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Degradation of joint surface morphology, shear behavior and closure characteristics during cyclic loading 被引量:6
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作者 FAN Wen-chen CAO Ping LONG Long 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第3期653-661,共9页
In order to investigate the failure mechanism of rock joint,a series of laboratory tests including cyclic direct shear tests under constant normal load(CNL)conditions were conducted.Morphology parameters of the rock j... In order to investigate the failure mechanism of rock joint,a series of laboratory tests including cyclic direct shear tests under constant normal load(CNL)conditions were conducted.Morphology parameters of the rock joint surface were precisely calculated by means of a three-dimensional laser scanning machine.All test results were analyzed to investigate the shear behavior and normal displacement behavior of rock joints under CNL conditions.Degradation of rock joint surface during cyclic shear tests was also analyzed.The comparison results of the height parameters and the hybrid parameters of the joint surface during cyclic tests show that the degradation of the surface mostly happens in the first shear and the constant normal loads imposed on the joints have significant promotion effects on the morphology degradation.During cyclic shear tests,joints surfaces evolve from rough state to smooth state but keep an overall undulation.Dilatancy of rock joints degrades with the degradation of joint surface and the increase of normal loads.The closure deformation of joint is larger than that of the intact rock,and the normal stiffness increases with the increase of shearing times. 展开更多
关键词 rock joint constant normal load condition surface morphology degradation shear behavior joint closure characteristic
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Study of the Material Transfer Characteristics and Surface Morphology Due to Arc Erosion of PtIr Contact Materials 被引量:1
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作者 WANG Saibei XIE Ming +6 位作者 YANG Youcai ZHANG Jiming CHEN Yongtai LIU Manmen YANG Yunfeng HU Jieqiong CUI Hao 《贵金属》 CAS CSCD 北大核心 2012年第A01期128-133,共6页
By means of breaking tests on PtIr contact materials via a JF04C contact material testing machine, it was attempted to elucidate the characteristics of the various surface morphology and material transfer after the ar... By means of breaking tests on PtIr contact materials via a JF04C contact material testing machine, it was attempted to elucidate the characteristics of the various surface morphology and material transfer after the arc erosion process caused by break arc. The material transfer characteristics appeared in the experiments were concluded and analyzed. Meanwhile, the morphology of the anode and cathode surface were observed and analyzed by SEM. 展开更多
关键词 PtIr contact materials arc erosion material transfer surface morphology
