To prepare a highly efficient NiMo/Al_(2)O_(3) hydrodesulfurization catalyst,the combined effects of specific organic functional groups and alumina surface characteristics were investigated.First,the correlation betwe...To prepare a highly efficient NiMo/Al_(2)O_(3) hydrodesulfurization catalyst,the combined effects of specific organic functional groups and alumina surface characteristics were investigated.First,the correlation between the surface characteristics of four different alumina and the existing Mo species states was established.It was found that the Mo equilibrium adsorption capacity can be used as a specific descriptor to quantitatively evaluate the changes in surface characteristics of different alumina.A lower Mo equilibrium adsorption capacity for alumina means weaker metal-support interaction and the loaded Mo species are easier to transform into MoS2.However,the Mo-O-Al bonds still exist at the metal-support interface.The introduction of cationic surfactant hecadecyl trimethyl ammonium bromide(CTAB)can further improve Mo species dispersion through electrostatic attraction with Mo anions and interaction of its alkyl chain with the alumina surface;meanwhile,the introduction of ethylenediamine tetraacetic acid(EDTA)can complex with Ni ions to enhance the Ni-promoting effect on Mo.Therefore,the NiMo catalyst designed using alumina with lower Mo equilibrium adsorption capacity and the simultaneous addition of EDTA and CTAB exhibits the highest hydrodesulfurization activity for 4,6-dimethyl dibenzothiophene because of its proper metal-support interaction and more well-dispersed Ni-Mo-S active phases.展开更多
A subgroup H of a group G is called F-z-supplemented in G if there exists a subgroup K of G, such that G = HK and H∩K≤ Z∞F（G）, where Z∞F（G） is the F-hypercenter of G. We obtain some results about the F-z-suppl...A subgroup H of a group G is called F-z-supplemented in G if there exists a subgroup K of G, such that G = HK and H∩K≤ Z∞F（G）, where Z∞F（G） is the F-hypercenter of G. We obtain some results about the F-z-supplemented subgroups and use them to determine the structure of some groups.展开更多
Anthropogenic disturbances are widespread in tropical forests and influence the species composition in the overstory.However,the impacts of historical disturbance on tropical forest overstory recovery are unclear due ...Anthropogenic disturbances are widespread in tropical forests and influence the species composition in the overstory.However,the impacts of historical disturbance on tropical forest overstory recovery are unclear due to a lack of disturbance data,and previous studies have focused on understory species.In this study,the purpose was to deter-mine the influence of historical disturbance on the diver-sity,composition and regeneration of overstory species in present forests.In the 20-ha Xishuangbanna tropical sea-sonal rainforest dynamics plot in southwestern China,the historical disturbance boundaries were delineated based on panchromatic photographs from 1965.Factors that drove species clustering in the overstory layer(DBH≥40 cm)were analyzed and the abundance,richness and composition of these species were compared among different tree groups based on multiple regression tree analysis.The coefficient of variation of the brightness value in historical panchro-matic photographs from 1965 was the primary driver of spe-cies clustering in the overstory layer.The abundance and richness of overstory species throughout the regeneration process were similar,but species composition was always different.Although the proportion of large-seeded and vigorous-sprouting species showed no significant differ-ence between disturbed and undisturbed forests in the tree-let layer(DBH<20 cm),the difference became significant when DBH increased.The findings highlight that historical disturbances have strong legacy effects on functional group composition in the overstory and the recovery of overstory species was multidimensional.Functional group composi-tion can better indicate the dynamics of overstory species replacement during secondary succession.展开更多
All parabolic subgroups and Borel subgroups of PΩ（2m ＋ 1, F） over a linearable field F of characteristic 0 are shown to be complete groups, provided m 〉 3.
