A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum ...A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum adsorption roller to prepare phase change material(PCM)particle(PCP).Then EP and EVMT-based composite PCM plates were respectively fabricated through a mold pressing method.The thermal property,chemical stability,microstructure and durability were characterized by differential scanning calorimeter(DSC),Fourier transform infrared spectroscope(FT-IR),scanning electron microscope(SEM)and thermal cycling tests,respectively.The results show that both PCPs have high latent heats with 110 J/g for EP-based PCP and more than 130 J/g for EVMT-based PCP,compact microstructure without PCM leakage,stable chemical property and good durability.The research results have proved the feasibility for the vacuum adsorption roller used in the composite PCM fabrication.Results of thermal storage performance experiment indicate that the fabricated PCM plates have better thermal inertia than common building materials,and the thermal storage performance of PCM plates has nonlinearly changed with outside air velocity and temperature increase.Therefore,PCM plates show a significant potential for the practical application of building thermal storage.展开更多
单一脂肪酸的相变温度普遍较高且易泄漏,不能满足其作为相变材料对夏季建筑空调能耗调节的需求。本工作基于真实溶剂类导体屏蔽模型(conductor-like screening model for real solvents,COSMO-RS),采用COSMOthermX软件对7种中链脂肪酸...单一脂肪酸的相变温度普遍较高且易泄漏,不能满足其作为相变材料对夏季建筑空调能耗调节的需求。本工作基于真实溶剂类导体屏蔽模型(conductor-like screening model for real solvents,COSMO-RS),采用COSMOthermX软件对7种中链脂肪酸和10种长链脂肪酸两两组合的136种二元低共熔脂肪酸进行设计计算,筛选预测其共熔温度与摩尔比。进而将最优组合作为芯材,三聚氰胺-尿素-甲醛树脂(MUF)为壁材,通过原位聚合法制备相变微胶囊,系统地探讨不同工艺条件(芯壁比、反应温度、反应时间和反应转速等)对该微胶囊热物理性能的影响。结果表明:COSMO-RS模型可以直观地判断材料氢键供体(hydrogen bond donor,HBD)与受体(hydrogen bond acceptor,HBA)之间的关系,最优组合月桂酸(lauric acid,LA)与肉豆蔻酸(myristic acid,MA)摩尔比为0.66∶0.34的LA-MA(LM)理论共熔温度(33.25℃)与实验结果(33.1℃)相似度达98.08%;在芯壁比2∶1、反应时间3 h、反应温度80℃、搅拌转速200 r/min的条件下,MUF对芯材LM的包覆效率为61.37%,较好地解决了泄漏问题,对降低建筑空调制冷能耗具有潜在的应用价值。展开更多
基金Project(51408184)supported by the National Natural Science Foundation of ChinaProject(E2017202136)supported by the Natural Science Foundation of Hebei Province,China+1 种基金Project(BSBE2017-05)supported by Opening Funds of State Key Laboratory of Building Safety and Built Environment and National Engineering Research Center of Building Technology,ChinaProject(QG2018-3)supported by Hebei Provincial Department of Transportation,China
文摘A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum adsorption roller to prepare phase change material(PCM)particle(PCP).Then EP and EVMT-based composite PCM plates were respectively fabricated through a mold pressing method.The thermal property,chemical stability,microstructure and durability were characterized by differential scanning calorimeter(DSC),Fourier transform infrared spectroscope(FT-IR),scanning electron microscope(SEM)and thermal cycling tests,respectively.The results show that both PCPs have high latent heats with 110 J/g for EP-based PCP and more than 130 J/g for EVMT-based PCP,compact microstructure without PCM leakage,stable chemical property and good durability.The research results have proved the feasibility for the vacuum adsorption roller used in the composite PCM fabrication.Results of thermal storage performance experiment indicate that the fabricated PCM plates have better thermal inertia than common building materials,and the thermal storage performance of PCM plates has nonlinearly changed with outside air velocity and temperature increase.Therefore,PCM plates show a significant potential for the practical application of building thermal storage.
文摘单一脂肪酸的相变温度普遍较高且易泄漏,不能满足其作为相变材料对夏季建筑空调能耗调节的需求。本工作基于真实溶剂类导体屏蔽模型(conductor-like screening model for real solvents,COSMO-RS),采用COSMOthermX软件对7种中链脂肪酸和10种长链脂肪酸两两组合的136种二元低共熔脂肪酸进行设计计算,筛选预测其共熔温度与摩尔比。进而将最优组合作为芯材,三聚氰胺-尿素-甲醛树脂(MUF)为壁材,通过原位聚合法制备相变微胶囊,系统地探讨不同工艺条件(芯壁比、反应温度、反应时间和反应转速等)对该微胶囊热物理性能的影响。结果表明:COSMO-RS模型可以直观地判断材料氢键供体(hydrogen bond donor,HBD)与受体(hydrogen bond acceptor,HBA)之间的关系,最优组合月桂酸(lauric acid,LA)与肉豆蔻酸(myristic acid,MA)摩尔比为0.66∶0.34的LA-MA(LM)理论共熔温度(33.25℃)与实验结果(33.1℃)相似度达98.08%;在芯壁比2∶1、反应时间3 h、反应温度80℃、搅拌转速200 r/min的条件下,MUF对芯材LM的包覆效率为61.37%,较好地解决了泄漏问题,对降低建筑空调制冷能耗具有潜在的应用价值。
