期刊文献+

Ti/SnO_2-Sb_2O_5/PbO_2阳极电化学氧化降解苯甲酸研究 被引量:6

Electrochemical Degradation of Benzoic Acid by Anodic Oxidation on Ti/SnO_2-Sb_2O_5/PbO_2 Electrodes
在线阅读 下载PDF
导出
摘要 文章研究了Ti/SnO2-Sb2O5/PbO2在两室电解池中氧化降解苯甲酸的性能,主要考察了电流密度、初始pH值、初始苯甲酸浓度和支持电解质这四个参数对TOC去除效率的影响。实验表明在电流密度为30 mA/cm2,初始苯甲酸浓度为0.5 mmol/L,支持电解质(Na2SO4)为0.1 mol/L的条件下,经过6 h反应,TOC去除效率达到65%。初始pH值对TOC去除没有显著的影响。 Electrochemical performance of Ti/SnO2-Sb2O5/PbO2 electrodes in the oxidation of simulated wastewater containing benzoic acid using a two-compartment electrochemical system was investigated.Influence of operating variables on TOC removal efficiency was studied as a function of current density,initial pH,initial benzoic acid concentration and supporting electrolyte concentration.Under the conditions of a density current of 30 mA/cm^2,initial benzoic acid concentration of 0.5 mmol/L,supporting electrolyte concentration(Na2SO)4of 0.1 mol/L and after 6h reaction,TOC removal efficiency was up to 65%.And no significant effect of initial pH on TOC removal could be observed.
出处 《环境科学与技术》 CAS CSCD 北大核心 2011年第7期17-19,共3页 Environmental Science & Technology
基金 国家自然科学基金项目资助(20977086)
关键词 Ti/SnO2-Sb2O5/PbO2 阳极氧化 苯甲酸 高级氧化技术 电化学 Ti/SnO2-Sb2O5/PbO2 anodic oxidation benzoic acid advanced oxidation process electrochemistry
作者简介 蔡国君(1971-),男,工程师,主要从事水污染控制工程方面的研究,(电话)13705767019(电子信箱)cgj7019@163.com; 通讯作者,(电话)0571-88320811(电子信箱)fanzh@zjut.cdu.cn。
  • 相关文献

参考文献8

  • 1Menini R, Henuset Y M, Foumier J. Electrochemical oxi- dation of phenolic compounds using a flow-through elec- trolyser with porous solid electrodes[J]. Journal of Applied Electrochemistry, 2005,35 (6) : 625-631.
  • 2Song S, Zhan L Y, He Z Q, et al. Mechanism of the an- odic oxidation of 4-chloro-3-methyl phenol in aqueous so- lution using Ti/SnO2-Sb/PbO2 electrodes[J]. Journal of Haz- ardous Materials, 2010,175( 1-3 ) : 614-621.
  • 3Vinodgopal K, Peller J, Makogon O, et al. Ultrasonic min- eralization of a reactive textile azo dye, remazol black B [J]. Water Research, 1998,32(12) : 3646-3650.
  • 4Israilides C J, Vlyssides A G, Mourafeti V N, et al. Olive oil wastewater treatment with the use of an electrolysis sys- tem[J]. Bioresource Technology, 1997,61 ( 2 ) : 163-170.
  • 5Chen X M, Chen G H, Yue P L. Investigation on the elec- trolysis voltage of electrocoagulation[J]. Chemical Engineer- ing Science, 2002,57(13) : 2449-2455.
  • 6Kirk D W, Shrifian H, Foulkes F R. Anodic oxidation of aniline for wastewater treatment[J]. Journal of Applied Elec- trochemistry, 1985,15( 2 ) : 285-292.
  • 7Martinez-Huitle C A, Brillas E. Decontamination of wastewaters containing synthetic organic dyes by electro- chemical methods:A general review[J]. Applied Catalysis B: Environmental, 2009,87(3-4) : 105-145.
  • 8Lucas M S, Peres J A. Decolorization of the azo dye Reac- tive Black 5 by Fenton and photo-Fenton oxidation [J]. Dyes and Pigments, 2006,71(3): 236-244.

同被引文献68

引证文献6

二级引证文献9

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部