The adsorption of dedecyltrimethylammoium chloride(DTAC) and hexadecyltrimethylammoium chloride(CTAC) on muscovite mica substrates was examined using atomic force microscopy(AFM). Adsorption morphology images and inte...The adsorption of dedecyltrimethylammoium chloride(DTAC) and hexadecyltrimethylammoium chloride(CTAC) on muscovite mica substrates was examined using atomic force microscopy(AFM). Adsorption morphology images and interaction forces of cationic surfactants at solid-solution interfaces were measured in tapping mode and Pico Force mode, respectively. The images demonstrated that the adsorbed structure was varied by a variety of surfactant concentrations. The adsorbed layer on mica was monolayer at first, and then became bilayer. A striped adsorbed structure was observed in a higher concentration of CTAC,which could not be found in any other concentrations of DTAC. For force measurements, the repulsive force was exponentially decreasing with the concentration increasing till a net attractive force appeared. A largest attractive force could be observed at a certain concentration, which was close to the point of charge neutralization. The results also showed a significant impact of hydrocarbon chain length on adsorption. An adsorption simulation was established to give a clear understanding of the interaction between cationic surfactants and mica.展开更多
This paper deals with the assessment of vibro-acoustic properties of a multifunctional carbon fiber reinfo rced panel manu factured by bulk infu sion,a modified resin film infusion process.The components of the epoxy ...This paper deals with the assessment of vibro-acoustic properties of a multifunctional carbon fiber reinfo rced panel manu factured by bulk infu sion,a modified resin film infusion process.The components of the epoxy resin were chosen to contrast the electrical insulating property and poor flame resistance of the epoxy resins impregnating carbon woven fabric.To confer electrical conductivity to the resin a percentage of 0.5 wt%of Multi-Wall Carbon Nanotubes(MWCNTs)was dispersed in the resin,whereas to increase flame resistance a percentage of 5 wt%of Glycidil Polyhedral Oligomeric Silsesquioxanes(GPOSS)was solubilized in the epoxy mixture.Furthermore,as hardener agents,a mixture of 4,4’-DiaminoDiphenyl Sulfone(DDS)(53.4 wt%)and Bis(3-Aminophenyl)Methyl Phosphine Oxide(BAMPO)(46.7 wt%)was used.The values of the electrical conductivity were found satisfactory enough,being4.02×10^(-2)S/m for the multifunctional resin and 1.39×10^(4)S/m for the in-plane conductivity of the panel,whereas the Limiting Oxygen Index(LOI)value of the multifunctional resin was found to increase from 27%to 36%.Considering these promising results,an experimental assessment of the vibro-acoustic properties of the manufactured multifunctional panel was also performed.The panel was tested mainly to evaluate its low-frequency vibration damping and sound insulation characteristics.The manufactured panel demonstrated an improved efficiency if compared to a baseline configuration,presenting almost the double modal damping and a gain of 10 dB on the global noise reduction.展开更多
原子力显微镜(atomic force microscopy,AFM)在微纳米尺度力学测量领域有着广泛应用,其微悬臂梁探针的弹性常数是直接影响测量结果准确性的关键因素之一。弯曲法是标定微悬臂梁弹性常数的一类重要方法,基于弯曲标定原理提出了一种新的...原子力显微镜(atomic force microscopy,AFM)在微纳米尺度力学测量领域有着广泛应用,其微悬臂梁探针的弹性常数是直接影响测量结果准确性的关键因素之一。弯曲法是标定微悬臂梁弹性常数的一类重要方法,基于弯曲标定原理提出了一种新的技术实现方案,并研制了相应的标定系统。借助精密运动定位台使微悬臂梁接触超精密天平并产生弯曲,分别以天平和光杠杆机构同步测得接触力和梁的弯曲量,再根据胡克定律直接算得弹性常数。利用所研制的系统对多种型号的微悬臂梁进行了标定,实验结果表明该系统具有良好的准确性和重复性,测量相对标准差小于5%。展开更多
应用原子力显微镜(atomic force microscopy,AFM)探测了静息、脂多糖(LPS)或伴刀豆蛋白(ConA)活化的人外周血淋巴细胞的形态结构、超微结构及粘滞力特性。从AFM图像可知,经LPS或ConA刺激活化后的淋巴细胞比静息状态的淋巴细胞有...应用原子力显微镜(atomic force microscopy,AFM)探测了静息、脂多糖(LPS)或伴刀豆蛋白(ConA)活化的人外周血淋巴细胞的形态结构、超微结构及粘滞力特性。从AFM图像可知,经LPS或ConA刺激活化后的淋巴细胞比静息状态的淋巴细胞有所增大,并且表面分布着大小不一的颗粒状聚合物。利用AFM高空间分辨的力位移曲线测量系统,发现经LPS或ConA刺激活化后淋巴细胞的粘滞力是静息状态淋巴细胞的2~3倍。通过AFM探测淋巴细胞活化状态的可视化数据,可以更好地理解淋巴细胞的行为。展开更多