Tuning the coordination atoms of central metal is an effective means to improve the electrocatalytic activity of atomic catalysts.Herein,iridium(Ir) is proposed to be asymmetrically anchored by sp-N and pyridinic N of...Tuning the coordination atoms of central metal is an effective means to improve the electrocatalytic activity of atomic catalysts.Herein,iridium(Ir) is proposed to be asymmetrically anchored by sp-N and pyridinic N of hydrogen-substituted graphdiyne(HsGDY),and coordinated with OH as an Ir atomic catalyst(Ir_(1)-N-HsGDY).The electron structures,especially the d-band center of Ir atom,are optimized by these specific coordination atoms.Thus,the as-synthesized Ir_(1)-N-HsGDY exhibits excellent electrocatalytic performances for oxygen reduction and hydrogen evolution reactions in both acidic and alkaline media.Benefiting from the unique structure of HsGDY,IrN_(2)(OH)_(3) has been developed and demonstrated to act as the active site in these electrochemical reactions.All those indicate the fresh role of the sp-N in graphdiyne in producing a new anchor way and contributing to promote the electrocatalytic activity,showing a new strategy to design novel electrochemical catalysts.展开更多
A t-(v,k,λ)design is said to be G-point-primitive or G-block-transitive,if its automorphism group G acts primitively on the point set or transitively on the block set,respectively.In this paper we begin by extending ...A t-(v,k,λ)design is said to be G-point-primitive or G-block-transitive,if its automorphism group G acts primitively on the point set or transitively on the block set,respectively.In this paper we begin by extending some results on block-transitive Steiner 2-designs to block-transitive 3-designs,and then based on these results,investigate the G-point-primitive block-transitive 3-(v,k,λ)designs for alternating or symmetric groups G.We prove that when n≥min{λ^(2),30}the point stabilizer in G must be of intransitive type,and specifically,when n≥30 there exists no nontrivial G-point-primitive block-transitive 3-(v,k,2)design.展开更多
Given a maximal subgroup M of a group G, a θ*-completion C of M is called an s*-completion if either C = G or there exists a subgroup D of G which is not a θ*-completion of M such that D contains C as a maximal subg...Given a maximal subgroup M of a group G, a θ*-completion C of M is called an s*-completion if either C = G or there exists a subgroup D of G which is not a θ*-completion of M such that D contains C as a maximal subgroup. In this paper, we obtain several results on s*-completions which imply G to be solvable or supersolvable.展开更多
This paper is devoted to the discussion of homomorphic properties of fuzzy rough groups.The fuzzy approximation space was generated by fuzzy normal subgroups and the fuzzy rough approximation operators were discussed ...This paper is devoted to the discussion of homomorphic properties of fuzzy rough groups.The fuzzy approximation space was generated by fuzzy normal subgroups and the fuzzy rough approximation operators were discussed in the frame of fuzzy rough set model.The basic properties of fuzzy rough approximation operators were obtained.展开更多
The quantities c（G）, q（G） and p（G） for finite groups were defined by H. Behravesh. In this article, these quantities for the alternating group An and the symmetric group Sn are calculated. It is shown that c（G...The quantities c（G）, q（G） and p（G） for finite groups were defined by H. Behravesh. In this article, these quantities for the alternating group An and the symmetric group Sn are calculated. It is shown that c（G） = q（G） = p（G） = n,when G = An or Sn.展开更多
This is the second part of a pedagogical introduction to the theory of buildings of Jacques Tits.We de ne a(B,N)pair and construct a building out of it.Then we give a description of Chevalley groups,their(B,N)pair and...This is the second part of a pedagogical introduction to the theory of buildings of Jacques Tits.We de ne a(B,N)pair and construct a building out of it.Then we give a description of Chevalley groups,their(B,N)pair and the associated buildings.We illustrates this theory with many examples from classical groups.展开更多
