The experimental values of the enthalpy of formation of two isomeric 3,4-and 3,5-dinitro-1-(trinitromethyl)-1H-pyrazoles have been obtained(261.5±5.0and 246.4±6.7kJ/mol for crystalline 3,4-and 3,5-dinitro-1-...The experimental values of the enthalpy of formation of two isomeric 3,4-and 3,5-dinitro-1-(trinitromethyl)-1H-pyrazoles have been obtained(261.5±5.0and 246.4±6.7kJ/mol for crystalline 3,4-and 3,5-dinitro-1-(trinitromethyl)-1H-pyrazoles,respectively).The ballistic effectiveness of these potential oxidizers in composite solid propellants was studied.It is shown that these two oxidizers may be successfully applied in metal-free compositions or with a small content of metal.For the bottom stage 3,4-dinitro-1-(trinitromethyl)-1H-pyrazole is a bit better than 3,5-dinitro-1-(trinitromethyl)-1H-pyrazole,for the upper stage the both oxidizers show the equal ballistic parameters.These oxidizers allow to create metal-free solid composite propellants with the binder percentage not lower than 19%(volume fraction),with I3spequal to 256.5-257.0sat density equal to 1.72-1.74g/cm^3.展开更多
Composite laminates are made up of composite single-plies sequence. The plies generally have the same fiber and resin and their difference in fiber orientation results in a difference in various laminates' strengt...Composite laminates are made up of composite single-plies sequence. The plies generally have the same fiber and resin and their difference in fiber orientation results in a difference in various laminates' strength. Tsai-Hill failure criterion as a limiting state function to analyze structural reliability of a composite laminate and estimation theory in order to estimate statistical parameters of effective stress were utilized to construct probability box. Finally, we used the Monte Carlo simulation and FERUM software to calculate the upper and lower bounds of probability of failure.展开更多
This paper presents an approach of singular value de- composition plus digital phase lock loop to solve the difficult problem of blind pseudo-noise （PN） sequence estimation in low signal to noise ratios （SNR） dire...This paper presents an approach of singular value de- composition plus digital phase lock loop to solve the difficult problem of blind pseudo-noise （PN） sequence estimation in low signal to noise ratios （SNR） direct sequence spread spectrum （DS-SS） signals with residual carrier. This approach needs some given parameters, such as the period and code rate of PN sequence. The received signal is firstly sampled and divided into non-overlapping signal vectors according to a temporal window, whose duration is two periods of PN sequence. An autocorrelation matrix is then computed and accumulated by those signal vectors one by one. The PN sequence with residual carrier can be estimated by the principal eigenvector of the autocorrelation matrix. Further more, a digital phase lock loop is used to process the estimated PN sequence, it estimates and tracks the residual carrier and removes the residual carrier in the end. Theory analysis and computer simulation results show that this approach can effectively realize the PN sequence blind estimation from the input DS-SS signals with residual carrier in lower SNR.展开更多
交叉熵法可显著加速电网可靠性评估,但往往聚焦于独立随机变量,若将其拓展至相关性变量可进一步提升加速性能。为有效获取相关性变量的重要抽样密度函数以实现其重要抽样,针对相关性建模中广泛使用的核密度估计模型(kernel density esti...交叉熵法可显著加速电网可靠性评估,但往往聚焦于独立随机变量,若将其拓展至相关性变量可进一步提升加速性能。为有效获取相关性变量的重要抽样密度函数以实现其重要抽样,针对相关性建模中广泛使用的核密度估计模型(kernel density estimation,KDE)开展了交叉熵优化研究。因KDE模型不属于指数分布家族,传统交叉熵优化难以实施,故利用复合抽样算法特点提出了新颖的直接交叉熵优化方法,推导出KDE模型最优权重参数的解析表达式。因权重参数数量级较小,直接优化易导致准确性退化,故基于子集模拟思想进一步提出间接交叉熵优化方法,将较小的权重参数优化转换成较大的条件概率优化,提升了优化准确性。通过MRTS79和MRTS96可靠性测试系统的评估分析,验证了所提方法在含相关性变量电网可靠性评估中的高效加速性能。展开更多
