展开更多
基金financially supported by National Natural Science Foundation of China (Nos.62305392 and 62305123)Independent Research and Development Project of Naval Engineering University (No.2023504050)the Nursery Plan Project of Navel University of Engineering (2022)。
文摘Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.This research,for the first time,conducted a comprehensive optimization design and comparative analysis of three compact LIBS system optical paths:the paraxial optical path(OP),the off-axis OP,and the reflective OP.The differences in spectral intensity and stability among these paths were revealed,providing a scientific basis for selecting the optimal OP for LIBS systems.The research found that the paraxial OP excels in spectral performance and quantitative analysis accuracy,making it the preferred choice for compact LIBS systems.Specifically,the paraxial OP significantly enhances spectral intensity,achieving a 6 times improvement over the off-axis OP and an even more remarkable 150 times increase compared to the reflective OP,greatly enhancing detection sensitivity.Additionally,the relative standard deviation,spectral stability index,maintains a consistently low level,ranging from 10.9%to 13.4%,significantly outperforming the other two OPs and ensuring the reliability of analytical results.In the field of quantitative analysis,the paraxial OP also demonstrates higher accuracy,precision,and sensitivity,comparing to other OPs.The quantitative analysis models for Si,Cu,and Ti elements exhibit excellent fitting,providing users with high-quality quantitative analysis results that are of great significance for applications in material science,environmental monitoring,industrial inspection,and other fields.In summary,this study not only confirms the enormous application potential of the paraxial OP in compact LIBS systems but also provides valuable practical experience and theoretical support for the miniaturization and integration of LIBS systems.Looking ahead,with continuous technological advancements,the design of the paraxial OP is expected to further propel the widespread adoption of LIBS technology in portable,on-site detection applications.
基金Project supported by the Shanghai Science and Technology Innovation Action(Grant No.22dz1208700).
文摘Pulse echo accumulation is commonly employed in coherent Doppler wind LiDAR(light detection and ranging)under the assumption of steady wind.Here,the measured spectral data are analyzed in the time dimension and frequency dimension to cope with the temporal wind shear and achieve the optimal accumulation time.A hardware-efficient algorithm combining the interpolation and cross-correlation is used to enhance the wind retrieval accuracy by reducing the frequency sampling interval and then reduce the spectral width calculation error.Moreover,the temporal broadening effect and spatial broadening effect are decoupled according to the strategy we developed.
文摘Fatigue failure has long been an important issue for ships and offshore structures. Among the numerous methods for predicting fatigue life, the spectral method is accepted as the most reliable. Although the theory behind spectral analysis is straight-forward, the analysis itself is complicated and time-consuming because it is closely related to critical technical details such as the application of fatigue loading (wave pressures and the inertial forces due to cargoes), the extraction of the stress, and the calculation of stress RAO. Here, four key technical details-loading application, displacement boundary condition, the calculation of stress RAO, and the extraction of the fatigue stress-are discussed thoroughly. For each aspect, a resolution is presented based on the finite element pre-and post-processing software MSC/PATRAN or FE solver MSC/NASTRAN. The resolutions are effective and efficient, which can help engineers perform spectral fatigue analysis accurately and faster.
文摘The application of ti me-series modeling and forecasting method to the spectral analysis for lubricat ing oil of mechanical equipment is discussed. The AR model is used to perform a time-series modeling and forecasting analysis for the spectral analysis data co llected from aero-engines. In the oil condition monitoring field of mechanical equipment, the use of the method of time-series analysis has rarely been report ed. As indicated in the satisfactory example, a practical method for condition m onitoring and fault forecasting of mechanical equipment has been achieved.
基金supported by National Natural Science Foundation of China(Nos.11272218,11472178)State Key Program of National Natural Science of China(No.11032003)Program for Liaoning Excellent Talents in University of China(No.LR2013008)
文摘In order to obtain the elemental compositions of the projectile and target materials during 2A12 aluminum projectile shot on a natural dolomite plate, three kinds of experiments have been conducted using a spectral acquirement system established on a two-stage light gas gun for impact velocities ranging from 2.20 km/s to 4.20 km/s, at the same projectile incidence angle of 30°. Experimental results show that the elemental compositions of the projectile and target materials in the strong shock experiments have a good agreement with the original elemental compositions of the projectile and target. In addition, the relations between spectral radiant intensity and elemental compositions of the projectile and target materials have been obtained for different impact velocities, in which the spectral radiant intensity of the main elements in the material increases with increasing impact velocity, and more elements appear with increasing impact velocity since more energy would result from a higher velocity impact.