Walking in groups is very common in a realistic walking environment. An extended floor field cellular automaton （CA） model is therefore proposed to describe the walking behavior of pedestrian groups, This model repr...Walking in groups is very common in a realistic walking environment. An extended floor field cellular automaton （CA） model is therefore proposed to describe the walking behavior of pedestrian groups, This model represents the motion of pedestrian groups in a realistic way. The simulation results reveal that the walking behavior of groups has an important but negative influence on pedestrian flow dynamics, especially when the density is at a high level. The presence of pedestrian groups retards the emergence of lane formation and increases the instability of operation of pedestrian flow. Moreover, the average velocity and volume of pedestrian flow are significantly reduced due to the group motion. Meanwhile, the parameter-sensitive analysis suggests that pedestrian groups should make a compromise between efficient movement and staying coherent with a certain spatial structure when walking in a dense crowd.展开更多
Objective To investigate whether ABO blood groups is associated with the severity of coronary artery disease(CAD). Methods Between January 2015 and December 2017, 1425 first diagnosed CAD patients confirmed by selecti...Objective To investigate whether ABO blood groups is associated with the severity of coronary artery disease(CAD). Methods Between January 2015 and December 2017, 1425 first diagnosed CAD patients confirmed by selective coronary angiography were recruited into this cross-sectional study, and their baseline characteristics, ABO blood groups, Gensini score were collected. Multiple linear regression analysis was performed to test the association between the severity of CAD and ABO blood groups. Results The Gensini score was significantly higher in the blood group A than in the non-A groups(41.2 ± 32 vs. 38 ± 27;P = 0.026). After adjusting for age, male, smoking, family history of CAD, hypertension, diabetes mellitus and hypercholesterolemia, multivariate linear regression indicated that blood group A was associated with the severity of CAD(β= 3.298, 95% CI: 0.91–6.505, P = 0.044). In diabetes group, A blood type was also associated with increased Gensini score(P = 0.02) after adjusting for age, male, family history of CAD, hypercholesterolemia, smoking and hypertension. Conclusion In this cross-sectional study, the data indicated that blood group A was an independent risk factor of severity of CAD in Chinese population and Chinese patients with type 2 diabetes.展开更多
MXenes are well known for their potential application in supercapacitors due to their high-rate intercalation pseudocapacitance and long cyclability.However,the reported low capacity of pristine MXenes hinders their p...MXenes are well known for their potential application in supercapacitors due to their high-rate intercalation pseudocapacitance and long cyclability.However,the reported low capacity of pristine MXenes hinders their practical application in lithium-ion batteries.In this work,a robust strategy is developed to control the functional groups of Nb_2 CT_x MXene.The capacity of pristine Nb_2 CT_x MXene can be significantly increased by Li~+ intercalation and surface modification.The specific capacity of the treated Nb_2 CT_x is up to 448 mAh g^(-1) at 0.05 A g^(-1),and at a large current density of 2 A g^(-1) remains a high reversible capacity retention rate of 75% after an ultra-long cycle of 2000 cycles.These values exceed most of the reported pristine MXenes(including the most studied Ti_3 C_2 T_x) and carbon-based materials.It demonstrates that this strategy has great help to improve the electrochemical performance of pristine MXene,and the results enhance the promise of MXenes in the application of lithium-ion batteries.展开更多
By a method improving that of [1], the authors prove the existence of a non-trivial product of filtration, s ＋ 6, in the stable homotopy groups of sphere, πt-6S, which is represented up to non-zero scalar by β^-s＋...By a method improving that of [1], the authors prove the existence of a non-trivial product of filtration, s ＋ 6, in the stable homotopy groups of sphere, πt-6S, which is represented up to non-zero scalar by β^-s＋2ho（hmbn-1 -hnbm-1） ∈ ExtA^s＋6,t＋s（Zp, Zp） in the Adams spectral sequence, where p ≥ 7, n ≥ m ＋ 2 ≥ 5, q = 2（p- 1）, 0 ≤ s 〈 p - 2, t= （s ＋ 2 ＋ （s ＋ 2）p ＋ p^m ＋ p^n）q. The advantage of this method is to extend the range of s without much complicated argument as in [1].展开更多