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Morphology characteristics of joint surface in rock mass
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作者 胡建华 阮德修 +1 位作者 罗先伟 周科平 《Journal of Central South University》 SCIE EI CAS 2012年第10期2918-2925,共8页
In order to quantify the characteristics of the surface of jointed rock mass,new equipment,the three-dimensional laser surface topography instrument,was used to accurately measure surface morphology of joints.Scan pic... In order to quantify the characteristics of the surface of jointed rock mass,new equipment,the three-dimensional laser surface topography instrument,was used to accurately measure surface morphology of joints.Scan pictures and parameters were obtained to describe the rock joint surface characteristics,for example,the height frequency of surface,and mean square roughness.Using the method of fractal dimension,the values of joint roughness coefficient(JRC) were calculated based on the above parameters.It could access to the joint surface rock sample morphology of the main parameters of characteristic.The maximum peak height is 2.692 mm in the test joint plane.The maximum profile height is 4.408 mm.JRC value is 6.38 by fractal dimension computing.It belongs to the smooth joint surface.The results show that it is a kind of the effective method to quantitatively evaluate the surface topography by the three-dimensional laser surface topography instrument and the fractal dimension method.According to the results,during the process of underground large-scale mining,safe measures to prevent slip failure of the joint plane by controlling surface tension and shear mechanical response were proposed. 展开更多
关键词 joint surface morphology characteristic fi'actal dimension joint roughness coefficient
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不同电流下Ce掺杂AgCuO触头材料转移行为研究
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作者 王海涛 王彦岭 +3 位作者 李书舸 王景芹 李文华 赵伟 《电工技术学报》 北大核心 2025年第2期574-586,共13页
材料转移是电弧侵蚀中的一个必然过程,研究材料转移机制对于优化电极的材料选择和设计,开发更耐用、更稳定的电极材料有重要意义,该文以Ce掺杂的AgCuO触头为研究对象,分析材料转移方向在不同电流下变化的机理。通过溶胶-凝胶法和粉末冶... 材料转移是电弧侵蚀中的一个必然过程,研究材料转移机制对于优化电极的材料选择和设计,开发更耐用、更稳定的电极材料有重要意义,该文以Ce掺杂的AgCuO触头为研究对象,分析材料转移方向在不同电流下变化的机理。通过溶胶-凝胶法和粉末冶金法制备触头试样,借助JF04D电接触测试系统,在18 V电压下设置10、15、20和25 A四个电流等级,对触头进行20000次电弧侵蚀实验。首先对比了15 A电流条件下添加Ce后材料的性能提升情况,然后重点关注AgCuOCeO_(2)触头在不同电流下的燃弧能量与燃弧时间,测定侵蚀实验后阴阳极的质量变化,采用三维表面轮廓仪和扫描电镜表征阳极和阴极的表面侵蚀形貌,并对不同电流下的材料转移机制进行深入讨论分析。结果表明,Ce元素提升了触头性能,电流大小影响电极间金属离子和气体离子的浓度,引发金属相或气体相电弧的产生,导致材料转移方向在电流增大时发生改变。为选用和开发性能优良的AgCuO触头材料,进而提升AgCuO触头可靠性提供了理论依据。 展开更多
关键词 agCuO触头材料 电弧侵蚀 材料转移 表面形貌 燃弧能量 燃弧时间
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Effect of water absorption ratio on tensile strength of red sandstone and morphological analysis of fracture surfaces 被引量:1
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作者 WANG Min CAO Ping +1 位作者 LI Rui-chao FAN Xiang 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第7期1647-1653,共7页