基金Project(50974134)supported by the National Natural Science Foundation of China
文摘The adsorption of dedecyltrimethylammoium chloride(DTAC) and hexadecyltrimethylammoium chloride(CTAC) on muscovite mica substrates was examined using atomic force microscopy(AFM). Adsorption morphology images and interaction forces of cationic surfactants at solid-solution interfaces were measured in tapping mode and Pico Force mode, respectively. The images demonstrated that the adsorbed structure was varied by a variety of surfactant concentrations. The adsorbed layer on mica was monolayer at first, and then became bilayer. A striped adsorbed structure was observed in a higher concentration of CTAC,which could not be found in any other concentrations of DTAC. For force measurements, the repulsive force was exponentially decreasing with the concentration increasing till a net attractive force appeared. A largest attractive force could be observed at a certain concentration, which was close to the point of charge neutralization. The results also showed a significant impact of hydrocarbon chain length on adsorption. An adsorption simulation was established to give a clear understanding of the interaction between cationic surfactants and mica.
文摘This paper deals with the assessment of vibro-acoustic properties of a multifunctional carbon fiber reinfo rced panel manu factured by bulk infu sion,a modified resin film infusion process.The components of the epoxy resin were chosen to contrast the electrical insulating property and poor flame resistance of the epoxy resins impregnating carbon woven fabric.To confer electrical conductivity to the resin a percentage of 0.5 wt%of Multi-Wall Carbon Nanotubes(MWCNTs)was dispersed in the resin,whereas to increase flame resistance a percentage of 5 wt%of Glycidil Polyhedral Oligomeric Silsesquioxanes(GPOSS)was solubilized in the epoxy mixture.Furthermore,as hardener agents,a mixture of 4,4’-DiaminoDiphenyl Sulfone(DDS)(53.4 wt%)and Bis(3-Aminophenyl)Methyl Phosphine Oxide(BAMPO)(46.7 wt%)was used.The values of the electrical conductivity were found satisfactory enough,being4.02×10^(-2)S/m for the multifunctional resin and 1.39×10^(4)S/m for the in-plane conductivity of the panel,whereas the Limiting Oxygen Index(LOI)value of the multifunctional resin was found to increase from 27%to 36%.Considering these promising results,an experimental assessment of the vibro-acoustic properties of the manufactured multifunctional panel was also performed.The panel was tested mainly to evaluate its low-frequency vibration damping and sound insulation characteristics.The manufactured panel demonstrated an improved efficiency if compared to a baseline configuration,presenting almost the double modal damping and a gain of 10 dB on the global noise reduction.
文摘原子力显微镜(atomic force microscopy,AFM)在微纳米尺度力学测量领域有着广泛应用,其微悬臂梁探针的弹性常数是直接影响测量结果准确性的关键因素之一。弯曲法是标定微悬臂梁弹性常数的一类重要方法,基于弯曲标定原理提出了一种新的技术实现方案,并研制了相应的标定系统。借助精密运动定位台使微悬臂梁接触超精密天平并产生弯曲,分别以天平和光杠杆机构同步测得接触力和梁的弯曲量,再根据胡克定律直接算得弹性常数。利用所研制的系统对多种型号的微悬臂梁进行了标定,实验结果表明该系统具有良好的准确性和重复性,测量相对标准差小于5%。
基金The project was supported by the National Natural Science Foundation of China(60904095,61175103)National High Technology Research and Development Program of China(863)(2009AA03Z316)Chinese Academy of Sciences Foreign Experts Affairs International Partnership Program for Creative Research Teams~~
文摘应用原子力显微镜(atomic force microscopy,AFM)探测了静息、脂多糖(LPS)或伴刀豆蛋白(ConA)活化的人外周血淋巴细胞的形态结构、超微结构及粘滞力特性。从AFM图像可知,经LPS或ConA刺激活化后的淋巴细胞比静息状态的淋巴细胞有所增大,并且表面分布着大小不一的颗粒状聚合物。利用AFM高空间分辨的力位移曲线测量系统,发现经LPS或ConA刺激活化后淋巴细胞的粘滞力是静息状态淋巴细胞的2~3倍。通过AFM探测淋巴细胞活化状态的可视化数据,可以更好地理解淋巴细胞的行为。