Correlations among free radicals, apparent activation energy, and functional groups during lowtemperature oxidation of Jurassic coal in Northern Shaanxi were investigated by examining three coal samples collected from...Correlations among free radicals, apparent activation energy, and functional groups during lowtemperature oxidation of Jurassic coal in Northern Shaanxi were investigated by examining three coal samples collected from the Ningtiaota, Jianxin, and Shigetai coal mines. Free radical concentrations at less than 120 ℃ were investigated by electron spin resonance experiments while the thermogravimetric experiments were conducted to analyze apparent activation energies. In addition, Fourier transform infrared spectroscopy was employed to study the spectrum of functional groups generated in coal. The results indicated that, in decreasing order, the apparent activation energies were Shigetai 〉Jianxin 〉 Ningtiaota, indicating that, from 50 to 120 ℃, the Ningtiaota coal sample most easily absorbed and reacted with oxygen while the most resistant was the Shigetai coal sample. Free radical concentrations and line heights increased with increased temperature, and the line width and Lande factor showed irregular fluctuations. Functional group variations were different among these coals, and the phenol and alcohol-associated OHs, carboxyls, and aromatic ring double bonds might have had a major impact on free radical concentrations. These results were meaningful for better consideration and management of coal oxidation at low temperatures.展开更多
MXenes are a novel family of two-dimensional(2D)materials that are fast gaining popularity due to their versatile characteristics.The surfaces of these materials are often functionalized by negatively charged terminal...MXenes are a novel family of two-dimensional(2D)materials that are fast gaining popularity due to their versatile characteristics.The surfaces of these materials are often functionalized by negatively charged terminal groups,such as=O,OH,and F during their synthesis,and it has been hypothesized that regulating the surface terminators enables to control the material characteristics.However,there is still a large gap between computational and experimental investigations regarding comprehending the surface functional groups.Surfaces with mixed terminations are consistently synthesized in experiments,although pure terminated surfaces are predicted by computational research.Here we summarized the nature of chemical bonding in transition metal carbide materials(MXenes)by1H and19F nuclear magnetic resonance(NMR),Raman,X-ray absorption near edge structure(XANES),extended X-ray absorption fine structure(EXAFS),ultraviolet photoelectron spectroscopy(UPS),X-ray photoelectron spectroscopy(XPS)/scanning transmission electron microscopy(STEM),and thermogravimetric analysis-mass spectrometry(TGA-MS)characterizations.Previous literature reveals that=O,–OH,–F,and–Cl are typical MXene surface terminators.However,recent comparative investigations on the valence band intensity distribution in MXenes reveal that the–OH cannot be considered an intrinsic termination species in MXenes.The surface terminals(=O,–OH,–F,and–Cl)of several MXenes,particularly V2CTxand Ti3C2Tx,will be identified and quantified here.We have also discussed different etching approaches for the synthesis of MXene,the dependence of MXene conductivity on MXene terminating groups,and the emission of various gaseous products that evolved during its chemical transformations.This paper provides significance,especially in the field of energy conversion and storage materials,where the intercalation process is crucial.展开更多
This is a pedagogical introduction to the theory of buildings of Jacques Tits and to some applications of this theory.This paper has 4 parts.In the first part we discuss incidence geometry,Coxeter systems and give two...This is a pedagogical introduction to the theory of buildings of Jacques Tits and to some applications of this theory.This paper has 4 parts.In the first part we discuss incidence geometry,Coxeter systems and give two definitions of buildings.We study in the second part the spherical and affine buildings of Chevalley groups.In the third part we deal with Bruhat-Tits theory of reductive groups over local fields.Finally we discuss the construction of the p-adic flag manifolds.展开更多
Let X be a compact complex manifold. Consider a small deformation π ： X → B of X, the dimensions of the cohomology groups of tangent sheaf Hq（xt, Txt ） may vary under this deformation. This article studies such p...Let X be a compact complex manifold. Consider a small deformation π ： X → B of X, the dimensions of the cohomology groups of tangent sheaf Hq（xt, Txt ） may vary under this deformation. This article studies such phenomena by studying the obstructions to deform a class in Hq（X, 5TX） with parameter t and gets a formula for the obstructions.展开更多
In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups c...In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mo- bility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%, respectively, which is better than that of the reference compound （13.18%）. Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD （16.87%）.展开更多
基金funding of the National Key Research and Development Plan(Grant 2017YFB0306600)the Project of SINOPEC(NO.117006).