Brazilian disc tests were undertaken on a number of red sandstone samples with different water absorption ratios.The tensile strength of the red sandstone decreases as the water absorption ratio increases.The fracture... Brazilian disc tests were undertaken on a number of red sandstone samples with different water absorption ratios.The tensile strength of the red sandstone decreases as the water absorption ratio increases.The fracture surfaces of failed red sandstone discs were scanned by Talysurf CLI 2000.With the aid of Talymap Gold software,based on ISO25178,a set of statistical parameters was obtained for the fracture surfaces.The maximum peak height(S_p),maximum pit height(S_v) and maximum height(S_z) of the fracture surfaces exhibited the same decreasing trend with increasing water absorption.Sa and Sku values for the fracture surfaces showed a downward trend as the water absorption ratio increased.The fractal dimensions of fracture surfaces were calculated and found to decrease as the water absorption ratio increased.Through analysis of PSD curves,the smallest dominant wavelength was observed to reflect the roughness of the fracture surfaces.Additionally,the results suggest that the roughness of fracture surfaces becomes small as the water absorption ratio increases. 展开更多
关键词 WATER ABSORPTION ratio BRAZILIAN DISC test fracture surface morphologICAL analysis ROUGHNESS
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Laser-assisted water jet machining of high quality micro-trap structures on stainless steel surfaces
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作者 LIU Li YAO Peng +3 位作者 CHU Dong-kai XU Xiang-yue QU Shuo-shuo HUANG Chuan-zhen 《中国光学(中英文)》 EI CAS CSCD 北大核心 2024年第6期1476-1488,共13页
Secondary electron emission(SEE)has emerged as a critical issue in next-generation accelerators.Mitigating SEE on metal surfaces is crucial for enhancing the stability and emittance of particle accelerators while exte... Secondary electron emission(SEE)has emerged as a critical issue in next-generation accelerators.Mitigating SEE on metal surfaces is crucial for enhancing the stability and emittance of particle accelerators while extending their lifespan.This paper explores the application of laser-assisted water jet technology in constructing high-quality micro-trap structures on 316L stainless steel,a key material in accelerator manufacturing.The study systematically analyzes the impact of various parameters such as laser repetition frequency,pulse duration,average power,water jet pressure,repeat times,nozzle offset,focal position,offset distance between grooves,and processing speed on the surface morphology of stainless steel.The findings reveal that micro-groove depth increases with higher laser power but decreases with increasing water jet pressure and processing speed.Interestingly,repeat times have minimal effect on depth.On the other hand,micro-groove width increases with higher laser power and repeat times but decreases with processing speed.By optimizing these parameters,the researchers achieved high-quality pound sign-shaped trap