The Ti/SnO2 Sb2O4 electrode has been prepared by the electroplate sinter method. The effect of SbCl3 adding amount and sintering temperature on its electrode lifetime and oxygen evolution potential were investigated b...The Ti/SnO2 Sb2O4 electrode has been prepared by the electroplate sinter method. The effect of SbCl3 adding amount and sintering temperature on its electrode lifetime and oxygen evolution potential were investigated by means of EDX, SEM and XRD analysis. The results indicated that the electrode appeared the best performance when the SbCl3 adding amounts was 0.2g and the sintering temperature was 550℃. In optimized conditions Ti substrate was entirely covered by SnO2 Sb2O4 and the combinations among them were tight. Due to the use of electroplate method, the electrical conductivity, the oxygen evolution potential and the electrode lifetime were increased, so the electro catalytic activity and the electrochemical stability of the prepared electrode were found to be superior.展开更多
Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electroc...Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electrochemical decomposition was monitored by ultra-violet spectrophotometry and CODCr method. The electrochemical decomposition mechanism of imazethapyr was studied primarily by UV-VIS spectrophotometry. The effectiveness of the electrochemical pretreatment was proved by the comparative aerobic biological treatment test based on the activated sludge process.展开更多
采用超声涂覆-热分解法制备稀土金属Ce掺杂Ti/SnO_2-Sb电极,利用SEM对电极表面形态进行表征,并考察了Ce掺杂量和电流密度对修饰电极电催化性能和稳定性的影响。结果表明,掺杂后电极涂层中引入了新物质CeO_2,优化了电极的表面结构和形态...采用超声涂覆-热分解法制备稀土金属Ce掺杂Ti/SnO_2-Sb电极,利用SEM对电极表面形态进行表征,并考察了Ce掺杂量和电流密度对修饰电极电催化性能和稳定性的影响。结果表明,掺杂后电极涂层中引入了新物质CeO_2,优化了电极的表面结构和形态;制备得到的电极对苯酚和对甲酚都有较好的降解效果,当Ce掺杂量为1%时降解苯酚性能最优,Ce掺杂量为2%时降解对甲酚性能最优;在最优掺杂量下,当电流密度为10 m A/cm2时降解苯酚性能最佳,电流密度为20 m A/cm2时降解对甲酚性能最佳。展开更多
为了研究满足压载水排放标准的处理系统,建立了可以实现单独控制的以钛基氧化锡钌(Ti/SnO2-RuO2)为阳极材料的电催化系统和紫外辐射复合压载水处理系统。以杜氏盐藻、青岛大扁藻、锥状克里斯普藻和四爿藻为目标处理微生物,对该系统进行...为了研究满足压载水排放标准的处理系统,建立了可以实现单独控制的以钛基氧化锡钌(Ti/SnO2-RuO2)为阳极材料的电催化系统和紫外辐射复合压载水处理系统。以杜氏盐藻、青岛大扁藻、锥状克里斯普藻和四爿藻为目标处理微生物,对该系统进行微藻灭活实验结果表明,Ti/SnO2-RuO2阳极电催化-UV复合系统克服了单独电催化系统高能耗、单独紫外辐射系统紫外灯衰减迅速的缺点,在紫外辐射出度45μW/cm2、电流密度130 m A/cm2、HRT为1.0 s的条件下,处理出水4 h后活藻数量可以达到国际海事组织(IMO)对压载水中10~50μm微生物的灭活要求。总剩余氧化物(TRO)含量会随时间推移而有衰减,且没有出现细胞光复活和修复现象,说明该复合系统具有理想的持续灭活作用。展开更多
目前在电化学氧化处理法降解苯酚废水的研究过程中,研究者多将重心放在活性电极的探索及制备上,而对于反应器的开发鲜有报道。就这一问题,本文研究了新型微流控反应器中苯酚的电化学降解效果。电化学氧化实验在装有Ti/SnO2-Sb2O5阳极的...目前在电化学氧化处理法降解苯酚废水的研究过程中,研究者多将重心放在活性电极的探索及制备上,而对于反应器的开发鲜有报道。就这一问题,本文研究了新型微流控反应器中苯酚的电化学降解效果。电化学氧化实验在装有Ti/SnO2-Sb2O5阳极的微型流通池中操作进行,实验对循环体系的体积流率ΦV、电极间距h的影响进行了考察。结果表明,当流通电解槽中的阴阳极间距采用微米级尺寸时,苯酚的阳极氧化反应取得了较快的氧化速度。在i=20 m A/cm2、ΦV=0.54 m L/min的电解条件下,电解2~3h苯酚去除率即可达到90%以上,相同流速下电极间距h越小降解速率越快。且由数据回归得到了苯酚的一系列随h的减小而增大的准一级反应的反应速率常数。这一结论表明微流控电解槽内的苯酚降解过程主要传质控制过程。展开更多
文摘The Ti/SnO2 Sb2O4 electrode has been prepared by the electroplate sinter method. The effect of SbCl3 adding amount and sintering temperature on its electrode lifetime and oxygen evolution potential were investigated by means of EDX, SEM and XRD analysis. The results indicated that the electrode appeared the best performance when the SbCl3 adding amounts was 0.2g and the sintering temperature was 550℃. In optimized conditions Ti substrate was entirely covered by SnO2 Sb2O4 and the combinations among them were tight. Due to the use of electroplate method, the electrical conductivity, the oxygen evolution potential and the electrode lifetime were increased, so the electro catalytic activity and the electrochemical stability of the prepared electrode were found to be superior.