文摘To prepare a highly efficient NiMo/Al_(2)O_(3) hydrodesulfurization catalyst,the combined effects of specific organic functional groups and alumina surface characteristics were investigated.First,the correlation between the surface characteristics of four different alumina and the existing Mo species states was established.It was found that the Mo equilibrium adsorption capacity can be used as a specific descriptor to quantitatively evaluate the changes in surface characteristics of different alumina.A lower Mo equilibrium adsorption capacity for alumina means weaker metal-support interaction and the loaded Mo species are easier to transform into MoS2.However,the Mo-O-Al bonds still exist at the metal-support interface.The introduction of cationic surfactant hecadecyl trimethyl ammonium bromide(CTAB)can further improve Mo species dispersion through electrostatic attraction with Mo anions and interaction of its alkyl chain with the alumina surface;meanwhile,the introduction of ethylenediamine tetraacetic acid(EDTA)can complex with Ni ions to enhance the Ni-promoting effect on Mo.Therefore,the NiMo catalyst designed using alumina with lower Mo equilibrium adsorption capacity and the simultaneous addition of EDTA and CTAB exhibits the highest hydrodesulfurization activity for 4,6-dimethyl dibenzothiophene because of its proper metal-support interaction and more well-dispersed Ni-Mo-S active phases.
文摘A subgroup H of a group G is called F-z-supplemented in G if there exists a subgroup K of G, such that G = HK and H∩K≤ Z∞F（G）, where Z∞F（G） is the F-hypercenter of G. We obtain some results about the F-z-supplemented subgroups and use them to determine the structure of some groups.
基金supported by the Natural Science Foundation of Yunnan Province(Grant No:202301AT070356)the Open Fund of the Key Laboratory of Tropical Forest Ecology,Chinese Academy of Sciences,National Science Foundation of China(Grant No.32061123003)+1 种基金the Joint Fund of the National Natural Science Foundation of China-Yunnan Province(Grant No.U1902203)the Field Station Foundation of the Chinese Academy of Sciences.
文摘Anthropogenic disturbances are widespread in tropical forests and influence the species composition in the overstory.However,the impacts of historical disturbance on tropical forest overstory recovery are unclear due to a lack of disturbance data,and previous studies have focused on understory species.In this study,the purpose was to deter-mine the influence of historical disturbance on the diver-sity,composition and regeneration of overstory species in present forests.In the 20-ha Xishuangbanna tropical sea-sonal rainforest dynamics plot in southwestern China,the historical disturbance boundaries were delineated based on panchromatic photographs from 1965.Factors that drove species clustering in the overstory layer(DBH≥40 cm)were analyzed and the abundance,richness and composition of these species were compared among different tree groups based on multiple regression tree analysis.The coefficient of variation of the brightness value in historical panchro-matic photographs from 1965 was the primary driver of spe-cies clustering in the overstory layer.The abundance and richness of overstory species throughout the regeneration process were similar,but species composition was always different.Although the proportion of large-seeded and vigorous-sprouting species showed no significant differ-ence between disturbed and undisturbed forests in the tree-let layer(DBH<20 cm),the difference became significant when DBH increased.The findings highlight that historical disturbances have strong legacy effects on functional group composition in the overstory and the recovery of overstory species was multidimensional.Functional group composi-tion can better indicate the dynamics of overstory species replacement during secondary succession.