structure with consistent dimensions.We tested the secondary electron emission coefficient of the"well"structure.The coefficient is reduced by 0.5 at most compared to before processing,effectively suppressing secondary electron emission.These results offer indispensable insights for the fabrication of micro-trap structures on material surfaces.Laser-assisted water jet technology demonstrates considerable potential in mitigating SEE on metal surfaces. 展开更多
关键词 laser-assisted water jet 316L stainless steel micro-trap structures "well"structure surface morphology secondary electron emission(SEE) groove depth groove width
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基于Cu-Ag基底的顶空-SERS法快速现场检测水中甲基砷酸盐
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作者 田克芳 张旻 +2 位作者 张清哲 景传勇 蔡勇 《环境化学》 北大核心 2025年第6期2068-2078,共11页
目前,甲基砷酸盐分析方法多依赖大型精密仪器,难以进行现场检测.表面增强拉曼光谱(SERS)作为一种原位无损的检测技术,可用于环境中痕量甲基砷酸盐(一甲基砷酸盐:MMAA、二甲基砷酸盐:DMAA)的分析.本研究采用简便的金属置换法,制备了铜网... 目前,甲基砷酸盐分析方法多依赖大型精密仪器,难以进行现场检测.表面增强拉曼光谱(SERS)作为一种原位无损的检测技术,可用于环境中痕量甲基砷酸盐(一甲基砷酸盐:MMAA、二甲基砷酸盐:DMAA)的分析.本研究采用简便的金属置换法,制备了铜网-银枝晶(Cu-Ag)SERS基底,并基于此开发了一种便携式SERS分析装置,首次利用顶空法快速现场检测水中甲基砷酸盐.研究系统探究了装置条件、盐酸(HCl)及硼氢化钾(KBH4)浓度、甲基砷酸盐溶液体积等因素对SERS检测的影响.结果表明,在60℃加热搅拌下,最佳检测时间为10 min,HCl及KBH4的最佳浓度分别为0.2 mol·L^(−1)和0.6 mol·L^(−1),最佳甲基砷酸盐溶液体积为20 mL.根据特征峰位移可区分MMAA(622 cm^(−1))与DMAA(596 cm^(−1)和614 cm^(−1)),其中MMAA的检测限低至1.29 g·L^(−1).性能测试结果显示,该SERS基底具有优异的均匀性、稳定性和批次重复性.此外,用该装置检测不同地区的实际水样,MMAA回收率在95.6%—102.6%之间,相对标准偏差(RSD)范围为4.5%—6.6%,且该SERS方法的检测结果与高效液相色谱-氢化物发生-原子荧光光谱法相近,证实该便携式SERS装置可用于现场检测水体中的甲基砷酸盐. 展开更多
关键词 顶空法 甲基砷酸盐 现场检测 表面增强拉曼光谱 铜网-银枝晶.
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Influence of surface finish and annealing treatment on oxidation behavior of Ti-48Al-8Cr-2Ag alloy
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作者 席艳君 刘泳俊 《Journal of Central South University》 SCIE EI CAS 2009年第4期541-545,共5页
The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA)... The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy was investigated at 900 and 1 000 ℃, respectively in air. Thermal gravimetric analysis (TGA) was conducted for the characterization of oxidation kinetics. The microstructures of oxide scales were studied by scanning electron microscopy (SEM) and transmission election microscopy (TEM) techniques. Unfavorable effect of the annealing treatment on the oxidation behavior of the coating was also investigated. The results indicate that the oxidation behavior of the alloy is influenced by surface finish and annealing treatment. The oxidation rate of ground sample is lower than that of the polished alloy at 1 000 ℃ in air. The former forms a scale of merely Al2O3, and the latter forms a scale of the mixture of Al2O3 and TiO2. Annealing can improve the formation of TiO2. 展开更多
关键词 Ti-48Al-8Cr-2ag alloy COATING surface finish ANNEALING oxidation behavior
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Fe_(3)O_(4)-Au-Ag复合纳米材料的合成及其作为拉曼光谱基底的应用
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作者 吴睿 周正 《稀有金属与硬质合金》 北大核心 2025年第2期100-108,共9页