基金Ministry of Education and Science of the Russian Federation(14.613.21.0043)
文摘The experimental values of the enthalpy of formation of two isomeric 3,4-and 3,5-dinitro-1-(trinitromethyl)-1H-pyrazoles have been obtained(261.5±5.0and 246.4±6.7kJ/mol for crystalline 3,4-and 3,5-dinitro-1-(trinitromethyl)-1H-pyrazoles,respectively).The ballistic effectiveness of these potential oxidizers in composite solid propellants was studied.It is shown that these two oxidizers may be successfully applied in metal-free compositions or with a small content of metal.For the bottom stage 3,4-dinitro-1-(trinitromethyl)-1H-pyrazole is a bit better than 3,5-dinitro-1-(trinitromethyl)-1H-pyrazole,for the upper stage the both oxidizers show the equal ballistic parameters.These oxidizers allow to create metal-free solid composite propellants with the binder percentage not lower than 19%(volume fraction),with I3spequal to 256.5-257.0sat density equal to 1.72-1.74g/cm^3.
文摘Composite laminates are made up of composite single-plies sequence. The plies generally have the same fiber and resin and their difference in fiber orientation results in a difference in various laminates' strength. Tsai-Hill failure criterion as a limiting state function to analyze structural reliability of a composite laminate and estimation theory in order to estimate statistical parameters of effective stress were utilized to construct probability box. Finally, we used the Monte Carlo simulation and FERUM software to calculate the upper and lower bounds of probability of failure.
基金supported by the National Natural Science Foundation of China (10776040 60602057)+4 种基金Program for New Century Excellent Talents in University (NCET)the Project of Key Laboratory of Signal and Information Processing of Chongqing (CSTC2009CA2003)the Natural Science Foundation of Chongqing Science and Technology Commission (CSTC2009BB2287)the Natural Science Foundation of Chongqing Municipal Education Commission (KJ060509 KJ080517)
文摘This paper presents an approach of singular value de- composition plus digital phase lock loop to solve the difficult problem of blind pseudo-noise （PN） sequence estimation in low signal to noise ratios （SNR） direct sequence spread spectrum （DS-SS） signals with residual carrier. This approach needs some given parameters, such as the period and code rate of PN sequence. The received signal is firstly sampled and divided into non-overlapping signal vectors according to a temporal window, whose duration is two periods of PN sequence. An autocorrelation matrix is then computed and accumulated by those signal vectors one by one. The PN sequence with residual carrier can be estimated by the principal eigenvector of the autocorrelation matrix. Further more, a digital phase lock loop is used to process the estimated PN sequence, it estimates and tracks the residual carrier and removes the residual carrier in the end. Theory analysis and computer simulation results show that this approach can effectively realize the PN sequence blind estimation from the input DS-SS signals with residual carrier in lower SNR.
文摘交叉熵法可显著加速电网可靠性评估,但往往聚焦于独立随机变量,若将其拓展至相关性变量可进一步提升加速性能。为有效获取相关性变量的重要抽样密度函数以实现其重要抽样,针对相关性建模中广泛使用的核密度估计模型(kernel density estimation,KDE)开展了交叉熵优化研究。因KDE模型不属于指数分布家族,传统交叉熵优化难以实施,故利用复合抽样算法特点提出了新颖的直接交叉熵优化方法,推导出KDE模型最优权重参数的解析表达式。因权重参数数量级较小,直接优化易导致准确性退化,故基于子集模拟思想进一步提出间接交叉熵优化方法,将较小的权重参数优化转换成较大的条件概率优化,提升了优化准确性。通过MRTS79和MRTS96可靠性测试系统的评估分析,验证了所提方法在含相关性变量电网可靠性评估中的高效加速性能。