文摘All parabolic subgroups and Borel subgroups of PΩ（2m ＋ 1, F） over a linearable field F of characteristic 0 are shown to be complete groups, provided m 〉 3.
基金supported by the National Natural Science Foundation of China(22172090,21790051)the National Key Research and Development Project of China(2022YFA1204500,2022YFA1204501)+2 种基金the Natural Science Foundation of Shan-dong Province(ZR2021MB015)the Open Funds of the State Key Laboratory of Electroanalytical Chemistry(SKLEAC202202)the Young Scholars Program of Shandong University。
文摘Tuning the coordination atoms of central metal is an effective means to improve the electrocatalytic activity of atomic catalysts.Herein,iridium(Ir) is proposed to be asymmetrically anchored by sp-N and pyridinic N of hydrogen-substituted graphdiyne(HsGDY),and coordinated with OH as an Ir atomic catalyst(Ir_(1)-N-HsGDY).The electron structures,especially the d-band center of Ir atom,are optimized by these specific coordination atoms.Thus,the as-synthesized Ir_(1)-N-HsGDY exhibits excellent electrocatalytic performances for oxygen reduction and hydrogen evolution reactions in both acidic and alkaline media.Benefiting from the unique structure of HsGDY,IrN_(2)(OH)_(3) has been developed and demonstrated to act as the active site in these electrochemical reactions.All those indicate the fresh role of the sp-N in graphdiyne in producing a new anchor way and contributing to promote the electrocatalytic activity,showing a new strategy to design novel electrochemical catalysts.
基金supported by the National Natural Science Foundation of China(No.12471022)。
文摘A t-(v,k,λ)design is said to be G-point-primitive or G-block-transitive,if its automorphism group G acts primitively on the point set or transitively on the block set,respectively.In this paper we begin by extending some results on block-transitive Steiner 2-designs to block-transitive 3-designs,and then based on these results,investigate the G-point-primitive block-transitive 3-(v,k,λ)designs for alternating or symmetric groups G.We prove that when n≥min{λ^(2),30}the point stabilizer in G must be of intransitive type,and specifically,when n≥30 there exists no nontrivial G-point-primitive block-transitive 3-(v,k,2)design.
文摘Given a maximal subgroup M of a group G, a θ*-completion C of M is called an s*-completion if either C = G or there exists a subgroup D of G which is not a θ*-completion of M such that D contains C as a maximal subgroup. In this paper, we obtain several results on s*-completions which imply G to be solvable or supersolvable.
基金Supported by the National Natural Science Foundation of China（60875034）
文摘This paper is devoted to the discussion of homomorphic properties of fuzzy rough groups.The fuzzy approximation space was generated by fuzzy normal subgroups and the fuzzy rough approximation operators were discussed in the frame of fuzzy rough set model.The basic properties of fuzzy rough approximation operators were obtained.
文摘The quantities c（G）, q（G） and p（G） for finite groups were defined by H. Behravesh. In this article, these quantities for the alternating group An and the symmetric group Sn are calculated. It is shown that c（G） = q（G） = p（G） = n,when G = An or Sn.
文摘This is the second part of a pedagogical introduction to the theory of buildings of Jacques Tits.We de ne a(B,N)pair and construct a building out of it.Then we give a description of Chevalley groups,their(B,N)pair and the associated buildings.We illustrates this theory with many examples from classical groups.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51278101 and 51338003)the Specialized Research Fund for the Doctoral Program of Higher Education,China(Grant No.20120092110043)the Scientific Innovation Research Project of College Graduate in Jiangsu Province,China(Grant No.CXZZ13 0117)
文摘Walking in groups is very common in a realistic walking environment. An extended floor field cellular automaton （CA） model is therefore proposed to describe the walking behavior of pedestrian groups, This model represents the motion of pedestrian groups in a realistic way. The simulation results reveal that the walking behavior of groups has an important but negative influence on pedestrian flow dynamics, especially when the density is at a high level. The presence of pedestrian groups retards the emergence of lane formation and increases the instability of operation of pedestrian flow. Moreover, the average velocity and volume of pedestrian flow are significantly reduced due to the group motion. Meanwhile, the parameter-sensitive analysis suggests that pedestrian groups should make a compromise between efficient movement and staying coherent with a certain spatial structure when walking in a dense crowd.