以三乙醇胺水热法制备Fe_(3)O_(4)纳米粒子,柠檬酸钠共还原法合成纳米Au-Ag合金溶胶,并对Fe_(3)O_(4)纳米粒子进行表面氨基化修饰。随后将Au-Ag纳米粒子负载在Fe_(3)O_(4)上合成Fe_(3)O_(4)-Au-Ag磁性复合纳米材料,并借助XRD、UV-Vis、... 以三乙醇胺水热法制备Fe_(3)O_(4)纳米粒子,柠檬酸钠共还原法合成纳米Au-Ag合金溶胶,并对Fe_(3)O_(4)纳米粒子进行表面氨基化修饰。随后将Au-Ag纳米粒子负载在Fe_(3)O_(4)上合成Fe_(3)O_(4)-Au-Ag磁性复合纳米材料,并借助XRD、UV-Vis、TEM和EDS等方法对复合材料进行表征。将该复合材料作为表面增强拉曼散射(SERS)基底,并利用标准工作曲线开辟了一种检测左氧氟沙星的新方法,同时做了加标回收实验,分析了Fe_(3)O_(4)-Au-Ag增强左氧氟沙星拉曼光谱的机理。SERS峰强度与左氧氟沙星浓度(10^(-7)~10^(-3)mol/L)对数之间呈相对较好的线性关系,标准工作曲线方程为y=957x+7516.2,相关系数R^(2)=0.9522。该方法具有良好的稳定性,相对标准偏差为2.2%;灵敏度较高,检出限为2×10^(-9)mol/L,加标回收率在93%以上。Fe_(3)O_(4)-Au-Ag增强左氧氟沙星拉曼光谱的机理包括电磁增强机理和化学增强机理以及三个增强模型(镜像模型、天线模型和避雷针模型)。此新方法有望用在农业、工业、环境、食品、医药和卫生等领域,实现对实际样品中抗生素的高灵敏检测。 展开更多
关键词 磁性复合纳米材料 Fe_(3)O_(4)-Au-ag 表面增强拉曼光谱 基底 左氧氟沙星 增强机理
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5%Ag掺杂对MNO_(2)纳米棒和海胆微球形貌及其甲苯氧化性能的影响
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作者 鲁美娟 方汉孙 +4 位作者 黄华军 李丹萍 吴玮玲 屈小路 喻成龙 《环境工程技术学报》 CAS CSCD 北大核心 2024年第4期1239-1246,共8页
采用水热法制备了MNO_(2)纳米棒和海胆微球,并原位掺杂5%Ag制备了Mn-Ag复合氧化物,利用SEM、XRD、BET、Raman等表征技术对其结构进行表征,并考察不同催化剂对甲苯的去除性能。结果表明:(NH_(4))_(2)S_(2)O_(8)的掺入量会对MNO_(2)的形... 采用水热法制备了MNO_(2)纳米棒和海胆微球,并原位掺杂5%Ag制备了Mn-Ag复合氧化物,利用SEM、XRD、BET、Raman等表征技术对其结构进行表征,并考察不同催化剂对甲苯的去除性能。结果表明:(NH_(4))_(2)S_(2)O_(8)的掺入量会对MNO_(2)的形貌产生影响,当其掺入量为2.28 g时,形成MNO_(2)纳米棒,当其掺入量为6.84 g时,形成MNO_(2)海胆微球;MNO_(2)纳米棒掺杂5%的Ag后,形貌未发生变化,但当MNO_(2)海胆微球掺杂5%Ag时,表面的纳米线较MNO_(2)海胆微球有所增长,且出现了缠绕现象,形成了空心鸟巢状结构;5%Ag掺杂后,对MNO_(2)纳米棒和MNO_(2)海胆微球的晶型未产生影响,均为α-MNO_(2),但5%Ag-MNO_(2)纳米棒出现了Mn2O_(3)的衍射峰;MNO_(2)海胆微球较MNO_(2)纳米棒的比表面积、孔径和孔容均增大,且Ag的掺杂进一步提高了MNO_(2)海胆微球的比表面积、孔径和孔容;MNO_(2)海胆微球比MNO_(2)纳米棒具有更好的甲苯去除性能,且5%Ag掺杂后,MNO_(2)海胆微球对甲苯的去除性能达到最好。 展开更多
关键词 MNO_(2)纳米棒 MNO_(2)海胆微球 ag掺杂 形貌影响 甲苯去除
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Influence of aging treatment on corrosion behavior and mechanism of Mg–Y alloys 被引量:4
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作者 徐宏 张新 +2 位作者 蒋三生 任霁萍 高翔宇 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第5期987-1002,共16页
This paper studied the influence of aging treatment on the corrosion behavior and mechanism of Mg-Y alloys with different Y content through corrosion mass loss test, electrochemical test and corrosion morphologies obs... This paper studied the influence of aging treatment on the corrosion behavior and mechanism of Mg-Y alloys with different Y content through corrosion mass loss test, electrochemical test and corrosion morphologies observation. Results show that the peak-aging times of Mg-(0.25, 2.5, 5, 8 and 15) Y alloys at 250 ℃ were 4, 6, 10, 12 and 16 h. The aging treatment reduced the corrosion resistance of Mg-Y alloys, and the corrosion resistance of Mg-Y alloys became worse with increasing of the aging time. The change magnitude of the open circuit potentials for Mg-(0.25, 2.5)Y alloys was greater than that of Mg-(5, 8 and 15)-Y alloys. The polarization curves of Mg (0.25, 2.5, 5, 8 and 15) Y alloys had the similar shape after aging treatment, and the slopes of the anodic branch were greater than those of the cathodic branches. After aging treatment, the corrosion modes of Mg-0.25Y and Mg-(2.5, 5, 8 and 15) Y alloys were uniform corrosion and pitting corrosion with small local deep corrosion. 展开更多