文摘Methodology for the electrochemical decomposition of imazethapyr using Ti/SnO2-Sb2O5/PbO2 anode in Na2SO4 medium is suggested in this paper. The electrolysis reaction conditions were optimized. The process of electrochemical decomposition was monitored by ultra-violet spectrophotometry and CODCr method. The electrochemical decomposition mechanism of imazethapyr was studied primarily by UV-VIS spectrophotometry. The effectiveness of the electrochemical pretreatment was proved by the comparative aerobic biological treatment test based on the activated sludge process.
文摘采用超声涂覆-热分解法制备稀土金属Ce掺杂Ti/SnO_2-Sb电极,利用SEM对电极表面形态进行表征,并考察了Ce掺杂量和电流密度对修饰电极电催化性能和稳定性的影响。结果表明,掺杂后电极涂层中引入了新物质CeO_2,优化了电极的表面结构和形态;制备得到的电极对苯酚和对甲酚都有较好的降解效果,当Ce掺杂量为1%时降解苯酚性能最优,Ce掺杂量为2%时降解对甲酚性能最优;在最优掺杂量下,当电流密度为10 m A/cm2时降解苯酚性能最佳,电流密度为20 m A/cm2时降解对甲酚性能最佳。
文摘为了研究满足压载水排放标准的处理系统,建立了可以实现单独控制的以钛基氧化锡钌(Ti/SnO2-RuO2)为阳极材料的电催化系统和紫外辐射复合压载水处理系统。以杜氏盐藻、青岛大扁藻、锥状克里斯普藻和四爿藻为目标处理微生物,对该系统进行微藻灭活实验结果表明,Ti/SnO2-RuO2阳极电催化-UV复合系统克服了单独电催化系统高能耗、单独紫外辐射系统紫外灯衰减迅速的缺点,在紫外辐射出度45μW/cm2、电流密度130 m A/cm2、HRT为1.0 s的条件下,处理出水4 h后活藻数量可以达到国际海事组织(IMO)对压载水中10~50μm微生物的灭活要求。总剩余氧化物(TRO)含量会随时间推移而有衰减,且没有出现细胞光复活和修复现象,说明该复合系统具有理想的持续灭活作用。
文摘目前在电化学氧化处理法降解苯酚废水的研究过程中,研究者多将重心放在活性电极的探索及制备上,而对于反应器的开发鲜有报道。就这一问题,本文研究了新型微流控反应器中苯酚的电化学降解效果。电化学氧化实验在装有Ti/SnO2-Sb2O5阳极的微型流通池中操作进行,实验对循环体系的体积流率ΦV、电极间距h的影响进行了考察。结果表明,当流通电解槽中的阴阳极间距采用微米级尺寸时,苯酚的阳极氧化反应取得了较快的氧化速度。在i=20 m A/cm2、ΦV=0.54 m L/min的电解条件下,电解2~3h苯酚去除率即可达到90%以上,相同流速下电极间距h越小降解速率越快。且由数据回归得到了苯酚的一系列随h的减小而增大的准一级反应的反应速率常数。这一结论表明微流控电解槽内的苯酚降解过程主要传质控制过程。
