To develop a cleaner production process of H2O2-based chlorine dioxide, this paper presents a study on reaction mechanism and dynamics of the process.It is shown that a complex H2ClO2-ClO 3 exists as an intermediate i...To develop a cleaner production process of H2O2-based chlorine dioxide, this paper presents a study on reaction mechanism and dynamics of the process.It is shown that a complex H2ClO2-ClO 3 exists as an intermediate in the process.A rational reaction process is proposed, which unifies several reaction mechanisms reported by different researchers in a wider range of reaction temperature.A theoretical model of the dynamics is presented, and parameters of the model are experimentally estimated and verified.展开更多
文摘To develop a cleaner production process of H2O2-based chlorine dioxide, this paper presents a study on reaction mechanism and dynamics of the process.It is shown that a complex H2ClO2-ClO 3 exists as an intermediate in the process.A rational reaction process is proposed, which unifies several reaction mechanisms reported by different researchers in a wider range of reaction temperature.A theoretical model of the dynamics is presented, and parameters of the model are experimentally estimated and verified.