关键词 Mg-Y alloy aging treatment electrochemical corrosion resistance corrosion morphology
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Mechanical behaviors of interaction between coral sand and structure surface 被引量:2
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作者 FENG Ze-kang XU Wen-jie MENG Qing-shan 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第11期3436-3449,共14页
Based on the interface shear tests,the macro-and meso-mechanical behaviors of interaction between coral sand and different structure surfaces are studied,in which CCD camera is used to capture digital images to analyz... Based on the interface shear tests,the macro-and meso-mechanical behaviors of interaction between coral sand and different structure surfaces are studied,in which CCD camera is used to capture digital images to analyze the evolution of the interaction band and a particle analysis apparatus is applied to studying the distribution characteristics of particle morphology.This study proposes four-stage evolution process based on the shear stress−strain curve.During the shear process,coral sand particles slide and rotate within the interaction band,causing the changes in shear stress and vertical displacement.In addition,the effects of structure surface roughness on shear strength,volume change and particle breakage are illustrated that the greater the roughness of slabs is,the larger the shear stress is,the more obvious the contraction effect is and the more the particles break.Furthermore,the change in particle’s 3D morphology during the breakage will change not only their size but also other morphological characteristics with convergence and self-organization. 展开更多
关键词 coral sand direct shear test interaction surface particle morphology
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电镀参数对电沉积Sn-Ag-Cu合金镀层的影响 被引量:3
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作者 文思倩 闫焉服 +1 位作者 周慧 程江洋 《稀有金属与硬质合金》 CAS CSCD 北大核心 2024年第1期63-68,80,共7页
采用自主研发的甲磺酸锡银铜电镀液在黄铜基体上制备了Sn-Ag-Cu合金镀层。通过扫描电子显微镜(SEM)及其自带的能谱仪(EDS)分析了电镀工艺参数对Sn-Ag-Cu合金镀层的成分、表面形貌以及镀层厚度产生的影响。结果表明,当电流密度为4 A/dm^... 采用自主研发的甲磺酸锡银铜电镀液在黄铜基体上制备了Sn-Ag-Cu合金镀层。通过扫描电子显微镜(SEM)及其自带的能谱仪(EDS)分析了电镀工艺参数对Sn-Ag-Cu合金镀层的成分、表面形貌以及镀层厚度产生的影响。结果表明,当电流密度为4 A/dm^(2)、温度为25℃及pH为5.5时,可获得结晶较细且致密,表面平整光亮且厚度均匀的Sn-Ag-Cu合金镀层。 展开更多
关键词 Sn-ag-Cu合金 电镀参数 甲磺酸锡银铜电镀液 表面形貌 镀层厚度 电流密度
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Effect of Substrate Surface Roughness on Properties of Ni-Cr Alloy Thin Film
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作者 王广海 于晓艳 +1 位作者 李国新 焦清介 《Defence Technology(防务技术)》 CAS 2012年第1期41-46,共6页