基金Project supported by China Special Fund for Meteorological Research in the Public Interest(Grant No.GYHY201406002)the National Natural Science Foundation of China(Grant Nos.41575065 and 41405049)+1 种基金the National Natural Science Foundation International Cooperation Project,China(Grant No.41661144024)Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA17010100)
文摘We used a weather research and forecasting model to simulate a torrential rainstorm that occurred in Xinjiang,China during June 16–17,2016.The model successfully simulated the rainfall area,precipitation intensity,and changes in precipitation.We identified a clear wave signal using the two-dimensional fast Fourier transform method;the waves propagated westwards,with wavelengths of 45–20 km,periods of 50–120 min,and phase velocities mainly concentrated in the-25 m/s to-10 m/s range.The results of wavelet cross-spectral analysis further confirmed that the waves were gravity waves,peaking at 11:00 UTC,June 17,2016.The gravity wave signal was identified along 79.17–79.93°E,81.35–81.45°E and 81.5–81.83°E.The gravity waves detected along 81.5–81.83°E corresponded well with precipitation that accumulated in 1 h,indicating that gravity waves could be considered a rainstorm precursor in future precipitation forecasts.
基金supported by National Energy R&D Center of Petroleum Refining Technology of China(RIPP,SINOPEC)National Key Research and Development Program of China(No.2017YFA0304203)+5 种基金Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China(No.IRT_17R70)National Natural Science Foundation of China(Nos.61975103,61875108,61775125 and 11434007)Industrial Application Innovation Project(No.627010407)Scientific and Technological Innovation Project of Shanxi Gemeng US-China Clean Energy R&D Center Co.,Ltd111 Project(D18001)Fund for Shanxi‘1331KSC’。
文摘Although laser-induced breakdown spectroscopy(LIBS),as a fast on-line analysis technology,has great potential and competitiveness in the analysis of chemical composition and proximate analysis results of coal in thermal power plants,the measurement repeatability of LIBS needs to be further improved due to the difficulty in controlling the stability of the generated plasmas at present.In this paper,we propose a novel x-ray fluorescence(XRF) assisted LIBS method for high repeatability analysis of coal quality,which not only inherits the ability of LIBS to directly analyze organic elements such as C and H in coal,but also uses XRF to make up for the lack of stability of LIBS in determining other inorganic ash-forming elements.With the combination of elemental lines in LIBS and XRF spectra,the principal component analysis and the partial least squares are used to establish the prediction model and perform multi-elemental and proximate analysis of coal.Quantitative analysis results show that the relative standard deviation(RSD) of C is 0.15%,the RSDs of other elements are less than 4%,and the standard deviations of calorific value,ash content,sulfur content and volatile matter are 0.11 MJ kg,0.17%,0.79% and 0.41%respectively,indicating that the method has good repeatability in determination of coal quality.This work is helpful to accelerate the development of LIBS in the field of rapid measurement of coal entering the power plant and on-line monitoring of coal entering the furnace.
文摘Spatio-temporal assessment of the above ground biomass （AGB） is a cumbersome task due to the difficulties associated with the measurement of different tree parameters such as girth at breast height and height of trees. The present research was conducted in the campus of Birla Institute of Technology, Mesra, Ranchi, India, which is predomi- nantly covered by Sal （Shorea robusta C. F. Gaertn）. Two methods of regression analysis was employed to determine the potential of remote sensing parameters with the AGB measured in the field such as linear regression analysis between the AGB and the individual bands, principal components （PCs） of the bands, vegetation indices （VI）, and the PCs of the VIs respectively and multiple linear regression （MLR） analysis be- tween the AGB and all the variables in each category of data. From the linear regression analysis, it was found that only the NDVI exhibited regression coefficient value above 0.80 with the remaining parameters showing very low values. On the other hand, the MLR based analysis revealed significantly improved results as evidenced by the occurrence of very high correlation coefficient values of greater than 0.90 determined between the computed AGB from the MLR equations and field-estimated AGB thereby ascertaining their superiority in providing reliable estimates of AGB. The highest correlation coefficient of 0.99 is found with the MLR involving PCs of VIs.
基金supported by the National Natural Science Foundation of China(No.41804141)。
文摘Energy resolution calibration is crucial for gamma-ray spectral analysis,as measured using a scintillation detector.A locally constrained regularization method was proposed to determine the resolution calibration parameters.First,a Monte Carlo simulation model consistent with an actual measurement system was constructed to obtain the energy deposition distribution in the scintillation crystal.Subsequently,the regularization objective function is established based on weighted least squares and additional constraints.Additional constraints were designed using a special weighting scheme based on the incident gamma-ray energies.Subsequently,an intelligent algorithm was introduced to search for the optimal resolution calibration parameters by minimizing the objective function.The most appropriate regularization parameter was determined through mathematical experiments.When the regularization parameter was 30,the calibrated results exhibited the minimum RMSE.Simulations and test pit experiments were conducted to verify the performance of the proposed method.The simulation results demonstrate that the proposed algorithm can determine resolution calibration parameters more accurately than the traditional weighted least squares,and the test pit experimental results show that the R-squares between the calibrated and measured spectra are larger than 0.99.The accurate resolution calibration parameters determined by the proposed method lay the foundation for gamma-ray spectral processing and simulation benchmarking.