基金supported by grants from Clinical Vascular Grant in Chinese Physicians—VG
文摘Objective To investigate whether ABO blood groups is associated with the severity of coronary artery disease(CAD). Methods Between January 2015 and December 2017, 1425 first diagnosed CAD patients confirmed by selective coronary angiography were recruited into this cross-sectional study, and their baseline characteristics, ABO blood groups, Gensini score were collected. Multiple linear regression analysis was performed to test the association between the severity of CAD and ABO blood groups. Results The Gensini score was significantly higher in the blood group A than in the non-A groups(41.2 ± 32 vs. 38 ± 27;P = 0.026). After adjusting for age, male, smoking, family history of CAD, hypertension, diabetes mellitus and hypercholesterolemia, multivariate linear regression indicated that blood group A was associated with the severity of CAD(β= 3.298, 95% CI: 0.91–6.505, P = 0.044). In diabetes group, A blood type was also associated with increased Gensini score(P = 0.02) after adjusting for age, male, family history of CAD, hypercholesterolemia, smoking and hypertension. Conclusion In this cross-sectional study, the data indicated that blood group A was an independent risk factor of severity of CAD in Chinese population and Chinese patients with type 2 diabetes.
基金Project supported by the National Science Foundation of China (No.51772070 and 51772069)。
文摘MXenes are well known for their potential application in supercapacitors due to their high-rate intercalation pseudocapacitance and long cyclability.However,the reported low capacity of pristine MXenes hinders their practical application in lithium-ion batteries.In this work,a robust strategy is developed to control the functional groups of Nb_2 CT_x MXene.The capacity of pristine Nb_2 CT_x MXene can be significantly increased by Li~+ intercalation and surface modification.The specific capacity of the treated Nb_2 CT_x is up to 448 mAh g^(-1) at 0.05 A g^(-1),and at a large current density of 2 A g^(-1) remains a high reversible capacity retention rate of 75% after an ultra-long cycle of 2000 cycles.These values exceed most of the reported pristine MXenes(including the most studied Ti_3 C_2 T_x) and carbon-based materials.It demonstrates that this strategy has great help to improve the electrochemical performance of pristine MXene,and the results enhance the promise of MXenes in the application of lithium-ion batteries.
基金supported by the National Natural Science Foundation of China (10501045, 10771105)the NCET and the Fund of the Personnel Division of Nankai University.
文摘By a method improving that of [1], the authors prove the existence of a non-trivial product of filtration, s ＋ 6, in the stable homotopy groups of sphere, πt-6S, which is represented up to non-zero scalar by β^-s＋2ho（hmbn-1 -hnbm-1） ∈ ExtA^s＋6,t＋s（Zp, Zp） in the Adams spectral sequence, where p ≥ 7, n ≥ m ＋ 2 ≥ 5, q = 2（p- 1）, 0 ≤ s 〈 p - 2, t= （s ＋ 2 ＋ （s ＋ 2）p ＋ p^m ＋ p^n）q. The advantage of this method is to extend the range of s without much complicated argument as in [1].