The effect of surface roughness of aluminum oxide (95%) substrate on the properties of Ni-Cr alloy thin film is studied.The thin films are prepared on the substrates with different roughness by using magnetron sputter... The effect of surface roughness of aluminum oxide (95%) substrate on the properties of Ni-Cr alloy thin film is studied.The thin films are prepared on the substrates with different roughness by using magnetron sputtering.The micro-structure,adhesive and electrical properties of the thin films were investigated by using scanning electron microscopy,scratch method and four-probe method.The burst voltage and current of the thin film transducers with different substrates were measured according to D-optimization method.The results show that the particle size,structural defect,resistivity and adhesion strength of the thin film increase with the increase of the substrate roughness.The difference among the burst time of the samples with difference substrate roughness gradually decreases with the increase of stimulation amount.The burst time is approximate to 20 μs in the charging voltage of 37 V. 展开更多
关键词 physical chemistry Ni-Cr thin film magnetron sputtering surface roughness electrical property morphology ADHESION
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不同脉冲能量Er:YAG激光对钛盘表面形貌及生物学性能的影响
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作者 刘翼 邱江珊 +2 位作者 申道南 关鑫 丁一 《国际口腔医学杂志》 CAS CSCD 北大核心 2024年第6期713-721,共9页
目的探究不同脉冲能量Er:YAG激光照射后钛盘表面形貌与粗糙度的变化,研究不同钛盘表面形貌对细胞生物学行为以及细菌生物学特性的影响,探索Er:YAG激光改性钛表面的合适参数。方法将Ti6Al4V钛盘随机分为5组,设置不同的参数(0、50、100、... 目的探究不同脉冲能量Er:YAG激光照射后钛盘表面形貌与粗糙度的变化,研究不同钛盘表面形貌对细胞生物学行为以及细菌生物学特性的影响,探索Er:YAG激光改性钛表面的合适参数。方法将Ti6Al4V钛盘随机分为5组,设置不同的参数(0、50、100、150、200 mJ/P)进行Er:YAG激光照射,通过原子力显微镜观察钛盘表面形貌和粗糙度的变化,使用扫描电子显微镜、酶联免疫吸附试验检测钛盘表面MG63细胞的黏附、增殖和成骨分化能力,通过结晶紫染色和活/死细菌染色观察钛盘表面生物膜的形成。结果激光对钛盘表面形貌的改变程度以及钛盘表面粗糙度与脉冲能量成正比,组间差异具有统计学意义(P<0.05)。细胞实验结果显示:100 mJ/P组钛盘表面MG63细胞的早期黏附形态、增殖和成骨分化能力明显优于其他组,差异有统计学意义(P<0.05)。细菌实验结果显示:50 mJ/P组钛盘表面生物膜形成明显低于未处理组,差异有统计学意义(P<0.05)。结论在100 mJ/P处理后钛盘表面MG63细胞表现出良好的黏附、增殖及分化能力,在50 mJ/P处理时细菌生物膜形成最少。50~100 mJ/P可能是Er:YAG激光改性种植体表面的适宜参数区间。 展开更多
关键词 ER:Yag激光 参数 钛盘 表面形貌
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利用激光辐照AgCl纳米立方体制备表面增强拉曼散射基底的方法 被引量:1
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作者 马艳颍 王佳乐 《东华大学学报(自然科学版)》 CAS 北大核心 2024年第2期46-51,共6页
利用激光辐照AgCl纳米立方体,通过析出Ag纳米颗粒制备了表面增强拉曼散射(surface-enhanced Raman scattering,SERS)基底。利用水热法合成AgCl纳米立方体,随后利用波长为633 nm的激光进行辐照,AgCl纳米立方体表面会析出Ag纳米颗粒。利... 利用激光辐照AgCl纳米立方体,通过析出Ag纳米颗粒制备了表面增强拉曼散射(surface-enhanced Raman scattering,SERS)基底。利用水热法合成AgCl纳米立方体,随后利用波长为633 nm的激光进行辐照,AgCl纳米立方体表面会析出Ag纳米颗粒。利用场发射扫描电子显微镜对辐照后的样品进行形貌表征,同时采用对氨基硫酚(PATP)探索Ag@AgCl样品的SERS灵敏度。结果发现,随着辐照功率增大或者辐照时间增加,析出的Ag颗粒数量增多并且尺寸增大,因此获得的SERS基底的灵敏度得到增强。研究结果为制备SERS基底提供了一种比较简便的方法。 展开更多
关键词 agCl纳米立方体 激光辐照 表面等离子体 表面增强拉曼散射 ag
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WS_(2)@Ag复合材料光热降解RhB性能研究
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作者 储德亮 刘钟馨 王洁琼 《水处理技术》 CAS CSCD 北大核心 2024年第6期80-84,共5页
光热过程是太阳能利用中最有效的能量转换过程。在这项研究中,将制备的WS_(2)@Ag复合材料作为光热催化剂。结合过一硫酸盐(PMS)辅助催化去除有机染料RhB。通过UV-Vis、XRD、SEM、TEM等测试手段对该催化剂进行了表征。并在一个模拟太阳... 光热过程是太阳能利用中最有效的能量转换过程。在这项研究中,将制备的WS_(2)@Ag复合材料作为光热催化剂。结合过一硫酸盐(PMS)辅助催化去除有机染料RhB。通过UV-Vis、XRD、SEM、TEM等测试手段对该催化剂进行了表征。并在一个模拟太阳光照射下,以广泛使用的有机染料RhB的降解为例,从光热催化、光催化和热催化等方面综合评价了WS_(2)@Ag复合材料的光热降解性能。动力学分析表明,WS_(2)@Ag作为催化剂,光热组的降解效率分别是纯光组和纯热组的1.33和1.82倍,在50 min内降解率达到95%。系统地研究了光热催化条件下催化剂和PMS的用量及复合材料的循环稳定性,通过捕获实验测试结果表明:WS_(2)@Ag/PMS催化体系中存在SO_(4)^(·-)、·OH和^(1)O_(2)活性物种,协同降解RhB。最后提出了WS_(2)@Ag材料通过不同方式激活PMS产生高活性物种来氧化RhB的降解机理。 展开更多
关键词 光热催化 降解有机染料 WS_(2)@ag 表面等离子效应
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纯水相Ag^(+)/TiO_(2)溶液的制备及其抗菌性能研究
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作者 吴世斌 谢镇泽 +1 位作者 王景光 杜昶 《功能材料》 CAS CSCD 北大核心 2024年第4期4167-4173,共7页
采用低温液相法制备了纯水相纳米TiO_(2)溶液,然后在纳米TiO_(2)表面沉积Ag^(+)获得了纯水相Ag^(+)/TiO_(2)溶液。通过扫描电子显微镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、傅里叶变换红外光谱仪(FT-IR... 采用低温液相法制备了纯水相纳米TiO_(2)溶液,然后在纳米TiO_(2)表面沉积Ag^(+)获得了纯水相Ag^(+)/TiO_(2)溶液。通过扫描电子显微镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、傅里叶变换红外光谱仪(FT-IR)、紫外-可见光吸收光谱仪(UV-Vis)和荧光光谱仪(PL)进行表征。经过各项表征分析可知,Ag^(+)/TiO_(2)粒子是粒径10 nm的球形颗粒,XRD特征峰为锐钛矿二氧化钛和硫酸银的叠加峰。此外,沉积的Ag以+1的价态存在,且提高了纳米TiO_(2)的光催化活性,产生了协同效应。抗菌测试结果表明,制备的纯水相Ag^(+)/TiO_(2)溶液在不同菌种和不同应用环境下均表现优异的抗菌性能,说明了Ag^(+)/TiO_(2)抗菌的高效性和广谱性,具有极大的市场应用价值。 展开更多
关键词 ag^(+)/TiO_(2)溶液 低温液相 表面沉积 纯水相 抗菌
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AgCl/Ag复合粉体材料的制备及机理
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作者 杨华键 赵远云 《硅酸盐通报》 CAS 北大核心 2024年第7期2697-2705,共9页
采用超声辅助脱合金法,以Ca-Mg-Cu-Ag非晶条带为前驱体,Cu-Ag纳米多孔材料为中间产物,不同溶剂组成的盐酸溶液为反应液,制备出不同形貌的AgCl粉体材料,利用SEM、XRD等检测手段对样品的形貌、结构、成分等进行了表征分析,揭示了AgCl/Ag... 采用超声辅助脱合金法,以Ca-Mg-Cu-Ag非晶条带为前驱体,Cu-Ag纳米多孔材料为中间产物,不同溶剂组成的盐酸溶液为反应液,制备出不同形貌的AgCl粉体材料,利用SEM、XRD等检测手段对样品的形貌、结构、成分等进行了表征分析,揭示了AgCl/Ag复合粉体材料在不同反应液中的形成过程及机理。研究表明:在超声辅助作用下,当以盐酸乙醇溶液为反应液时,改变浓盐酸溶液与乙醇溶剂的体积比后Cu-Ag纳米多孔材料可以完全溶解于该溶液中并重新析出不同形貌的AgCl粉体材料;而以盐酸水溶液为反应液时,改变盐酸水溶液与蒸馏水溶液的体积比后Cu-Ag纳米多孔材料只能直接转变为近球形的AgCl粉体材料,且不能溶解于盐酸水溶液中再重新析出。在超声与盐酸乙醇溶液的共同作用下,Cu-Ag纳米多孔材料存在一种新颖的AgCl“生成-溶解-再析出”机制,可以精准地控制再析出AgCl晶体的形貌和尺寸。 展开更多
关键词 agCl/ag 复合粉体材料 超声辅助 脱合金法 形貌
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Cu掺杂对Ag/SnO_(2)电接触材料性能的影响
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作者 刘松涛 孙仲明 +4 位作者 王俊勃 思芳 郑贤军 刘建江 方晨羽 《稀有金属与硬质合金》 CAS CSCD 北大核心 2024年第6期89-97,共9页
为了系统讨论Cu掺杂对Ag/SnO_(2)电接触材料耐电弧烧蚀性能的影响,分别制备了Ag/SnO_(2)电接触材料和不同添加量Cu掺杂Ag/SnO_(2)电接触材料。利用XRD、TEM、SEM、EDS分别表征了SnO_(2)粉体和电弧烧蚀前后Ag/SnO_(2)电接触材料的物相结... 为了系统讨论Cu掺杂对Ag/SnO_(2)电接触材料耐电弧烧蚀性能的影响,分别制备了Ag/SnO_(2)电接触材料和不同添加量Cu掺杂Ag/SnO_(2)电接触材料。利用XRD、TEM、SEM、EDS分别表征了SnO_(2)粉体和电弧烧蚀前后Ag/SnO_(2)电接触材料的物相结构、微观组织和成分分布,并测试了Ag/SnO_(2)电接触材料的物理性能和耐电弧烧蚀性能,探讨了Cu掺杂影响Ag/SnO_(2)电接触材料性能的机制。结果表明:掺杂的Cu离子溶入SnO_(2)的晶体结构引起晶格畸变,抑制SnO_(2)晶粒生长,使其晶粒尺寸减小。随着Cu添加量的增加,Cu掺杂Ag/SnO_(2)电接触材料的硬度、电阻率及电弧烧蚀下的质量损失均先减小后增大,而密度先增大后减小;Cu/Sn物质的量之比为0.12的Cu掺杂Ag/SnO_(2)(Ag/0.12Cu-SnO_(2))电接触材料的电阻率、硬度、电弧烧蚀下的质量损失均最低,密度最大,相对于无掺杂的Ag/SnO_(2)电接触材料,其组织分布的均匀性明显改善,平均电阻率、平均硬度和电弧作用下的质量损失分别降低了13.33%、6.87%和59.40%,而平均密度提高了4.11%。适量添加Cu可以明显改善Ag/SnO_(2)电接触材料的耐电弧烧蚀性能,但过量添加反而会降低该性能。原因在于,Cu掺杂SnO_(2)晶粒尺寸减小,提高了其与Ag基体间的界面结合强度以及二者之间的润湿性,抑制了SnO_(2)颗粒从Ag熔池中逸出并在电接触材料表面富集,从而提高Ag/SnO_(2)电接触材料的耐电弧烧蚀性能。 展开更多
关键词 ag/SnO_(2)电接触材料 CU掺杂 晶体结构 形貌 耐电弧烧蚀性能 物理性能 机制
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