基金supported by the Key Projects of the National Natural Science Foundation of China (Nos. 51504187, 51774233, and 51704226)Shaanxi Province Industrial Science and Technology Research Project (No. 2016GY-192)the China Postdoctoral Science Foundation (No. 2016-M-590963)
文摘Correlations among free radicals, apparent activation energy, and functional groups during lowtemperature oxidation of Jurassic coal in Northern Shaanxi were investigated by examining three coal samples collected from the Ningtiaota, Jianxin, and Shigetai coal mines. Free radical concentrations at less than 120 ℃ were investigated by electron spin resonance experiments while the thermogravimetric experiments were conducted to analyze apparent activation energies. In addition, Fourier transform infrared spectroscopy was employed to study the spectrum of functional groups generated in coal. The results indicated that, in decreasing order, the apparent activation energies were Shigetai 〉Jianxin 〉 Ningtiaota, indicating that, from 50 to 120 ℃, the Ningtiaota coal sample most easily absorbed and reacted with oxygen while the most resistant was the Shigetai coal sample. Free radical concentrations and line heights increased with increased temperature, and the line width and Lande factor showed irregular fluctuations. Functional group variations were different among these coals, and the phenol and alcohol-associated OHs, carboxyls, and aromatic ring double bonds might have had a major impact on free radical concentrations. These results were meaningful for better consideration and management of coal oxidation at low temperatures.
基金supported by the National Natural Science Foundation of China(21703147 and U1401248)the support of China Scholarship Council(2018SLJ022487)。
文摘MXenes are a novel family of two-dimensional(2D)materials that are fast gaining popularity due to their versatile characteristics.The surfaces of these materials are often functionalized by negatively charged terminal groups,such as=O,OH,and F during their synthesis,and it has been hypothesized that regulating the surface terminators enables to control the material characteristics.However,there is still a large gap between computational and experimental investigations regarding comprehending the surface functional groups.Surfaces with mixed terminations are consistently synthesized in experiments,although pure terminated surfaces are predicted by computational research.Here we summarized the nature of chemical bonding in transition metal carbide materials(MXenes)by1H and19F nuclear magnetic resonance(NMR),Raman,X-ray absorption near edge structure(XANES),extended X-ray absorption fine structure(EXAFS),ultraviolet photoelectron spectroscopy(UPS),X-ray photoelectron spectroscopy(XPS)/scanning transmission electron microscopy(STEM),and thermogravimetric analysis-mass spectrometry(TGA-MS)characterizations.Previous literature reveals that=O,–OH,–F,and–Cl are typical MXene surface terminators.However,recent comparative investigations on the valence band intensity distribution in MXenes reveal that the–OH cannot be considered an intrinsic termination species in MXenes.The surface terminals(=O,–OH,–F,and–Cl)of several MXenes,particularly V2CTxand Ti3C2Tx,will be identified and quantified here.We have also discussed different etching approaches for the synthesis of MXene,the dependence of MXene conductivity on MXene terminating groups,and the emission of various gaseous products that evolved during its chemical transformations.This paper provides significance,especially in the field of energy conversion and storage materials,where the intercalation process is crucial.
文摘This is a pedagogical introduction to the theory of buildings of Jacques Tits and to some applications of this theory.This paper has 4 parts.In the first part we discuss incidence geometry,Coxeter systems and give two definitions of buildings.We study in the second part the spherical and affine buildings of Chevalley groups.In the third part we deal with Bruhat-Tits theory of reductive groups over local fields.Finally we discuss the construction of the p-adic flag manifolds.
基金partially supported by China-France-Russian mathematics collaboration grant,No.34000-3275100,from Sun Yat-Sen University
文摘Let X be a compact complex manifold. Consider a small deformation π ： X → B of X, the dimensions of the cohomology groups of tangent sheaf Hq（xt, Txt ） may vary under this deformation. This article studies such phenomena by studying the obstructions to deform a class in Hq（X, 5TX） with parameter t and gets a formula for the obstructions.
基金supported by the National Basic Research Program of China (No. 2015CB932200)the CAS-Iranian Vice Presidency for Science and Technology Joint Research Project (No. 116134KYSB20160130)+2 种基金the Natural Science Foundation of Anhui Province (No. 1508085SMF224)the National Natural Science Foundation of China (No. 51474201)the External Cooperation Program of BIC, Chinese Academy of Sciences (No. GJHZ1607)
文摘In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending z-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mo- bility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%, respectively, which is better than that of the reference compound （13.18%）. Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD （16.87%）.
